A catalyst for use in a rigid foaming system including an isocyanate and a halogenated olefinic blowing agent is described and a process for creating a rigid foaming system thereof. The catalyst can include a morpholine ring and a central N-alkyl group.

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.

The embodiments described herein generally relate to methods and chemical compositions of triazine-arylhydroxy-aldehyde condensates. In one embodiment, a triazine-arylhydroxy-aldehyde condensate is reacted with at alkoxylation agent to form alkoxylated triazine-arylhydroxy-aldehyde condensates.

The present disclosure relates to a method for producing rigid polyurethane foam composite elements, including at least one outer layer and a rigid polyurethane foam layer, by mixing (a) polyisocyanates with (b) compounds having at least two hydrogen atoms reactive with isocyanate groups, (c) optionally flame retardant(s), (d) blowing agent, (e) catalyst, and (f) optionally auxiliaries and adjuvants to form a reaction mixture, applying the reaction mixture to the outer layer, and curing it to form the rigid polyurethane foam. The present disclosure further relates to a rigid polyurethane foam composite element obtainable by such a method.

Catalyst compositions useful in the production of insulating polyurethane or polyisocyanurate foam are disclosed. The catalyst compositions impart increased stability of a mixture of the catalyst, a halogen-containing blowing agent, and a polyol. These catalyst compositions comprise of at least 10% of a tetraalkylguanidine and at least 10% of a tertiary amine catalyst with an isocyanate reactive group. These improved catalysts can be used with any halogenated blowing agent, and provide substantial stability benefits with the use of hydrofluoroolefins and hydrofluorochloroolefins. In an exemplary embodiment, a process includes providing a pre-mix comprising a hydrohaloolefin blowing agent, at least one polyol, water, and a catalyst comprising 10-50% tetramethylguanidine and 10-90% of one or more of an amine catalyst containing an isocyanate reactive group.

The present invention provides all liquid, two-component foam forming compositions for forming fire-resistant rigid polyurethane foams comprising a chlorine-free liquid flame retardant (FR) additive. The compositions comprise a polyisocyanate component and, as a separate component, a polyol component of a blend of one or more high hydroxyl functional aromatic polyester polyols and one or more low hydroxyl functional aromatic polyester polyols, a novolac polyether polyol, a trimerization catalysts, a liquid FR additive, preferably, one FR additive, more preferably, a halogen free FR additive, and water, or water and a physical blowing agent as a blowing agent. The low hydroxyl functional aromatic polyester polyols enable the provision of readily processible, all liquid polyol components having a low viscosity as well as ASTM E84A Class A rated rigid polyurethane foams.

Polyurethane composites and methods of preparation are described herein. The methods of making the polyurethane composite can include mixing (1) at least one isocyanate selected from the group consisting of diisocyanates, polyisocyanates, and mixtures thereof, (2) at least one polyol, (3) an inorganic filler, and (4) an evaporative coolant in an extruder to form a mixture. The method also include extruding the mixture into a mold cavity, generating heat in the mold cavity from the reaction of the at least one isocyanate and the at least one polyol, and allowing the evaporative coolant to migrate to an interface between the mixture and the interior mold surface. The temperature of the mixture causes evaporation of the evaporative coolant at the interface thereby removing heat at the interface. Suitable evaporative coolants for use in the methods of making the polyurethane composites include hydrofluorocarbons and hydrochlorofluorocarbons.

Provided is a method for producing a light rigid urethane foam superior in moldability (cell interconnection, spraying thickness, adhesiveness, etc.), heat-insulating efficiency, and others by a spraying method, using water as foaming agent. A method for producing an open-cell polyurethane foam, comprising obtaining the open-cell polyurethane foam by mixing and reacting a polyol composition containing a polyol compound, water as a foaming agent, a foam stabilizer, a catalyst, and a flame retardant with a polyisocyanate compound by a spraying method, the polyol compound containing polyols (A), (B), and (C) at a polyol (A) content of 10 to 40 wt parts, a polyol (B) content of 10 to 70 wt parts, and a polyol (C) content of 10 to 70 wt parts.

An isocyanate reactive composition for making a polyurethane foam includes a tertiary amine urethane catalyst comprising a di(C1-C4)alkyl fatty alkyl amine and a polyester polyol. The use of one or more of fatty alkyl tertiary amine serves to reduce hydrolysis of the polyester polyol in the isocyanate reactive composition.

Esterified arylhydroxy compounds for the production of polyurethane or polyisocyanurate. In order to provide aromatic polyols for the production of polyurethanes or polyisocyanurates which are process-technically suitable in terms of their viscosity and at the same time give the end product good physical properties and a good reaction to fire, esterified arylhydroxy compounds are proposed as polyols.