Provided are a curable resin composition having high durability and adherence to a base material such as a metal, a molded composite member formed by coating the base material with the curable resin composition and performing resin molding, and a production method for the same. The curable resin composition contains a polyamide-based resin, a blocked polyisocyanate, and an epoxy compound, and the polyamide-based resin has an amino group concentration from 20 to 300 mmol/kg, and has a water absorption of 1 mass % or less determined by a water absorption test specified by ASTM D570. The polyamide-based resin has a C.sub.8-18 alkylene chain and has a melting point from 160 to 250? C. Per 1 mol of amino groups of the polyamide-based resin, a proportion of isocyanate groups of the blocked polyisocyanate is from 1.5 to 5 mol, and a proportion of epoxy groups of the epoxy compound is from 0.1 to 0.8 mol.

Provided is an adhesive comprising a reaction product of (A) an aliphatic polyisocyanate having a molecular weight of from 132 to 700; and (B) a polyaspartate comprising a reaction product of (B1) a polyamine having a molecular weight of at least 240, and (B2) a Michael addition receptor, wherein viscosity @ 23? C. according to ASTM D1084-16, remains below 150 cps after four hours, and wherein the adhesive develops an acceptable bond strength to a substrate, defined as having a minimum of 150 g/in. measured @ 23? C. according to ASTM D 1876-01 or substrate tear, in less than five days after the substrate is laminated with the adhesive. The inventive flexible packaging adhesives are free of aromatic amines and may find use in multilayer laminates for a variety of industries, including the food processing, cosmetics, and detergents industries.

In one or more embodiments, the present invention provides a novel approach to the addition of plasticizers for softening TPUs, i.e., lowering the durometer and the melt viscosity. This approach involves incorporating bonded sulfonate groups with quaternary ammonium counterions into the TPU. In one or more embodiments of the present invention, the softening of TPU is achieved by incorporating an ionic diol, such as N,N-bis (2-hydoxyethyl)-2-aminoethane-sulfonic acid (BES), coupled with various bulky alkyl ammonium cations, during the chain extension step of the TPU synthesis. It is believed that that steric hindrance of the bulky quaternary ammonium groups weakens the dipole-dipole interactions of the sulfonate groups and/or lowers the crystallinity of the hard block, thereby creating additional free volume that softens the polymer and lowers the melt viscosity.

The invention relates to water-vapor permeable, flat composite parts consisting of at least two layers, at least one layer being made of a polyester and polyether-based thermoplastic polyurethane. The invention also related to the use thereof.

A process for preparing a polymeric membrane for materials used in crop production comprising: a) providing an aqueous dispersion of a polyurethane or polyurethane-urea elastomer comprising segments formed from the copolymer segment of Formula I

A.sup.1-[Y.sup.1].sub.n-L-[Y.sup.2].sub.q-A.sup.2 Formula I

wherein A.sup.1 is an end capping group; A.sup.2 is hydrogen or an end capping group; each [Y.sup.1].sub.n and [Y.sup.2].sub.q is independently selected from a polyether macrodiol, polycarbonate macrodiol, polyester macrodiol, and wherein at least one of [Y.sup.1].sub.n and [Y.sup.2].sub.q is a polyester macrodiol; L is a divalent linking compound independently selected from urethane, urea, carbonate, ester, and phosphonate; n is an integer of 2 to 50; q is an integer of 2 to 50; and b) spraying the aqueous dispersion onto materials to be used in crop production to form a polymeric membrane on the materials.

A controlled release polymer is provided which includes a polymer that has backbone selected from polyesters and polyurethanes, and an amide group with a pendant functional group, where the nitrogen atom of the amide group is part of the polymer backbone, and an active compound dispersed in the polymer. The active compound may be released over time from the controlled release polymer

A polyurethane elastomer including a polymerization product of an amide group-including compound, a polyol compound, a polybasic acid compound, and a diisocyanate compound, a thermoplastic resin composition including the polyurethane elastomer, a molded article made of the thermoplastic resin composition, and a method of preparing the polyurethane elastomer.

The invention relates to a polymer or oligomer comprising a) An oligomeric or polymeric core comprising carbon atoms and at least one of oxygen atoms and nitrogen atoms, and b) at least three hydrocarbyl terminal and/or pending groups having 12 to 100 carbon atoms, wherein the hydrocarbyl groups are linked to the core via c) a linking moiety comprising i) a urethane group and ii) a group selected from urethane group, urea group, and biuret group.

A wet on wet process for multilayer coating of a substrate includes applying on the substrate to be coated a surfacer layer of an organic solvent-based surfacer coating composition comprising at least one polyaspartic acid ester, at least one polyisocyanate cross-linking agent with free isocyanate groups, at least one pigment and/or extender and at least one organic solvent. The surfacer layer on coated substrate is flashed off and a top coat layer is applied on the surfacer layer.

A polyurethane catalyst comprises a sodium compound, the sodium compound being 1 to 60 wt % of the polyurethane catalyst by the mass percent, and further comprises a tertiary amine and/or pyridine compound. The sodium compound and the tertiary amine and/or pyridine compound achieve a synergistic effect; during the catalysis of the polymerization of isocyanate and polyalcohol, the speed of the polymerization reaction is increased; and the prepared polyurethane material has excellent physical properties, does not contain any heavy metal element at all, is an environment-friendly catalyst, solves the technical problem of ensuring environmental protection, safety and the catalytic efficiency of the polyurethane catalyst, and is particularly applicable to the preparation of polyurethane synthetic leather resin slurry, a polyurethane elastomer (prepolymer), a polyurethane coating, a polyurethane adhesive, a polyurethane composite material, flexible polyurethane foam, and a rigid polyurethane material.