The present invention provides a glove having a coating formed of a urethane resin composition including a urethane resin (A) and water (B). The urethane resin (A) is produced using a polycarbonate polyol (a1-1) as a raw material. The coating has a 500% modulus of 7 MPa or less. Example urethane resins used as the urethane resin (A) preferably include: a urethane resin produced using a polycarbonate polyol (a1-1) and polytetramethylene glycol (a1-2) as raw materials at a specified mass ratio; and/or a urethane resin produced using a polycarbonate polyol (a1-1) and a compound (a1-4) as raw materials at a specified mass ratio, the compound (a1-4) having a number average molecular weight of less than 500, a branched structure, and 2 to 4 hydroxyl groups.

An ink composition for ink jet recording includes resin particles of a urethane resin colored with a disperse dye, and the acid value of the urethane resin is 1 KOHmg/g or more and less than 100 KOHmg/g.

A prepolymer comprising acid functionality is made by a process comprising the step of contacting: (i) a di-isocyanate, (ii) a polyol containing an acid group, (iii) a polyol without an acid group, and (iv) a metal salt catalyst, the contacting conducted under reaction conditions and in a solvent consisting essentially of: (A) a dialkyl amide, and (B) optionally, an aprotic glycol ether. The prepolymer is useful in the preparation of water-based polyurethane dispersions, and certain of the solvent blends consisting essentially of a dialkyl amide and an optional aprotic glycol ether are azeotropic or pseudo-azeotropic.

The disclosure relates to a method for preparing a hydroxyl-functional inherent matting waterborne polyurethane and a high-performance inherent matting coating made of the same. The inherent matting waterborne polyurethane includes the following components in parts by weight: a polymer polyol 15-25 parts; an isocyanate monomer 5-15 parts; 2,2-dimethylol propionic acid or 2,2-dimethylol butyric acid 0.2-0.8 parts; a pH regulator 0.1-0.7 parts; a hydroxyalkyl ethylenediamine chain extender 0.5-3.0 parts; a dialkyl alcohol amine blocking agent 0.1-4.0 parts; a diaminosulphonate chain extender 0.2-1.5 parts; a catalyst 0.01-0.05 parts; an organic solvent 2-10 parts; deionized water 50-80 parts; a thickener 0.1-3 parts. In the post-chain extension stage of the waterborne polyurethane, through hydroxyalkyl ethylene diamine chain extension and dialkyl alcohol amine blocking, hydroxyl groups are introduced into the polymer molecular chain.

An ink jet ink composition which is an aqueous ink includes a resin dispersion, in which the resin dispersion is a polyurethane resin dispersion formed of a polyurethane resin (U) obtained by reacting an active hydrogen atom-containing component (A) containing a high-molecular-weight polyol component (a1) having a number-average molecular weight of 500 or more and an organic polyisocyanate component (B), and the high-molecular-weight polyol component (a1) includes a polyolefin polyol (a11) having a constituent unit represented by General Formula (1) and/or a constituent unit represented by General Formula (2), and a polyester polyol (a12) having a constituent unit represented by General Formula (3).

A process for the preparation of a polyurethane dispersion with at least one extension agent B that has x hydroxyl groups and y amine groups, where x+y≥2 with x and y equal or larger than 0, and that has an additional functional group that is capable of forming a salt, such that the dispersion of the polyurethane has a solids content of at least 50 weight percent and does not contain acetone or other solvents or amines that have a boiling point of below 250° C.

A polyurethane resin having an anionic group and a polyalkylene oxide in a side chain thereof is obtainable by reacting a polyester polyol, a polyether diol, a polyol containing an anionic group, and a polyisocyanate, and the polyester polyol is obtained by reacting an aromatic polycarboxylic acid and a polyol. The polyurethane resin can be used as binder in an ink jet ink and provides excellent scratch and solvent resistance of printed images.

An object of the present invention is to provide an aqueous dispersion for use in a cosmetic, which has both the flexibility and hair styling properties (hair set retention properties), and which allows for easily re-styling hair when the hair style once set has been disturbed; and a cosmetic including the same. In the above mentioned aqueous dispersion and the cosmetic, a polyurethane is used, which is obtainable from a polyol component including at least one type of a polyether polyol and a polyester polyol, and a polyvalent isocyanate component, wherein the polyol component includes: a polyether polyol containing as a major component a structural unit derived from a polyalkylene glycol having from 2 to 4 carbon atoms, and having a number average molecular weight of 400 or more and 4,000 or less; or a polyester polyol containing a structural unit derived from at least one type of dicarboxylic acid selected from the group consisting of phthalic acid, isophthalic acid and terephthalic acid.

A coating composition includes: an aqueous medium; first core-shell particles dispersed in the aqueous medium, where the first core-shell particles include (i) keto and/or aldo functional groups, (ii) a polymeric shell including carboxylic acid functional groups and urethane linkages, and (iii) a polymeric core at least partially encapsulated by the polymeric shell, where the polymeric shell and/or the polymeric core may comprise the keto and/or aldo functional groups; second core-shell particles dispersed in the aqueous medium, where the second core-shell particles are different from the first core-shell particles and include (a) a polymeric shell including carboxylic acid functional groups and hydroxyl groups, and (b) a polymeric core including hydroxyl functional groups and which is at least partially encapsulated by the polymeric shell; a first crosslinker including a polyhydrazide reactive with the first core-shell particles; and a second crosslinker reactive with the first and second core-shell particles.

A waterborne polyurethane is provided. The waterborne polyurethane is formed by mixing a polyol, a diisocyanate, a dimethylol alkyl acid, and an epoxy resin into a mixture, and polymerizing the mixture. When the usage amount of the epoxy resin used is 1 part by weight, the usage amount of the polyol is 3 to 30 parts by weight, the usage amount of the diisocyanate is 1 to 10 parts by weight, and the usage amount of the dimethylol alkyl acid is 0.1-3.0 parts by weight. The epoxy resin includes an epoxy resin having a cyclic structure, a triacylglycerol having an epoxy group, or a combination thereof.