This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the adhesion of ROMP compositions to substrate materials using an adhesion promoter composition, where the adhesion promoter composition comprises a pre-reacted mixture comprising at least one compound containing at least two isocyanate groups and at least one compound comprising a heteroatom-containing functional group and a metathesis active olefin, where the adhesion promoter composition is storage stable and/or possesses in-resin storage stability when added to a resin composition, particularly a cyclic olefin resin composition, such as a ROMP composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

A two-component epoxy resin composition includes a first component K1 including at least one epoxy resin A that contains on average more than one epoxy group per molecule; and a second component K2 including a hardener B for epoxy resins; wherein the two-component epoxy resin composition contains between 2 and 35 wt.-%, based on the total weight of the composition, of at least one impact modifier I in either one or both of components K1 and K2; wherein the impact modifier I is a reaction product of at least one polymeric diol, at least one polyisocyanate, and cardanol. The two-component epoxy resin composition exhibits excellent toughness and impact peel strength

A two-component epoxy resin composition includes a first component K1 including at least one epoxy resin A that contains on average more than one epoxy group per molecule; and a second component K2 including a hardener B for epoxy resins; wherein the two-component epoxy resin composition contains between 2 and 35 wt.-%, based on the total weight of the composition, of at least one impact modifier I in either one or both of components K1 and K2; wherein the impact modifier I is a reaction product of at least one polymeric diol, at least one polyisocyanate, and cardanol. The two-component epoxy resin composition exhibits excellent toughness and impact peel strength

A stain resistant coating composition includes: urethane acrylate core-shell particles including (1) a polymeric acrylic core; and (2) a polymeric shell including a urethane linkage. The polymeric shell is formed from a reaction mixture including an isocyanate and a polyol. The polyol is substantially free of a six or more consecutive methylene group chain and/or the polyol is formed from monomers comprising a monomer content including at least 10 wt % substituted polyol and/or substituted polyacid and/or at least 25 wt % polyol or polyacid containing cyclic content, based on the total weight of the monomers forming the polyol.

An embodiment includes a platform shape memory polymer system. Such an embodiment exhibits a blend of tunable, high performance mechanical attributes in combination with advanced processing capabilities and good biocompatibility. A post-polymerization crosslinking synthetic approach is employed that combines polyurethane and thiol-ene synthetic processes. Other embodiments are described herein.

An alternative polyurethane composition is provided comprising a reaction product of an azidated polyol and a poly(alkynyl carbamate) allophanate prepolymer, wherein the poly(alkynyl carbamate) allophanate prepolymer comprises a reaction product of a first alkynol and a poly(alkynyl carbamate) prepolymer, in the presence of a metallo-organic compound of the formula: M(acac).sub.n, wherein, M=a metal, acac=an acetylacetonate residue, and n=2 or 3, wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate and a stoichiometric equivalent of a second alkynol, and wherein the polyisocyanate comprises isocyanate groups and uretdione groups. The inventive alternative polyurethane compositions may be used to provide solventborne or waterborne coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.

The present invention relates to compount (I) comprising at least one functional group A and at least one functional group B, wherein the functional groups A has structural formula A: wherein R.sub.1 is H, R.sub.2, R.sub.3 and R.sub.4 are independently chosen from H, methyl or ethyl, m is 1-6; and the functional groups B has structural formula B: R.sub.5 is H or methyl, X is O or NH, Z′ is a polyalkoxy group or an omega-alkoxy polycaprolacton group, Y′ is a collection of atoms covalently connected in linear or branched configuration n″ is 0 or 1, and m′ is an integer from 1-6; with the proviso that the summed amount of the number of functional groups A and the number of functional groups B in compound (I) is from 2-13; and the compound has a molecular weight in the range from 800-10000 Dalton.

##STR00001##

A coating composition includes a polyisocyanate component and a polyol component. The polyisocyanate component includes an aromatic ring-containing isocyanate. The polyol component includes an acrylic polyol. The acrylic polyol is a polymer of a monomer composition containing a hydroxyl group-containing polymerizable monomer and a carboxyl group-containing polymerizable monomer and containing no (meth)acrylonitrile.

A composition containing a compound (A) containing a structure represented by the following general formula (I) as a first component, at least one of an antioxidant (B1) different from a phosphorus-based antioxidant and a light stabilizer (B2) as a second component, and a resin component (C) as a third component:

##STR00001##

wherein R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, or an aralkyl group; and R.sup.3 and R.sup.4 each independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, or an aralkyl group.

A composition containing a compound (A) containing a structure represented by the following general formula (I) as a first component, at least one of an antioxidant (B1) different from a phosphorus-based antioxidant and a light stabilizer (B2) as a second component, and a resin component (C) as a third component:

##STR00001##

wherein R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, or an aralkyl group; and R.sup.3 and R.sup.4 each independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, or an aralkyl group.