A resin composition useful for additive manufacturing is provided, which resin composition may exhibit improved shelf life through inhibition of crystallization. Such resin composition may include a crystallization inhibitor as taught herein, and/or a prepolymer produced by reaction of an isocyanate with multiple isomers and comprising a lower percentage of the structurally symmetric isomer. Methods of forming a three-dimensional object using such resin composition are also provided.

A process for producing an object from a precursor comprises the steps of: I) depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; II) depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; III) repeating step II) until the precursor is formed; IV) treating the precursor obtained after step III) under conditions sufficient to at least partially trimerize to isocyanurate groups NCO groups present in the free-radically crosslinked resin of the obtained precursor to obtain the object.

A coated article is disclosed that includes a metal substrate and a coating composition disposed on at least a portion of the metal substrate. The coating can be formed from a composition that includes an acrylic copolymer, which is preferably the reaction product of ethylenically unsaturated monomers and a functional monomer. The functional monomer can be the reaction product of a multifunctional isocyanate and an ethylenically unsaturated nucleophilic monomer. The functional monomer preferably includes a blocked isocyanate group. The articles can be useful for packaging foods and beverages.

A colorless radiation curable binder dispersion includes water and a radiation curable polyurethane. The polyurethane is formed from a polyisocyanate; an acrylate or methacrylate having at least two hydroxyl (OH) groups and an acrylate or methacrylate group; another acrylate or methacrylate having an OH or amino group; and one of: i) a sulfonate or sulfonic acid having one amino group; ii) a combination of i and a compound including a carboxylic group and an OH or amino group; iii) a combination of i and a homopolymer or copolymer of poly(ethylene glycol) having one or two OH or amino groups at one chain end; or iv) a combination of i, a compound including a carboxylic group and an OH or amino group, and a homopolymer or copolymer of poly(ethylene glycol) having one or two OH or amino groups at one chain end.

A colorless radiation curable binder dispersion includes water and a radiation curable polyurethane. The polyurethane is formed from a polyisocyanate; an acrylate or methacrylate having at least two hydroxyl (OH) groups and an acrylate or methacrylate group; another acrylate or methacrylate having an OH or amino group; and one of: i) a sulfonate or sulfonic acid having one amino group; ii) a combination of i and a compound including a carboxylic group and an OH or amino group; iii) a combination of i and a homopolymer or copolymer of poly(ethylene glycol) having one or two OH or amino groups at one chain end; or iv) a combination of i, a compound including a carboxylic group and an OH or amino group, and a homopolymer or copolymer of poly(ethylene glycol) having one or two OH or amino groups at one chain end.

The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. The present disclosure further provides an article and methods thereof.

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.