Disclosed and claimed herein are radiation curable compositions for coating an optical fiber containing an oligomer, a diluent, a photoinitiator, and optionally, additives. The oligomer includes a reactive urethane oligomer having at least three arms, each arm having a most distal termination point and bound together at a single junction point, wherein at least one arm comprises the reaction product of a polyol, a polyisocyanate, and an isocyanate-reactive (meth)acrylate. The reactive urethane oligomer possesses specified molecular weight and/or average functionality values, and it may possess specified chain length values between the oligomer junction point and the distal termination point along one or more arm(s). Also disclosed are methods of coating an optical fiber incorporating the compositions described herein, along with the coated optical fibers and cables produced therefrom.

A prepolymer with multiple functional groups is disclosed. The embodiments of the prepolymer may have the compound of formula X:

##STR00001##

A polymerizable liquid comprising such prepolymer that can be used for producing three-dimensional objects by methods of additive manufacturing and the method using such polymerizable liquid to form three-dimensional objects is also described.

Provided is a curable composition including a urethanization reaction product of: a branched polyolefin diol; at least one selected from an isocyanurate product, an adduct product, and a biuret product, of an aliphatic diisocyanate having 6 to 10 total carbon atoms; and a hydroxy saturated C.sub.1 to C.sub.4 alkyl (meth)acrylate. Also provided are a method for producing the curable composition, and a specific curable compound included in the curable composition.

A resin composition for coating an optical fiber is a resin composition comprising: a base resin containing an oligomer comprising urethane (meth)acrylate, a monomer, and a photopolymerization initiator; and hydrophobic zirconium oxide, wherein the content of the zirconium oxide is 0.5% by mass or more and 65% by mass or less based on the total amount of the resin composition.

Provided are a composition for forming a polyurethane resin used for a membrane sealing material, the composition having low viscosity and contributing to the formation of a membrane sealing material having reduced elution of low-molecular weight reaction products; and a membrane sealing material and a membrane module using this composition. Disclosed is a composition for forming a polyurethane resin used for a membrane sealing material, the composition including a base agent (A) and a curing agent (B), wherein the base agent (A) comprises an isocyanate group-terminated prepolymer (A1), the isocyanate group-terminated prepolymer (A1) is a reaction product between an isocyanate group-containing compound (a1) and an active hydrogen-containing compound (a2), the base agent (A) comprises diphenylmethane diisocyanate, the monomer content of the diphenylmethane diisocyanate is 35% by mass or less, and the curing agent (B) comprises a compound (b1) represented by Formula (1). In Formula (1), R represents an alkyl group having 2 or more carbon atoms. ##STR00001##

A method for producing a polyurethane according to the present invention including: a first step wherein an epoxy carboxylate compound (X) is obtained by reacting (a) an epoxy compound that includes a halogen atom content of 10 ppm by mass or less, while having only two epoxy groups and no hydroxyl group in each molecule, (b) an unsaturated aliphatic monocarboxylic acid that has an ethylenic unsaturated group in each molecule, while having no aromatic ring, and (c) an aromatic monocarboxylic acid that has no ethylenic unsaturated group in each molecule; and a second step wherein the epoxy carboxylate compound (X) obtained in the first step is reacted with a diisocyanate compound (Y).

The present invention aims to provide an aqueous inkjet ink composition for lamination that can provide various advantages such as reduction of residual solvent, improvement of the printing work environment, prevention of air pollution, and fire safety, enables efficient adaptation to the recent decrease in lot size and increase in product variety, has high versatility that allows use for various types of base film, and enables production of a food packaging container that does not break at least during processes such as transportation and display and can be easily opened without causing the double bag state. The aqueous inkjet ink composition for lamination of the present invention contains a colorant, an alkali-soluble or self-emulsifying aqueous polyurethane resin satisfying the following condition 1, and an aqueous medium: Condition 1: the alkali-soluble or self-emulsifying aqueous polyurethane resin is a reaction product of reaction components including hexamethylene diisocyanate, at least one selected from the group of polyester diol compounds represented by the following formula 1, and an acid group-containing diol compound:

##STR00001##

wherein Xs are each independently a hydrocarbon group represented by —CH.sub.2—CH.sub.2—CH.sub.2—CH.sub.2—CH.sub.2—CH.sub.2— or —CH.sub.2—CH.sub.2—CH(CH.sub.3)—CH.sub.2—CH.sub.2—, and n is an integer of 2 to 20.

The present invention relates to an inkjet composition having 1.0-5.0 mol/kg acryloyl groups comprising: i) photo polymerization reactive compound (M) containing exactly one acryloyl group, ii) photo polymerization reactive compound (N) containing at least two acryloyl groups, iii) radical photoinitiator (R), iv) cyanate ester compound (D) containing at least two cyanate groups and v) cyanate ester curing catalyst (C), wherein (M) is different from (D) and (N) is different from (D),

25-50 mol % of the contained acryloyl groups are provided by the reactive compound (N) and the molar ratio of contained acryloyl groups to contained cyanate groups of compound (D) is 0.30 to 0.95.

Provided is a liquid crystal display element that can be baked at a low temperature when forming a liquid crystal alignment film capable of imparting an alignment regulating property and a pretilt angle developing property via a photoalignment method. Further provided is a liquid crystal display element in which the liquid crystal pretilt angles are highly stable, and display burn-in hardly occurs even due to long usage. Further provided are a vertical liquid crystal alignment film to be used in the liquid crystal display element, and a liquid crystal aligning agent with which it is possible to provide the vertical liquid crystal alignment film. A liquid crystal aligning agent of the present invention contains: component (A), which is a polymer including (A-1) a site having an isocyanate group and/or a blocked isocyanate group and (A-2) a site having photoreactivity; component (B), which is a compound having, in a molecule, at least two functional groups of at least one type selected from the group consisting of an amino group and a hydroxyl group; and an organic solvent.

Provided is a coated granular fertilizer, which includes a granular fertilizer and a resin coat that coats the granular fertilizer, in which the resin coat contains a urethane resin that is a polyaddition product between a polyisocyanate component and a polyol component, the polyisocyanate component includes an aromatic polyisocyanate, and the polyol component includes a castor oil-modified diol, an alkylene diol having 2 to 8 carbon atoms, and a compound having three or more hydroxyl groups.