There is provided a pressure sensitive adhesive composition comprising a polyurethane polymer that comprises the reaction product of a polyisocyanate component and a polyol component. The polyol component has a hydrophilic-lipophilic balance (HLB) less than 10. The polyurethane further comprises 0.5 to 10 wt.-% of hydrophilic polymerized units having an HLB greater than 12, such as a reaction product of a polyethylene glycol polymer. In another embodiment, the polyurethane further comprises pendent ethylenically unsaturated groups. Also described are articles such as laminating tapes and protective films as well as methods of bonding substrates with the pressure sensitive adhesive and laminating tape.

In various embodiments, a resin composition includes a urethane (meth)acrylate, a reactive diluent, and a urethane (meth)acrylate toughener. The urethane (meth)acrylate toughener includes at least one additional polyol having a number average molecular weight Mn of greater than 1,000 g/mol. Cured articles made from the resin composition have an average fracture toughness (K.sub.Ic) value from 1 MPa*m.sup.1/2 to 3 MPa*m.sup.1/2 when measured in accordance with ASTM D5045. Processes for making the resin composition as well as processes using the resin composition are also provided.

The present invention relates to polymerizable compositions which contain components that can be crosslinked both via isocyanurate bonds and by a radical reaction mechanism. The invention further relates to methods by way of which polymers can be produced from said compositions.

The present invention relates to polymerizable compositions which contain components that can be crosslinked both via isocyanurate bonds and by a radical reaction mechanism. The invention further relates to methods by way of which polymers can be produced from said compositions.

A process for producing an object from a precursor comprises the steps of: I) depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; II) depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; III) repeating step II) until the precursor is formed;
wherein the depositing of a free-radically crosslinked resin at least in step II) is effected by exposure and/or irradiation of a selected region of a free-radically crosslinkable resin corresponding to the respectively selected cross section of the object and wherein the free-radically crosslinkable resin has a viscosity (23 C., DIN EN ISO 2884-1) of 5 mPas to 100000 mPas. In the process the free-radically crosslinkable resin comprises a curable component in which NCO groups and olefinic CC double bonds are present, wherein in the curable component the molar ratio of NCO groups to olefinic CC double bonds is in a range from 1:5 to 5:1.

In the process, after step III) step IV) is further performed: IV) treating the precursor obtained after step III) under conditions sufficient to at least partially trimerize to isocyanurate groups NCO groups present in the free-radically crosslinked resin of the obtained precursor to obtain the object.

The invention further relates to the use of a free-radically crosslinkable resin having a viscosity (23 C., DIN EN ISO 2884-1) of 5 mPas to 100000 mPas in an additive manufacturing process, wherein the resin comprises a curable compound having isocyanurate groups, NCO groups and olefinic CC double bonds. The invention finally relates to a polymer obtainable by crosslinking such a resin.

Fiber coatings with low Young's modulus, low fiber pullout force for fibers in the as-drawn state, and small time-dependent increases in pullout force as the fiber ages. The fiber coatings are cured products of coating compositions that include an oligomer formed from an isocyanate, a hydroxy acrylate compound and a polyol. The oligomer includes a polyether urethane acrylate and a di-adduct compound. The reaction mixture used to form the oligomer includes a molar ratio of isocyanate:hydroxy acrylate:polyol of n:m:p, where when p is 2, n is in the range from 3.0 to 5.0 and m is in the range from 1.50n-3 to 2.50n-5. Control of the n:m:p ratio leads to compositions that, when cured, provide coatings and cured products having low Young's modulus, low pullout force on glass, and weak variations with time as the fiber ages.

A process for producing an object from a precursor comprises the steps of: depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; repeating step II) until the precursor is formed; wherein the depositing of a free-radically crosslinked resin at least in step II) is effected by exposure and/or irradiation of a selected region of a free-radically crosslinkable resin corresponding to the respectively selected cross section of the object and wherein the free-radically crosslinkable resin has a viscosity (23 C., DIN EN ISO 2884-1) of 5 mPas to 100000 mPas. In the process the free-radically crosslinkable resin comprises a curable component in which NCO groups and olefinic CC double bonds are present, wherein in the curable component the molar ratio of NCO groups to olefinic CC double bonds is in a range from 1:5 to 5:1.

Provided is a composition having magnetostrictive properties, which contains a component (P): a compound having a polymerizable group, a component (M): a powdery magnetostrictive material, and a component (R): a radical polymerization initiator.

The present disclosure provides coating compositions and cured products formed from the coating compositions. The cured products can be formed at high cure speeds from the coating compositions and feature low Young's modulus, high tear strength, and/or high tensile toughness. The cured products can be used as primary coatings for optical fibers. The primary coatings provide good microbending performance and are resistant to defect formation during fiber coating processing and handling operations. The coating compositions include an oligomer, an alkoxylated monofunctional acrylate monomer, and preferably, an N-vinyl amide compound.

The present invention provides a method for producing an antifouling film having excellent antifouling properties and rubbing resistance. The method for producing an antifouling film of the present invention includes Process (1) of applying a resin to a surface of a substrate; Process (2) of pushing the substrate to a die with the resin in between to form an uneven structure on a surface of the resin; and Process (3) of curing the resin including the uneven structure on the surface thereof to form a polymer layer. The resin contains an antifouling agent that contains a compound containing a perfluoro(poly)ether group. The die includes a surface having undergone release treatment using a release agent containing a compound that contains a perfluoro(poly)ether group, a hydrolyzable group, and a Si atom.