The invention is directed to a toughener for epoxy adhesives, the toughener comprising both soft and rubber units, and may be described as a capped soft-rubber PU toughener. The invention includes the tougheners and methods of making them, as well as adhesives comprising the inventive tougheners, methods of using the tougheners and adhesives comprising them, and cured inventive adhesives and products comprising them.

An object of the present invention is to provide a golf ball having excellent approach spin performance under a dry condition and excellent approach spin performance under a condition that there is grass between the golf ball and the club face. The present invention provides a golf ball comprising a golf ball body and a paint film formed on a surface of the golf ball body, wherein the paint film is composed of at least one layer, and an outermost paint film layer located at the outermost layer of the golf ball contains, as a base resin, a polyurethane obtained by a reaction between (A) a polyisocyanate composition and (B) a polyol composition, (B) the polyol composition contains a urethane polyol as a polyol component, and a loss tangent (tan ) of the outermost paint film layer measured with a dynamic viscoelasticity measuring apparatus under specific conditions has a peak temperature in a range of from 40 C. to 40 C.

A thermoplastic polyurethane is the reaction product of a polybutadiene diol, a polyester diol, and a isocyanate component. The polybutadiene diol has a weight average molecular weight (M.sub.w) of from 200 to 20,000 g/mol. The polyester diol has a melting point of from 40 to 90 C. The reactants allow the thermoplastic polyurethane itself to have a melt flow index measured at 120 C. and 22.6 kg of from 0.1 to 200 grams, per 10 minutes as measured according to ASTM 1238. The thermoplastic polyurethane also has a melting point of from 50 to 300 C. The theiinoplastic polyurethane is used to form a composite article.

A two-component polyurethane composition includes a first component, including at least one polybutadiene polyol P1 having an average molecular weight of 2,000 to 10,000 g/mol and an average OH functionality of 2.1 to 4, and a second component, including at least one polyisocyanate and optionally at least one isocyanate-terminated polyurethane prepolymer. The composition also contains at least one hydrophobic diol P2 having an average molecular weight of 500 to 5,000 g/mol, selected from polybutadiene diols, polyester diols, polycarbonate diols, polyether diols having a repeat unit having at least 4 C atoms, and/or at least one hydrophobic compound P3, which is terminated with amino groups and has an average molecular weight in the range of 200 to 2,000 g/mol. The ratio of the number of hydroxyl groups from P1 to the number of hydroxyl and primary and secondary amino groups from P2 and P3 is 2:1 to 16:1.

A two-component polyurethane composition includes a first component, including at least one polybutadiene polyol P1 having an average molecular weight of 2,000 to 10,000 g/mol and an average OH functionality of 2.1 to 4, and a second component, including at least one polyisocyanate and optionally at least one isocyanate-terminated polyurethane prepolymer. The composition also contains at least one hydrophobic diol P2 having an average molecular weight of 500 to 5,000 g/mol, selected from polybutadiene diols, polyester diols, polycarbonate diols, polyether diols having a repeat unit having at least 4 C atoms, and/or at least one hydrophobic compound P3, which is terminated with amino groups and has an average molecular weight in the range of 200 to 2,000 g/mol. The ratio of the number of hydroxyl groups from P1 to the number of hydroxyl and primary and secondary amino groups from P2 and P3 is 2:1 to 16:1.

A two-component polyurethane composition made of a polyol component and a polyisocyanate component, wherein the polyol component includes at least one reaction product of castor oil with ketone resins A1, at least one aliphatic triol A2, an aliphatic diol A3, and a polybutadiene polyol A4. The polyurethane composition has high strength and only a minor dependence of mechanical properties, especially of strength, on temperature, especially in the range from 60 C. to +60 C. Moreover, the composition is capable of curing without blistering under ambient conditions, even in the presence of substrates that typically promote foaming reactions owing to the presence of residual moisture, for example glass fiber weave.

One-component epoxy adhesives containing a phosphorus-modified epoxy resin, a toughener and an epoxy resin that is neither rubber-modified nor phosphorus-modified. These adhesives are structural adhesives useful in automotive applications. They exhibit particularly good corrosion resistance.

A method of bonding substrates having different coefficients of thermal expansion, especially in the shell construction of modes of transport or white goods, using a one-component thermosetting epoxy resin composition containing toughness improvers based on terminally blocked polyurethane prepolymers.

Provided is a two-component-curable polyurethane resin composition that has high compatibility, high adhesion, and a good low-dielectric-constant characteristic.

A two-component-curable polyurethane resin composition according to an embodiment includes a first component including a polyol and a terpene resin, and a second component including a polyisocyanate, wherein the polyol includes 30 mass % or more of a polybutadiene polyol and/or a hydrogenated polybutadiene polyol, and a content of the terpene resin relative to 100 parts by mass of the polyol is 1 to 60 parts by mass.

A thermosetting epoxy resin composition including, as curing agent, a dihydrazide selected from the group consisting of glutaric dihydrazide, adipic dihydrazide and pimelic dihydrazide, in combination with a specific urea accelerator, which features good storage stability and a low curing temperature. The epoxy resin composition is especially suitable for use as bodywork adhesive.