A vat resin for three-dimensional stereolithography printing of a thiourethane polymer part comprising a liquid mixture including a first type of monomer, a second type of monomer, a photolatent base decomposable upon exposure to a light to form a non-nucleophillic base catalyst having a pKa greater than 7, an anionic step-growth polymerization reaction inhibitor having an acidic group configured to form an acid-base pair with the non-nucleophillic base and a light absorber having an absorbance in the liquid mixture that is greater than an absorbance of the photolatent base at a wavelength of the light used for the exposure. Methods of preparing the vat resin and three-dimensional stereolithography printing a thiourethane polymer part using the vat resin are also disclosed.

The present invention provides a laminate 10 including: a foamed polyurethane layer 11 obtained from a foamable polyurethane resin composition containing an active hydrogen group-containing tin ricinoleate and a phosphorus-containing solid flame retardant; and a coating layer 15 adhered to the foamed polyurethane layer 11 by a polyurethane hot melt adhesive 13 containing a polyurethane prepolymer (I) obtained by using a polyol component (A) and a polyisocyanate component (B) as raw materials, and a catalyst (II).

A cationic curing agent includes porous particles and a compound represented by General Formula (1), where the compound is held in the porous particles.

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In the General Formula (1), R.sup.1 is an alkyl group having 1 to 18 carbon atoms or a phenyl group, where the alkyl group may be branched and the alkyl group and the phenyl group may each further have a substituent. R.sup.2 is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms where the alkyl group may be branched, a halogenoalkyl group, an alkoxy group, or a phenoxy group; where the alkyl group, the halogenoalkyl group, the alkoxy group, or the phenoxy group may further have a substituent. R.sup.1 and R.sup.2 may be identical to or different from each other.

A method of three-dimensional stereolithography printing a thiourethane polymer part using the vat resin. Adding a resin to a vat of a three-dimensional stereolithography printer, the resin a liquid mixture including: a first type of monomer including two or more thiol functional groups, a second type of monomer including two or more isocyanate functional groups, a photolatent base, an anionic step-growth polymerization reaction inhibitor and a light absorber. The photolatent base is decomposable upon exposure to a light to form a non-nucleophillic base catalyst having a pKa greater than 7. The anionic step-growth polymerization reaction inhibitor has an acidic group configured to form an acid-base pair with the non-nucleophillic base. The light absorber has an absorbance in the liquid mixture that is greater than an absorbance of the photolatent base at a wavelength of the light used for the exposure.

A polyurethane composition is provided. The polyurethane composition comprises (A) one or more polyurethane-prepolymers prepared by reacting at least one polyisocyanate compound with a first polyol component; and (B) a second polyol component; wherein at least one of the first polyol component and the second polyol component comprises an ester/ether block copolymer polyol synthesized by reacting a starting material polyether polyol with a C.sub.4-C.sub.20 lactone. The polyurethane foam prepared by using the polyurethane composition can achieve inhibited internal heat buildup, high thermal stability and superior tear strength. A polyurethane product prepared with said foam, a method for preparing the polyurethane foam and a method for improving the performance property of the polyurethane foam are also provided.

Provided is an electrophotographic electroconductive member, including: an electroconductive support; an electroconductive layer; and a surface layer in order, wherein an impedance is 1.0×10.sup.3Ω to 1.0×10.sup.8Ω at an outer surface of the electroconductive member, in the surface layer, an electronic electroconductive agent is dispersed, the electroconductive layer has a matrix containing a cross-linked product of a first rubber and domains each containing a cross-linked product of a second rubber and electroconductive particles, and wherein, and wherein among the domains observed in specified observation regions, 80% by number or more of the domains satisfy (1) and (2): (1) a proportion of sectional areas of the electroconductive particles with respect to the domain is 20% or more; (2) A/B is 1.00 to 1.10 when A is a perimeter of the domain and B is an envelope perimeter.

Described herein are binder formulations based on acryloyloxy-functionalized polyurethanes.

A method for producing a prepolymer for the production of an integral polyurethane foam is provided. The prepolymer is or can be obtained by reaction of a composition that contains the following components: component A containing a polyoxymethylene-polyoxyalkylene block copolymer having a hydroxyl number of 20 mg KOH/g to 200 mg KOH/g as component Al, component B containing di- and/or polyisocyanates with an NCO content of 15 to 45 wt.-% relative to component B, 0.04 to 1.0 wt.-%, relative to the composition, a proton acid as component C, and optionally a component D that contains auxiliary agents, at a characteristic number of 450 to 850. The invention further relates to the prepolymer obtained by the method, to an integral polyurethane foam based on the prepolymer, and to the use thereof.

Phenyl isocyanates are removed from a solvent stream obtained from an MDI and/or PMDI manufacturing process by reaction in the presence of a carbodiimidization catalyst to form the corresponding N,N-diphenylcarbodiimides. The N,N-diphenylcarbodiimides can be recycled into the MDI and/or PMDI manufacturing process where they can react with MDI and/or PMDI to form uretonimines. The uretonimines have at most minimal effect on the properties and usefulness of the MDI and/or PMDI product and so can be left in the MDI and/or PMDI product.

A curable composition is provided, comprising: (A) a binder composition; and (B) a polysiloxane resin comprising aromatic functional groups and terminal active hydrogen groups. The composition may be used to prepare articles of manufacture and coated articles, such as footwear components. The composition may additionally be used to mitigate dirt build-up on a substrate.