The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes at least one urethane component, at least one monofunctional reactive diluent, an initiator, and optionally an inhibitor. The present disclosure also provides an article including the reaction product of the photopolymerizable composition. Further, the present disclosure provides a method of making an article. The method includes (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

The present disclosure relates to polyurethane based switchable adhesives. In at least one embodiment, a switchable adhesive composition comprises an adhesive component, which is formed from at least one isocyanate and a material or materials capable of undergoing cross-linking with isocyanate other than by free radical polymerization.

The present invention relates to curable compositions, in particular, thiol-ene-curing compositions, a method of coating using said curable compositions, cured compositions obtained by curing said curable compositions, cured articles, comprising said cured compositions, a certain compound comprising olefinically unsaturated functional groups and a silyl functional group for use in said curable compositions and a method of manufacturing the curable compositions.

Provided is a two-component adhesive that includes a first composition and a second composition, in which the first composition contains: a complex derived from an organoborane and a first compound having a first group capable of undergoing an addition reaction to an isocyanate group; and as a diluent, a second compound not having a polymerizable group, the second composition containing: a third compound having an isocyanate group and a polymerizable group; and a dehydrating agent. The first composition preferably does not substantially contain a compound having a polymerizable group.

The invention provides reactive resins compounds and compositions made from renewable materials, such as plant and animal oils. The reactive resins compounds and compositions may include an accelerator as part of their structure and are made from renewable materials containing a variety of functional groups. The compositions provide excellent adhesion and sealing capability.

An adhesive composition including a resin and electro-conductive material, wherein the electro-conductive material is an ammonium salt of fluorosulfonic acid having 5 or more carbon atoms shown by the general formula (1): (R.sup.1XZSO.sub.3.sup.).sub.n M.sup.n+ (1), wherein, R.sup.1 represents a monovalent hydrocarbon group having 1 to 40 carbon atoms and optionally substituted by a heteroatom or optionally interposed by heteroatom; X represents any of a single bond, ether group, ester group, and amide group; Z represents an alkylene group having 2 to 4 carbon atoms, containing 1 to 6 fluorine atoms, and optionally containing a carbonyl group; M.sup.n+ represents a cation having one or two ammonium cation structures. This can form a living body contact layer for a bio-electrode with excellent electric conductivity, biocompatibility, and light weight, which manufactures at low cost and does not cause large lowering of the electric conductivity even when it is wetted with water or dried.

The present invention is a radically curable organosiloxane graft polyvinyl alcohol polymer having structural units represented by both of the following general formula (1) and general formula (2). The present invention provides a radically curable organosiloxane graft polyvinyl alcohol polymer having general properties such as film-forming property and transparency, excellent handleability as a liquid material since solubility in an organic solvent is high, and both of solvent resistance and moldability of the obtained film. ##STR00001##

Provided is a rubber composition containing from 1 to 50 parts by mass of an organic microparticle having an average particle size of 0.001 to 100 m and having a crosslinked structure per 100 parts by mass of a diene rubber, the organic microparticle being a crosslinked microparticle of a copolymer formed from at least two types of segments having repeating units that are different each other, the at least two types of segments being formed from an oligomer or prepolymer having a functional group and having a molecular weight of 500 to 20000, and the functional group forming a crosslinked structure between the at least two types of segments.

The present invention provides a silicone hydrogel composition. The silicone hydrogel composition includes a water-soluble silicone macromere, a hydrophilic monomer, a crosslinker, an initiator and an organic solvent. The water-soluble silicone macromere, the hydrophilic monomer, the crosslinker and the initiator is respectively in the amount of 50-80 wt %, 19-50 wt %, 0.1-1.5 wt % and 0.1-1 wt % based on the total weight of the silicone hydrogel composition.

Disclosed is a terminally functionalized polysiloxane urethane polymer comprising: polysiloxane segments comprising from 50 to 98% by weight based on the total polymer weight; urethane segments comprising from 2 to 50% by weight based on the total polymer weight; and terminal functional groups selected from (meth)acrylate functional groups, alkoxysilyl functional groups and mixtures thereof. The terminally functionalized polysiloxane urethane polymer finds use in liquid optically clear adhesive formulations wherein it can provide dual photo and moisture cure properties. In some embodiments cured reaction products of the liquid optically clear adhesive composition prepared with the terminally functionalized polysiloxane urethane polymer exhibit low haze of 2% or less and low yellowness b* values of 2 or less as prepared and after aging testing. In some embodiments cured reaction products of the liquid optically clear adhesive composition prepared with the terminally functionalized polysiloxane urethane polymer exhibit minimal shrinkage and a stable compression storage modulus from 40 to 100 C.