C08G59/58

Insulating heat dissipation coating composition and insulating heat dissipation unit formed using the same

An insulating heat dissipation coating composition including a coating layer-forming component including a subject resin, and an insulating heat dissipation filler. Therefore, the coating composition may have excellent thermal conductivity and excellent thermal emissivity, and therefore an insulating heat dissipation coating layer which exhibits excellent heat dissipation performance and has insulating property may be formed. In addition, the heat dissipation coating layer formed thereby has a very excellent adhesive strength to a surface to be coated so as to significantly prevent peeling of the coating layer during use, and to maintain durability of the coating layer even against a physical or chemical stimulus such as external heat, organic solvent, moisture or shock, which is generated after the coating layer is formed.

Insulating heat dissipation coating composition and insulating heat dissipation unit formed using the same

An insulating heat dissipation coating composition including a coating layer-forming component including a subject resin, and an insulating heat dissipation filler. Therefore, the coating composition may have excellent thermal conductivity and excellent thermal emissivity, and therefore an insulating heat dissipation coating layer which exhibits excellent heat dissipation performance and has insulating property may be formed. In addition, the heat dissipation coating layer formed thereby has a very excellent adhesive strength to a surface to be coated so as to significantly prevent peeling of the coating layer during use, and to maintain durability of the coating layer even against a physical or chemical stimulus such as external heat, organic solvent, moisture or shock, which is generated after the coating layer is formed.

Low temperature anhydride epoxy cured systems

A curing agent composition comprising anhydride and approximately equimolar amount of tertiary amine or imidazole and carboxylic acid, the amine being 1-piperidinylethanol (N-hydroxyethyl-piperidine, NHEP) represented by the structure below or an imidazole represented by the structure below: ##STR00001##
where R.sub.1=H, a C1-C20 straight chain or branched alkyl, or a monocyclic aryl; R.sub.2=a C1-C20 straight chain or branched alkyl, or a monocyclic aryl. The carboxylic acid is represented by RCOOH; R=a C1-C20 straight chain or branched alkyl, or a monocyclic aryl. The composition comprises a lower ratio of epoxy resin to anhydride (1:0.4-0.6) than typically used (1:0.8-1.1). In addition, it uses a higher loading of the hindered latent tertiary amine or the imidazole in combination with the carboxylic acid (wt % ratio of combined amine and carboxylic acid to anhydride ˜10%). With this composition a full cure can be achieved in less than 2 hr at a significantly lower temperature (˜100° C.).

Low temperature anhydride epoxy cured systems

A curing agent composition comprising anhydride and approximately equimolar amount of tertiary amine or imidazole and carboxylic acid, the amine being 1-piperidinylethanol (N-hydroxyethyl-piperidine, NHEP) represented by the structure below or an imidazole represented by the structure below: ##STR00001##
where R.sub.1=H, a C1-C20 straight chain or branched alkyl, or a monocyclic aryl; R.sub.2=a C1-C20 straight chain or branched alkyl, or a monocyclic aryl. The carboxylic acid is represented by RCOOH; R=a C1-C20 straight chain or branched alkyl, or a monocyclic aryl. The composition comprises a lower ratio of epoxy resin to anhydride (1:0.4-0.6) than typically used (1:0.8-1.1). In addition, it uses a higher loading of the hindered latent tertiary amine or the imidazole in combination with the carboxylic acid (wt % ratio of combined amine and carboxylic acid to anhydride ˜10%). With this composition a full cure can be achieved in less than 2 hr at a significantly lower temperature (˜100° C.).

Curable epoxy resin composition, fiber-reinforced composite material and molded body using same

Provided is a resin composition that has satisfactory impregnability into reinforcing fibers due to low viscosity and small viscosity increase even in an impregnation process performed for a long time. The resin composition being suitable as a matrix resin for a fiber-reinforced composite material for producing a cured molded article that has toughness and fatigue resistance. The resin composition for a fiber-reinforced composite material includes an epoxy resin, an acid anhydride-based curing agent, an imidazole-based curing accelerator, a radically polymerizable monomer, and a radical polymerization initiator as essential components, has a viscosity at 25° C. that falls within a range of 50 mPa.Math.s to 800 mPa.Math.s as measured by an E-type viscometer, and exhibits a viscosity increase ratio of 200% or less after 8 h at 25° C., wherein 50% by mass or more of the acid anhydride-based curing agent is an alicyclic acid anhydride having no olefinic unsaturated bond.

Curable epoxy resin composition, fiber-reinforced composite material and molded body using same

Provided is a resin composition that has satisfactory impregnability into reinforcing fibers due to low viscosity and small viscosity increase even in an impregnation process performed for a long time. The resin composition being suitable as a matrix resin for a fiber-reinforced composite material for producing a cured molded article that has toughness and fatigue resistance. The resin composition for a fiber-reinforced composite material includes an epoxy resin, an acid anhydride-based curing agent, an imidazole-based curing accelerator, a radically polymerizable monomer, and a radical polymerization initiator as essential components, has a viscosity at 25° C. that falls within a range of 50 mPa.Math.s to 800 mPa.Math.s as measured by an E-type viscometer, and exhibits a viscosity increase ratio of 200% or less after 8 h at 25° C., wherein 50% by mass or more of the acid anhydride-based curing agent is an alicyclic acid anhydride having no olefinic unsaturated bond.

EPOXY RESIN COMPOSITION, FIBER REINFORCED MATERIAL, MOLDED ARTICLE, AND PRESSURE VESSEL

An epoxy resin composition comprises components [A] to [C]. The component [C] is a component [c1] or [c2] and the rubbery state elastic modulus of a cured article produced by curing the epoxy resin composition in a dynamic viscoelasticity evaluation is 10 MPa or less. Component[A] is a phenyl glycidyl ether substituted by a tert-butyl group, a sec-butyl group, an isopropyl group or a phenyl group. Component [B] is a bifunctional or higher aromatic epoxy resin. Component [C] is a curing agent selected from component [c1], which is an acid anhydride-type curing agent and component [c2], which is an aliphatic amine-type curing agent.

EPOXY RESIN COMPOSITION, FIBER REINFORCED MATERIAL, MOLDED ARTICLE, AND PRESSURE VESSEL

An epoxy resin composition comprises components [A] to [C]. The component [C] is a component [c1] or [c2] and the rubbery state elastic modulus of a cured article produced by curing the epoxy resin composition in a dynamic viscoelasticity evaluation is 10 MPa or less. Component[A] is a phenyl glycidyl ether substituted by a tert-butyl group, a sec-butyl group, an isopropyl group or a phenyl group. Component [B] is a bifunctional or higher aromatic epoxy resin. Component [C] is a curing agent selected from component [c1], which is an acid anhydride-type curing agent and component [c2], which is an aliphatic amine-type curing agent.

THERMALLY CURING ADHESIVE AND ADHESIVE TAPE PRODUCED THEREFROM

An adhesive, more particularly a thermally curable, meltable, preferably pressure-sensitive adhesive, which is curable thermally from a temperature of 110 C., is storage-stable for approximately one month at 60 C. and longer than one year at 23 C., and an adhesive tape produced therefrom, comprising an epoxide-functionalized acrylonitrile/butadiene copolymer having on average more than 1.5 epoxide groups per molecule, and the ground reaction product of phthalic anhydride and diethylenetriamine, for use in the automotive industry both in bodyshell construction on oiled metal sheets and in the coating line on cathodically electrocoated or otherwise-coated metal sheets, for bonding and/or sealing, for example for hem fold bonding, for hem fold sealing, for seam sealing, for underseal bonding, for hole stopping, and much more.

Electrical device comprising a cross-linked layer

An electrical device includes at least one cross-linked layer obtained from a polymer composition that has: at least one polymer comprising one or more epoxy function(s), and at least one cross-linking agent. The cross-linking agent is selected from: a non-aromatic cyclic amine, an imidazole of formula (I)

##STR00001##

where R.sub.1 and R.sub.2 independently represent a hydrogen atom or a hydrocarbon group, R.sub.3 and R.sub.4 independently represent a hydrogen atom or a hydrocarbon group, or R.sub.3 and R.sub.4 form, together with the carbon atoms of the imidazole ring to which they are attached, a ring, with the imidazole being associated with a cross-linking co-agent having at least one reactive function capable of reacting with the epoxy function of said polymer, and, a mixture thereof.