The present invention relates to a method for producing a biopolyether polyol, which is a copolymerization reaction of tetrahydrofuran and 2-methyltetrahydrofuran in a monomer ratio (by mass) of 85/15 to 50/50, and the resulting polyether polyol of 100% plant origin having a number-average molecular weight of 500-5000. In addition, a polyurethane resin, which is the product of a synthetic reaction having as the main reactants the above polyether polyol of 100% plant origin, a polyisocyanate compound, and a chain extender that reacts with isocyanate groups, has a change in storage modulus (E) in the low temperature range (0 C.) with respect to normal temperature (20 C.) of within 0-15%.

The present invention relates to a method for producing a biopolyether polyol, which is a copolymerization reaction of tetrahydrofuran and 2-methyltetrahydrofuran in a monomer ratio (by mass) of 85/15 to 50/50, and the resulting polyether polyol of 100% plant origin having a number-average molecular weight of 500-5000. In addition, a polyurethane resin, which is the product of a synthetic reaction having as the main reactants the above polyether polyol of 100% plant origin, a polyisocyanate compound, and a chain extender that reacts with isocyanate groups, has a change in storage modulus (E) in the low temperature range (0 C.) with respect to normal temperature (20 C.) of within 0-15%.

The present disclosure relates to a curable precursor of a structural adhesive composition, comprising: a) a cationically self-polymerizable monomer; b) a polymerization initiator of the cationically self-polymerizable monomer which is initiated at a temperature T1; c) a curable monomer which is different from the cationically self-polymerizable monomer; and d) a curing initiator of the curable monomer which is initiated at a temperature T2 and which is different from the polymerization initiator of the cationically self-polymerizable monomer. According to another aspect, the present disclosure is directed to a partially cured precursor of a structural adhesive composition. According to still another aspect, the present disclosure relates to a method of bonding to parts. In yet another aspect, the disclosure relates to the use of a curable precursor or a partially cured precursor as described above, for industrial applications, in particular for body-in-white bonding applications for the automotive industry.

The present disclosure relates to a curable precursor of a structural adhesive composition, comprising: a) a cationically self-polymerizable monomer; b) a polymerization initiator of the cationically self-polymerizable monomer which is initiated at a temperature T1; c) a curable monomer which is different from the cationically self-polymerizable monomer; and d) a curing initiator of the curable monomer which is initiated at a temperature T2 and which is different from the polymerization initiator of the cationically self-polymerizable monomer. According to another aspect, the present disclosure is directed to a partially cured precursor of a structural adhesive composition. According to still another aspect, the present disclosure relates to a method of bonding to parts. In yet another aspect, the disclosure relates to the use of a curable precursor or a partially cured precursor as described above, for industrial applications, in particular for body-in-white bonding applications for the automotive industry.

The present disclosure is directed to a thermoplastic composition. The thermoplastic composition comprises: a) a copolyether-ester; b) an ethylene acrylic copolymer as defined; and c) aluminum trihydrate (ATH), present in an amount of at least 40% by weight of the thermoplastic composition; wherein the weight ratio of the copolyether-ester to the ethylene acrylic copolymer in the thermoplastic composition ranges from 98:2 to 65:35. The present disclosure is also directed to a wire or cable jacket formed from the thermoplastic composition.

The present disclosure is directed to a thermoplastic composition. The thermoplastic composition comprises: a) a copolyether-ester; b) an ethylene acrylic copolymer as defined; and c) aluminum trihydrate (ATH), present in an amount of at least 40% by weight of the thermoplastic composition; wherein the weight ratio of the copolyether-ester to the ethylene acrylic copolymer in the thermoplastic composition ranges from 98:2 to 65:35. The present disclosure is also directed to a wire or cable jacket formed from the thermoplastic composition.

The invention relates to inorganic-organic hybrid materials comprising interpenetrated organic and inorganic components, wherein the organic component comprises polymer chains formed at least in part by ring-opening polymerization of a cyclic monomer, and processes for the production thereof.

The invention relates to inorganic-organic hybrid materials comprising interpenetrated organic and inorganic components, wherein the organic component comprises polymer chains formed at least in part by ring-opening polymerization of a cyclic monomer, and processes for the production thereof.

The efficient production of poly(tetramethylene ether) diacetate [PTMEA] or other diesters, from tetrahydrofuran [THF] is obtained utilizing an acid-based catalyst that is based on a morphologically reconfigured and Bronsted acidity enhanced halloysite derived from a preparation method of using naturally occurring halloysites. More specifically, the method relates to morphological modification of the internal pore structure of halloysites via supercritical carbon dioxide treatment directly applied onto the raw halloysite minerals, that yields highly synergistic and reproducible results of elimination of inaccessible and detrimental extra-small pores. PTMEA is readily converted to poly(tetramethylene ether) glycol (PTMEG) by a transesterification reaction

The efficient production of poly(tetramethylene ether) diacetate [PTMEA] or other diesters, from tetrahydrofuran [THF] is obtained utilizing an acid-based catalyst that is based on a morphologically reconfigured and Bronsted acidity enhanced halloysite derived from a preparation method of using naturally occurring halloysites. More specifically, the method relates to morphological modification of the internal pore structure of halloysites via supercritical carbon dioxide treatment directly applied onto the raw halloysite minerals, that yields highly synergistic and reproducible results of elimination of inaccessible and detrimental extra-small pores. PTMEA is readily converted to poly(tetramethylene ether) glycol (PTMEG) by a transesterification reaction