C08G65/266

Treatment of aqueous mineral suspensions with polymeric flocculants

The present invention relates to a method of dewatering an aqueous mineral suspension comprising introducing into the suspension a flocculating system comprising a poly(ethylene oxide) copolymer, in particular a copolymer of ethylene oxide and one or more epoxy or glycidyl ether functionalized hydrophobic monomer. Said poly(ethylene oxide) copolymers are useful for the treatment of suspensions of particulate material, especially waste mineral slurries. The invention is particularly suitable for the treatment of tailings and other waste material resulting from mineral processing, in particular, the processing of oil sands tailings.

Lewis acid polymerization catalyst

A Lewis acid polymerization catalyst has a general formula M(R.sup.1).sub.1(R.sup.2).sub.1(R.sup.3).sub.1(R.sup.4).sub.0 or 1, whereas M is boron, R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are each independent, R.sup.1 is a 3,5-bis(trifluoromethyl)-substituted phenyl group, R.sup.2 is the 3,5-bis(trifluoromethyl)-substituted phenyl group or a first fluoro-substituted phenyl group selected from Set 1 structures, R.sup.3 is independently a second fluoro-substituted phenyl group selected from the Set 1 structures, and optional R.sup.4 includes a third functional group or functional polymer group.

PROCESS OF MANUFACTURING POLYOLS

A method of producing a polyether polyol that includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R.sup.1)1(R.sup.2)1(R.sup.3)1(R.sup.4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R.sup.1, R.sup.2, and R.sup.3 each includes a same fluoroalkyl-substituted phenyl group, and optional R.sup.4 includes a functional group or functional polymer group. R.sup.1, R.sup.2, and R.sup.3 are the same fluoroalkyl-substituted phenyl group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.

Spirocentric compounds and polymers thereof

The present invention is directed to novel functionalized spirocentric compounds and polymers thereof that produce hyper-rigid cross-linked membranes.

Functionalized membranes and methods of production thereof

The present invention is directed to methods of fabricating novel cross-linked membranes and to cross-linked membranes produced by the disclosed methods. Specifically, methods of fabricating cross-linked membranes according to the present invention may comprise direct crosslinking, crosslinking by addition of a small molecule, interfacial crosslinking of free-standing film, and interfacial crosslinking on a solid support.

Use of additives for increasing the tensile shear strength and composition containing a silane-functionalized prepolymer and additives
11059953 · 2021-07-13 · ·

The present invention relates to a compound of the formula (I) ##STR00001##
for improving the tensile shear strength of hardened compositions based on silane-modified prepolymers, a composition containing a silane-functionalized prepolymer and a compound of the formula (I), a method for the production of this composition and the use of the compound of the formula (I) in adhesives, sealants, coatings and/or primers, based on silane-functionalized prepolymers and the use of this compound for the production of adhesives, sealants, coatings and/or primers based on silane-functionalized prepolymers.

Method for producing polyether carbonate polyols

The invention relates to a method for producing polyether carbonate polyols by adding alkylene oxides and carbon dioxide to an H-functional starter substance in the presence of a double metal cyanide (DMC) catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein () alkylene oxide and carbon dioxide are added to an H-functional starter substance in a reactor with a total pressure (absolute) of 5 to 120 bar in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, and a reaction mixture containing the polyether carbonate polyol is obtained, () the reaction mixture obtained in step () remains in the reactor or is optionally continuously transferred to a downstream reactor at a starting total pressure (absolute) of 5 to 120 bar, the content of free alkylene oxide in the reaction mixture being reduced in the course of a downstream reaction in each case, and the total pressure (absolute) can be reduced by up to 50% during the step (), and () the content of highly volatile components of the obtained reaction mixture is thermally reduced at a temperature of 80 C. to 200 C. The invention is characterized in that () the reaction mixture resulting from step () is brought to a total pressure (absolute) of 2.0 bar, preferably 0.5 bar to 2.0 bar, particularly preferably 0.9 bar to 1.1 bar, prior to step () and then left at a temperature of 80 to 180 C. for a dwell time of at least 0.5 h. After the dwell time has expired, 5 to 100 ppm of component K is added to the resulting mixture, component K being selected from at least one compound which contains a phosphorus-oxygen-hydrogen group.

PROCESS OF MANUFACTURING POLYOLS

A method of producing a polyether polyol includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, and the low molecular weight initiator has a nominal hydroxyl functionality at least 2. The polymerization catalyst is a Lewis acid catalyst having the general formula M(R.sup.1).sub.1(R.sup.2).sub.1(R.sup.3).sub.1(R.sup.4)0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are each independent, R.sup.1 includes a fluoroalkyl-substituted phenyl group, R.sup.2 incudes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, R.sup.3 includes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, and optional R.sup.4 includes a functional group or functional polymer group, R.sup.1 being different from at least one of R.sup.2 and R.sup.3.

Hybrid materials and process for production thereof

The invention relates to inorganic-organic hybrid materials comprising interpenetrated organic and inorganic components, wherein the organic component comprises polymer chains formed at least in part by ring-opening polymerization of a cyclic monomer, and processes for the production thereof.

PROCESS OF MANUFACTURING SURFACTANTS AND LUBRICANTS

A method of producing an alcohol ethoxylate surfactant or lubricant, the method including reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a nominal hydroxyl functionality at least 1, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R.sup.1).sub.1(R.sup.2).sub.1(R.sup.3).sub.1(R.sup.4).sub.0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are each independent, R.sup.1 includes a first fluoroalkyl-substituted phenyl group, R.sup.2 includes a second fluoroalkyl-substituted phenyl group or a first fluoro/chloro-substituted phenyl group, R.sup.3 includes a third fluoroalkyl-substituted phenyl group or a second fluoro/chloro-substituted phenyl group, and optional R.sup.4 includes a functional group or functional polymer group, R.sup.1 being different from at least one of R.sup.2 and R.sup.3. The method further including forming an alcohol ethoxylate surfactant or lubricant having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.