Provided are a modified polyether polyol and the use thereof in polyurethane foam materials. The method for preparing a modified polyether polyol comprises the following steps: 1) reacting a compound A with a polyether polyol, wherein the compound A is an anhydride and/or dicarboxylic acid compound containing a polymerizable double bond, preferably selected from one or two of maleic anhydride and itaconic anhydride, preferably maleic anhydride; and 2) reacting the product obtained in step 1) with an epoxy compound containing a polymerizable double bond in the presence of a catalyst, in order to prepare the modified polyether polyol. The modified polyether polyol obtained by means of the preparation method has more active sites, uses the polymerizable double bond for blocking, is used as a dispersion stabilizer for the synthesis of copolymer polyols, and has the characteristics of a better dispersion stability, filterability and a low viscosity.

A fluoropolyether group-containing compound of formula (1) or (2):

##STR00001##

wherein R.sup.F1, R.sup.X1, R.sup.X2 and R.sup.Si are as defined herein.

Provided herein are polymeric α-hydroxy aldehyde or α-hydroxy ketone reagents which can be conjugated to amine-containing compounds to form stable conjugates in a single-step reaction. In selected embodiments, the polymeric reagent itself incorporates an internal proton-abstracting (basic) functional group, to promote more efficient reaction. The substituent is appropriately situated, via a linker if necessary, to position the group for proton abstraction, preferably providing a 4- or 5-bond spacing between the abstracting atom and the hydrogen atom on the α-carbon. Also provided are methods of using the reagents and stable, solubilized conjugates of the reagents with biologically active compounds. In preferred embodiments, the polymeric component of the reagent or conjugate is a polyethylene glycol.

The present invention provides, among other things, methods for preparing functionalized and other polymers from polymer alcohols such as poly(ethylene glycol)s. In addition, polymer compositions, conjugates, polymeric reagents, are also provided.

The present invention relates to copolymers comprising recurring units derived from (per) fluoropolyether polymers, and to their use in coatings, surface treatments and as additives in polymer composites and coating compositions

Provided are a modified polyether polyol and the use thereof in polyurethane foam materials. The method for preparing a modified polyether polyol comprises the following steps: 1) reacting a compound A with a polyether polyol, wherein the compound A is an anhydride and/or dicarboxylic acid compound containing a polymerizable double bond, preferably selected from one or two of maleic anhydride and itaconic anhydride, preferably maleic anhydride; and 2) reacting the product obtained in step 1) with an epoxy compound containing a polymerizable double bond in the presence of a catalyst, in order to prepare the modified polyether polyol. The modified polyether polyol obtained by means of the preparation method has more active sites, uses the polymerizable double bond for blocking, is used as a dispersion stabilizer for the synthesis of copolymer polyols, and has the characteristics of a better dispersion stability, filterability and a low viscosity.

Provided are a modified polyether polyol and the use thereof in polyurethane foam materials. The method for preparing a modified polyether polyol comprises the following steps: 1) reacting a compound A with a polyether polyol, wherein the compound A is an anhydride and/or dicarboxylic acid compound containing a polymerizable double bond, preferably selected from one or two of maleic anhydride and itaconic anhydride, preferably maleic anhydride; and 2) reacting the product obtained in step 1) with an epoxy compound containing a polymerizable double bond in the presence of a catalyst, in order to prepare the modified polyether polyol. The modified polyether polyol obtained by means of the preparation method has more active sites, uses the polymerizable double bond for blocking, is used as a dispersion stabilizer for the synthesis of copolymer polyols, and has the characteristics of a better dispersion stability, filterability and a low viscosity.

Provided are poly(AAG)-compositions, and corresponding coatings, foams, and coated articles. Also provided are methods for preparing the poly(AAG)-compositions and corresponding reagents including, e.g., polyol-AAG compositions. Coatings using the poly(AAG)-compositions may be useful for, e.g., replacing bisphenol-A cross-linked coatings used in food and beverage containers, coating metal articles, and the like.

A viscosity regulating composition and its method of manufacture. The composition comprises a mixture of (a) a branched polymer having the formula [M]-[(A.sup.1O)-L.sup.1-(A.sup.1O)—R.sup.1].sub.n, wherein M is polybranched hydrophobe; A.sup.1O is a polyoxyalkylene unit; L.sup.1 is an aliphatic linking segment or an aromatic linking segment each having at least two hydroxyl reactive linking groups; and R.sup.1 is an aliphatic end unit or aromatic end unit having 6 to 32 carbon atoms; n ranges from 3 to 6; and (b) a polymer having the formula R.sup.2-(A.sup.2O)-L.sup.2-(A.sup.2O)—R.sup.2, wherein (A.sup.2O) is a polyoxyalkylene unit, L.sup.2 is a aliphatic linking segment or an aromatic linking segment, and R.sup.2 is a aliphatic unit or an aromatic unit each having 6 to 32 carbon atoms.

The present invention provides a surfactant having a formula selected from the group consisting of: B—((X).sub.x—(CH.sub.2).sub.a-A).sub.n(VI), (A-(CH.sub.2).sub.a—(X).sub.x—B—(X).sub.x—(CH.sub.2).sub.a-A).sub.n (IV), (A-(CH.sub.2).sub.a—(X).sub.x—B).sub.n (V), and (B).sub.n—(X).sub.x—(CH.sub.2).sub.a-A (VII), wherein A is a perfluoropolyether; a is a positive integer; X is either a covalent bond or a linking group; x is a positive integer; B is a polyalkylene oxide unit; n is a positive integer greater than 1 and, in compounds comprising more than one A, B, X, a and x, each may be the same or different. The present invention also relates to methods of making such surfactants, uses of such surfactants and emulsions comprising such surfactants.