A resin film having an aromatic polysulfone as a forming material is provided. The resin film has a thickness of less than 100 μm, and further contains an organic compound having a boiling point no lower than 250° C. and no higher than 400° C. The organic compound is contained in an amount of at least 500 ppm and at most 4000 ppm relative to the mass of the aromatic polysulfone.

The present disclosure relates to a method for manufacturing a three-dimensional (3D) object with an additive manufacturing system, comprising a step consisting in printing layers of the three-dimensional object from the part material comprising a polymeric component comprising at least one poly(aryl ether sulfone) (PAES) polymer having a number average molecular weight (Mn) of at least 12,000 g/mol and a polydispersity (PDI) of less than 1.7. The present invention also relates to polymeric filaments comprising such a PAES, as well as to the use of this PAES to prepare filaments and to print 3D objects.

A method of removing metal ions is provided, which includes contacting a metal removal composition with a solution containing metal ions for removing the metal ions from the solution, wherein the metal removal composition includes a polymer with a chemical structure of:

##STR00001##

wherein Q is a quinoline-based group, n=90˜450, o=10˜50, and p=0˜20. The metal removal composition has a type of fiber or film. In addition, the metal removal composition has a porosity of 60% to 90%.

A photoresist composition is provided, which comprises a cationic polymerization resin, a resin A, a photoacid generator, and a solvent, wherein the resin A comprises at least one resin selected from the group consisting of polyester resins and polyether resins and is soluble in a ketone-based organic solvent.

Described here are blocky PEEK copolymers and corresponding synthesis methods. It was surprisingly found that synthesis of blocky PEEK copolymers in a non-solvent environment with respect to PEEK produced blocky PEEK copolymers with high degrees of functionalization and crystallinity. The blocky PEEK copolymers had an increased blocky structure, relative to corresponding PEEK copolymer synthesized with other known methods. Moreover, membranes formed from the blocky PEEK polymers are particularly desirable in fuel cell applications. For example, the membranes formed from the blocky PEEK polymers had surprisingly large ion conductivities as well as significantly improved chemical and thermal resistance, at least in part, to the improved functionalization and crystallinity.

A bio-based poly(arylether sulfone) copolymer (“copolymer b-PAES”) comprises at least two sulfone recurring units derived from two distinct dihydroxy/diol monomers: a bio-compatible and bio-based diol momoner and a bisphenol monomer distinct from Bisphenol S (BPS) and Bisphenol A (BPA). The dihydroxy bisphenol monomer comprises a substituted-phenol bisphenolic compound distinct from BPS and BPA, preferably comprises a bisphenol F derivative with both alkyl substituted-phenol groups. The bio-based diol monomer comprises at least one diol selected from isosorbide, isomannide and/or isoidide. The copolymer b-PAES is preferably free of BPA and BPS. A process for manufacturing such copolymer b-PAES, its use for manufacturing an article, an article made therefrom such as membranes, and a polymer solution for manufacture of membrane comprising such copolymer b-PAES.

Disclosed is a protective layer to protect a lithium metal negative electrode for a lithium secondary battery, in which the protective layer may inhibit formation of lithium dendrite and improve thermal/chemical stability, and conductivity of lithium ions. Further, disclosed are a production method of the protective layer, and a lithium secondary battery including the protectively layer. The protective layer contains a poly(arylene ether sulfone)-poly(ethylene glycol) graft copolymer represented by a following Chemical Formula 1:

##STR00001## where, in the Chemical Formula 1, n is an integer of 60 to 80, and m is an integer of 40 to 45.

A metallic or metallized reinforcer has at least a surface of which is at least partially metallic, the at least partially metallic surface being coated with a polybenzoxazine sulfide whose repeating units include at least one unit corresponding to formula (I) or (II):

##STR00001##

in which the two oxazine rings are connected together via a central aromatic group, the benzene ring of which bears one, two, three or four groups of formula —S.sub.x—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon-based group including 1 to 10 carbon atoms and optionally a heteroatom chosen from O, S, N and P. Such a reinforcement can be used for the reinforcement of a rubber article, in particular a motor vehicle tire.

A PEKK polymer powder, having a d.sub.0.9-value less than 150 μm, wherein the PEKK polymer has a Td(1%) of at least 500° C., as measured by thermal gravimetric analysis according to ASTM D3850, heating from 30° C. to 800° C. under nitrogen using a heating rate of 10° C./min. A method for producing a PEKK powder for the use in a method for manufacturing a 3D object, in which the PEKK has a Td(1%) of at least 500° C., as measured by thermal gravimetric analysis according to ASTM D3850, heating from 30° C. to 800° C. under nitrogen using a heating rate of 10° C./min, and the powder has been manufactured by grinding from a coarser powder and has a d.sub.0.9-value less than 150 μm, as measured by laser scattering in isopropanol.

Described herein are end-capped poly(aryl ether sulfone) (“PAES”) polymers and corresponding synthesis methods. The end-capped PAES polymers are end-capped by functionalizing a PAES polymer with a halophthalic diialkyl ester end-capping agent. It was surprisingly discovered that the resulting dialkyl phthalate end-capped PAES polymers could be synthesized with significantly improved end-capping conversion rates, relative to end-capped PAES polymers directly functionalized with traditional phthalic anhydride end-capping agents. It was also surprisingly found that by heating the isopropyl phthalate end-capped PAES polymers, the polymers could be converted to the corresponding phthalic anhydride end-capped PAES polymers, yielding a more efficient synthetic route to phthalic anhydride end-capped PAES polymers.