Provided herein according to some embodiments is a method of forming a three-dimensional object comprising nylon 6 by additive manufacturing, as well as objects so produced. Also provided is a polymerizable liquid composition useful for producing a three-dimensional object comprising nylon 6 by additive manufacturing, which composition may include: (a) a light polymerizable first component, and (b) a heat polymerizable second component; said heat polymerizable second component comprising: (i) caprolactam monomers, (ii) a catalyst for anionic polymerization of caprolactam, and (iii) an initiator for anionic polymerization of caprolactam.

Provided herein according to some embodiments is a method of forming a three-dimensional object comprising nylon 6 by additive manufacturing, as well as objects so produced. Also provided is a polymerizable liquid composition useful for producing a three-dimensional object comprising nylon 6 by additive manufacturing, which composition may include: (a) a light polymerizable first component, and (b) a heat polymerizable second component; said heat polymerizable second component comprising: (i) caprolactam monomers, (ii) a catalyst for anionic polymerization of caprolactam, and (iii) an initiator for anionic polymerization of caprolactam.

The invention relates to a method for the preparation of a polyamide 6 copolymer, characterised in that a copolymerization reaction is carried out between: o at least one caprolactam of formula (I): o at least one caprolactam, named substituted caprolactam, in which at least one of the carbon atoms is covalently linked to at least one A moiety, said A moiety being selected from the group formed of: # moieties comprising at least one group of formula: (A) # moieties comprising at least one group of formula: (B) # moieties comprising at least one group of formula: (C) The invention also relates to a polyamide 6, to polyamide 6 filaments and filaments yarns.

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The invention relates to a method for the preparation of a polyamide 6 copolymer, characterised in that a copolymerization reaction is carried out between: o at least one caprolactam of formula (I): o at least one caprolactam, named substituted caprolactam, in which at least one of the carbon atoms is covalently linked to at least one A moiety, said A moiety being selected from the group formed of: # moieties comprising at least one group of formula: (A) # moieties comprising at least one group of formula: (B) # moieties comprising at least one group of formula: (C) The invention also relates to a polyamide 6, to polyamide 6 filaments and filaments yarns.

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The present invention is to provide a spherical polyamide fine particle having smooth sliding properties and causing a low degree of environmental pollution. The polyamide fine particle according to the present invention includes: a polyamide including a repetition of a structural unit having at least one alkylene group and at least one amide bond, each of the at least one alkylene group having from 1 to 5 carbon atoms, wherein the polyamide fine particle has a sphericity of 80 or greater.

The present invention is to provide a spherical polyamide fine particle having smooth sliding properties and causing a low degree of environmental pollution. The polyamide fine particle according to the present invention includes: a polyamide including a repetition of a structural unit having at least one alkylene group and at least one amide bond, each of the at least one alkylene group having from 1 to 5 carbon atoms, wherein the polyamide fine particle has a sphericity of 80 or greater.

The present invention relates to a novel synthesis route that can be used to access novel statistical, aliphatic-aromatic copolyamides, by means of ring-opening polymerisation and chain-growth polycondensation, as well as to the resulting copolymers.

The present invention relates to a novel synthesis route that can be used to access novel statistical, aliphatic-aromatic copolyamides, by means of ring-opening polymerisation and chain-growth polycondensation, as well as to the resulting copolymers.

Provided are a method for preparing a polyamide by using a molecular weight controller having a double active group in anionic ring-opening copolymerization of a polyamide, thereby enabling molecular weight to be controlled through the addition reaction of the molecular weight controller, and a polyamide prepared thereby.

Provided are a method for producing a polyamide using an end-capping agent and a polyamide produced thereby, wherein the method is an eco-friendly process method without using a solvent as a catalyst and may prepare, by using an end-capping agent for suppressing side reaction, a polymer having a uniform molecular weight and a high conversion rate at a low temperature within a short polymerization time in comparison with a conventional polymerization method.