A method of manufacture of a polyetherimide composition includes contacting a substituted phthalic anhydride and an organic diamine in the presence of diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing solvents at a temperature of greater than 130 C. to provide a bis(phthalimide) composition comprising diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing solvents and a bis(phthalimide); and polymerizing the bis(phthalimide) and an alkali metal salt of a dihydroxy aromatic compound in the presence of diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing to form a polyetherimide. The method does not require any catalyst either for the imidization or the poly merization.

A method of manufacture of a bis(phthalimide) composition includes reacting, in the presence of molten diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing, a substituted phthalic anhydride with an organic diamine. The product mixture can be directly employed in the preparation of polyetherimides and other polyether polymers.

The present disclosure discloses a method for preparing a display screen cover plate, a display screen cover plate and a display device. The method for preparing a display screen cover plate including: condensing a dianhydride monomer with a first diamine monomer and a second diamine monomer to obtain a polyamide acid; reacting the polyimide acid with a dehydrating agent and a catalyst to obtain a polyimide polymer; dissolving the polyimide polymer in a solvent to obtain a polymer solution; coating the polymer solution onto the substrate to form a film, and peeling off to obtain the display screen cover plate; and the dianhydride monomer having a benzene ring structure and a fluorinated group connected to the benzene ring structure, the first diamine monomer having a pyridine structure, and the second diamine monomer having a benzene ring structure.

The present invention relates to a method for manufacturing a polyimide film and a polyimide film manufactured thereby. In one embodiment, the method for preparing a polyimide film includes: preparing a polyamic acid by polymerizing a mixture containing an aromatic diamine and an aromatic acid dianhydride: preparing a first composition containing the polyamic acid, an amine-based catalyst, an acid anhydride-based dehydrating agent, and a solvent; and forming a polyimide film at 150 C. or less using the first composition, wherein the first composition contains the amine-based catalyst and the acid anhydride-based dehydrating agent in a molar ratio of 1:2 to 1:5.

A polyimide is provided, which contains at least one repeating unit selected from a group consisting of the following general formulas, M, N, and O): ##STR00001##
X is a residue derived from TCA represented by formula I. Y.sub.1 is a residue derived from a diamine with a cardo structure. Y.sub.2 is a residue derived from a diamine with the structure of a benzene ring, biphenyl, phenylbenzimidazole or phenylbenzoxazole. Y.sub.3 is a residue derived from a diamine with an ether or an ester group. ##STR00002##

Disclosed herein is provided a method for manufacturing a polyimide film, the method comprising the steps of: preparing a polyamic acid solution; preparing a polyamic add composition by adding 2-3 mole equivalents of a dehydrating agent to the polyamic acid solution; and applying the polyamic acid to a support to form a film, followed by thermosetting the film in a heater.

Provided herein is a method for manufacturing a polyimide film, the method including the steps of: preparing a polyamic acid solution; preparing a polyamic acid composition by adding a dehydrating agent and an imidizing catalyst to the polyamic acid solution; and applying the polyamic acid to a support to form a film, followed by thermosetting the film in a heater, wherein the thermosetting step comprises a first heating step, a second heating step, and a third heating step, each of the first, the second, and the third step being carried out in a processing temperature range of 100 C. to 550 C.

Disclosed herein are a polyimide film for graphite sheets, a method of fabricating the same, and a graphite sheet fabricated using the same. The polyimide film is fabricated by imidizing a polyamic acid formed by reaction between a dianhydride monomer and a diamine monomer, wherein the reaction is carried out in the presence of particles of a metal compound having an average particle diameter (D.sub.50) of about 1 m to about 6 m.

Disclosed herein are a polyimide film for graphite sheets, a method of fabricating the same, and a graphite sheet fabricated using the same. The polyimide film is fabricated by imidizing a polyamic acid formed by reaction between a dianhydride monomer and a diamine monomer, wherein the reaction is carried out in the presence of a metal compound and the polyamic acid forms a chelate with metal ions.

A method of preparing a processable polyimide-phthalonitrile composition is disclosed, including providing a polyimide-phthalonitrile resin; combining the polyimide-phthalonitrile resin with a first solvent to form a solution, combining the solution with a second solvent, mixing the polyimide-phthalonitrile solution to form a homogeneous mixture, and applying the homogeneous mixture to a substrate. The first solvent has a boiling point greater than 150 C. The second solvent has a boiling point less than 150 C. The method of preparing a polyimide-phthalonitrile composite can include impregnating an additive with a homogeneous resin solution to create one or more pre-impregnated layers, and curing the one or more pre-impregnated layers into a composite material. The composite structure can include a substrate, a polyimide-phthalonitrile resin, and a composite material layer adhered to at least a portion of the substrate.