C08J11/24

OPTIMIZED PROCESS FOR DEPOLYMERIZING A POLYESTER COMPRISING POLYETHYLENE TEREPHTHALATE

The invention relates to a process for depolymerizing a polyester feedstock comprising PET, said process comprising, prior to the step of depolymerization by glycolysis and to the step of purification of the depolymerization effluent, an improved step of conditioning the feedstock in which the polyester feedstock is conditioned in terms of temperature and pressure and then mixed at least with a recycled residue effluent and a diol effluent in particular in order to substantially reduce the viscosity of the feedstock.

OPTIMIZED PROCESS FOR DEPOLYMERIZING A POLYESTER COMPRISING POLYETHYLENE TEREPHTHALATE

The invention relates to a process for depolymerizing a polyester feedstock comprising PET, said process comprising, prior to the step of depolymerization by glycolysis and to the step of purification of the depolymerization effluent, an improved step of conditioning the feedstock in which the polyester feedstock is conditioned in terms of temperature and pressure and then mixed at least with a recycled residue effluent and a diol effluent in particular in order to substantially reduce the viscosity of the feedstock.

CHEMICAL RECYCLING METHOD FOR POLYESTER BASED TEXTILE AND/OR PACKAGING WASTE

Chemical recycling method for polyester based textile and/or packaging waste. In the method, colorless bis hydroxyethyl terephthalate (BHET) is obtained from packaging waste containing polyester and/or textile produced from at least 50% polyester, having at most 50,000 ppm coloring agent or filler material, to be used in the production of packaging materials and/or textile materials such as yarns based on recycled colorless polyethylene terephthalate (PET), fabric, nonwoven (nonwoven fabric). The method also enables the re-production of PET from the BHET.

PROCESS FOR FORMATION OF ADDITIVE-CONTAINING POLYESTER

A method for forming additive-containing reclaimed polyester can include: providing a feed of recycled polyester; providing a feed of polyester precursors; depolymerizing the recycled polyester to obtain depolymerized polyester monomers; polymerizing the depolymerized polyester monomers with the polyester precursors to form a reclaimed polyester; adding additives to the reclaimed properties to adjust for example, the color and/or viscosity, and providing the additive-containing reclaimed polyester as output.

PROCESS FOR FORMATION OF ADDITIVE-CONTAINING POLYESTER

A method for forming additive-containing reclaimed polyester can include: providing a feed of recycled polyester; providing a feed of polyester precursors; depolymerizing the recycled polyester to obtain depolymerized polyester monomers; polymerizing the depolymerized polyester monomers with the polyester precursors to form a reclaimed polyester; adding additives to the reclaimed properties to adjust for example, the color and/or viscosity, and providing the additive-containing reclaimed polyester as output.

RECYCLING APPARATUS FOR A CROSS-LINKED POLYETHYLENE RESIN USING TWIN SCREW EXTRUDER

Disclosed is a recycling apparatus for a cross-linked polyethylene resin using a twin screw extruder. The recycling apparatus for a cross-linked polyethylene resin using a twin screw extruder according to an embodiment of the present disclosure includes: a raw material supply unit configured to supply a raw material that is a cross-linked polyethylene resin; and a twin screw extruder configured to receive the raw material from the raw material supply unit, the twin screw extruder including a cylinder and a twin screw installed inside the cylinder to rotate in the same direction, the twin screw extruder being configured to de-crosslink and recycle the raw material under a de-crosslinking reaction temperature and reaction pressure atmosphere while continuously transporting the raw material along the twin screw by the rotation of the twin screw.

RECYCLING APPARATUS FOR A CROSS-LINKED POLYETHYLENE RESIN USING TWIN SCREW EXTRUDER

Disclosed is a recycling apparatus for a cross-linked polyethylene resin using a twin screw extruder. The recycling apparatus for a cross-linked polyethylene resin using a twin screw extruder according to an embodiment of the present disclosure includes: a raw material supply unit configured to supply a raw material that is a cross-linked polyethylene resin; and a twin screw extruder configured to receive the raw material from the raw material supply unit, the twin screw extruder including a cylinder and a twin screw installed inside the cylinder to rotate in the same direction, the twin screw extruder being configured to de-crosslink and recycle the raw material under a de-crosslinking reaction temperature and reaction pressure atmosphere while continuously transporting the raw material along the twin screw by the rotation of the twin screw.

Chemical recycling of polyethylene terephthalate by microwave irradiation

A process for chemically recycling polyethylene terephthalate (PET) which utilizes a microwave absorber to optimize glycolytic depolymerization of PET via microwave irradiation. The method of chemically degrading PET to its reactive intermediate, bis(2-hydroxyethyl) terephthalate (BHET), is carried out by: (a) combining PET with ethylene glycol and a catalytic system comprising a catalyst and a microwave absorber to produce a heterogeneous reaction mixture; and then (b) heating by microwave irradiating the reaction mixture to a temperature sufficient to produce a reaction product comprising BHET. The BHET monomer then can be purified and re-polymerized to form new, virgin PET.

Chemical recycling of polyethylene terephthalate by microwave irradiation

A process for chemically recycling polyethylene terephthalate (PET) which utilizes a microwave absorber to optimize glycolytic depolymerization of PET via microwave irradiation. The method of chemically degrading PET to its reactive intermediate, bis(2-hydroxyethyl) terephthalate (BHET), is carried out by: (a) combining PET with ethylene glycol and a catalytic system comprising a catalyst and a microwave absorber to produce a heterogeneous reaction mixture; and then (b) heating by microwave irradiating the reaction mixture to a temperature sufficient to produce a reaction product comprising BHET. The BHET monomer then can be purified and re-polymerized to form new, virgin PET.

DEPOLYMERIZATION OF POLYMERS WITH ESTER, ETHER AND CARBONATE LINKAGES USING ACIDIC IONIC LIQUID (AIL) CATALYST
20230078491 · 2023-03-16 ·

The present invention provides an effective and selective process for the depolymerization of polyethylene terephthalate (PET), polyethylene furanoate (PEF), polylactic acid, polycarbonates, polyethers and polyamides into pure and high yielding valorized products by combining the glycolysis-hydrolysis reactions using a homogeneous acidic ionic liquid (AIL) catalyst, resulting in excellent polymer conversion.