C08L23/0815

BIAXIALLY ORIENTED PIPE
20220396693 · 2022-12-15 ·

The disclosure relates to a biaxially oriented pipe made of a polymer composition comprising a propylene-based polymer, wherein the pipe is made by a process comprising the steps of: •a) forming the polymer composition having a melting temperature Tm (° C.) into a tube, •b) heating the tube such that the tube has a drawing temperature Td (° C.) and •c) stretching the tube of step a) in the axial direction and in the peripheral direction at Td to obtain the biaxially oriented pipe, wherein Td is equal to or higher than Tm, wherein •i) the propylene-based polymer comprises (A1) a heterophasic propylene copolymer, wherein the heterophasic propylene copolymer consists of (a1) a propylene-based matrix, wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene copolymer consisting of at least 70 wt % of propylene monomer units and at most 30 wt % of ethylene and/or α-olefin monomer units, based on the total weight of the propylene-based matrix and (a2) a dispersed ethylene-α-olefin copolymer, wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100 wt %, wherein the amount of (a2) with respect to the propylene-based polymer is 2.0 to 30 wt % or ii) the propylene-based polymer comprises (B) a random copolymer of propylene and a comonomer which is ethylene and/or an α-olefin having 4 to 10 carbon atoms, wherein when the pipe has an outer diameter of less than 40 mm, the propylene-based polymer comprising (B) has a comonomer content of 0.1 to 3.8 wt % based on the propylene-based polymer.

LINEAR HIGH-DENSITY POLYETHYLENE WITH HIGH TOUGHNESS AND HIGH ESCR

An interpolymer product comprising: a first ethylene interpolymer comprising ethylene and an α-olefin having a weight-average molecular weight (M.sub.w) of greater than 250,000 and a density of less than 0.930 g/cm.sup.3, and a second ethylene interpolymer comprising ethylene and an α-olefin wherein the second ethylene interpolymer comprises a M.sub.w of less than 70,000 and a density of greater than 0.930 g/cm.sup.3; and wherein the interpolymer product comprises an environmental stress crack resistance (ESCR), measured according to ASTM D1693, Condition B, 10% IGEPAL CO-630, of greater than 90 hours. The interpolymer product may be manufactured in a continuous solution polymerization process utilizing at least two reactors employing at least one single site catalyst formulation and at least one heterogeneous catalyst formulation.

LINEAR HIGH-DENSITY POLYETHYLENE WITH HIGH TOUGHNESS AND HIGH ESCR

An interpolymer product comprising: a first ethylene interpolymer comprising ethylene and an α-olefin having a weight-average molecular weight (M.sub.w) of greater than 250,000 and a density of less than 0.930 g/cm.sup.3, and a second ethylene interpolymer comprising ethylene and an α-olefin wherein the second ethylene interpolymer comprises a M.sub.w of less than 70,000 and a density of greater than 0.930 g/cm.sup.3; and wherein the interpolymer product comprises an environmental stress crack resistance (ESCR), measured according to ASTM D1693, Condition B, 10% IGEPAL CO-630, of greater than 90 hours. The interpolymer product may be manufactured in a continuous solution polymerization process utilizing at least two reactors employing at least one single site catalyst formulation and at least one heterogeneous catalyst formulation.

Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents

The present invention relates to the use of N,N′,N″-substituted hexahydro-1,3,5-triazine in the anionic polymerization of conjugated diene monomer and vinylaromatic monomer. Use of this polar additive produces copolymers having both high vinylaromatic and low vinyl contents, while the blockiness of the vinylaromatic unit can be tailored.

High energy return foam compositions having improved abrasion resistance and uses thereof
11523655 · 2022-12-13 · ·

Components for articles of footwear and athletic equipment are provided including a high energy return foam having improved abrasion resistance. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness and an improved abrasion resistance. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.

High energy return foam compositions having improved abrasion resistance and uses thereof
11523655 · 2022-12-13 · ·

Components for articles of footwear and athletic equipment are provided including a high energy return foam having improved abrasion resistance. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness and an improved abrasion resistance. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.

POLYPROPYLENE COMPOSITION WITH IMPROVED PROCESSABILITY AND IMPACT STRENGTH

The present invention relates to heterophasic polypropylene compositions comprising a propylene homo- or copolymer forming a crystalline fraction as a matrix and an amorphous propylene ethylene elastomer as a soluble fraction dispersed in said matrix. The heterophasic polypropylene compositions further comprise an elastomeric ethylene/alpha-olefin random copolymer. The heterophasic polypropylene compositions have a well-balanced relation between stiffness and impact strength, low volatile and semi-volatile emissions and good processability.

POLYPROPYLENE COMPOSITION WITH IMPROVED PROCESSABILITY AND IMPACT STRENGTH

The present invention relates to heterophasic polypropylene compositions comprising a propylene homo- or copolymer forming a crystalline fraction as a matrix and an amorphous propylene ethylene elastomer as a soluble fraction dispersed in said matrix. The heterophasic polypropylene compositions further comprise an elastomeric ethylene/alpha-olefin random copolymer. The heterophasic polypropylene compositions have a well-balanced relation between stiffness and impact strength, low volatile and semi-volatile emissions and good processability.

ALPHA-OLEFIN INTERPOLYMERS WITH IMPROVED MOLECULAR DESIGN FOR PHOTOVOLTAIC ENCAPSULANTS

A composition comprising an ethylene/alpha-olefin interpolymer that comprises the following properties: a) a total unsaturation/1000C≥0.30; b) a molecular weight distribution (MWD)≤3.0; c) a TGIC broadness parameter B.sub.1/4≤8.0. A solution N polymerization process to prepare an ethylene/alpha-olefin/interpolymer, said process comprising polymerizing, in one reactor, at a reactor temperature ≥150° C., a reaction mixture comprising ethylene, an alpha-olefin, a solvent, and a metal complex as described herein. A method to determine the TGIC broadness parameter B.sub.1/x of a polymer composition comprising one or more olefin-based polymers.

ALPHA-OLEFIN INTERPOLYMERS WITH IMPROVED MOLECULAR DESIGN FOR PHOTOVOLTAIC ENCAPSULANTS

A composition comprising an ethylene/alpha-olefin interpolymer that comprises the following properties: a) a total unsaturation/1000C≥0.30; b) a molecular weight distribution (MWD)≤3.0; c) a TGIC broadness parameter B.sub.1/4≤8.0. A solution N polymerization process to prepare an ethylene/alpha-olefin/interpolymer, said process comprising polymerizing, in one reactor, at a reactor temperature ≥150° C., a reaction mixture comprising ethylene, an alpha-olefin, a solvent, and a metal complex as described herein. A method to determine the TGIC broadness parameter B.sub.1/x of a polymer composition comprising one or more olefin-based polymers.