The present invention provides a process for the synthesis of silylated polyurethanes, comprising three sequential steps, a step (i) of preparing NCO-terminated polyurethane, a step (ii) of partial grafting of the NCO functions with silane functions and a step (iii) of total grafting of the residual NCO functions with functions that react with the NCO functions by means of polyfunctional compounds. The present invention also provides a silylated polyurethane composition that can be obtained by means of the process according to the invention, an adhesive composition comprising said silylated polyurethane composition and a self-adhesive item obtained from the adhesive composition according to the invention.

The present invention provides a process for the synthesis of silylated polyurethanes, comprising three sequential steps, a step (i) of preparing NCO-terminated polyurethane, a step (ii) of partial grafting of the NCO functions with silane functions and a step (iii) of total grafting of the residual NCO functions with functions that react with the NCO functions by means of polyfunctional compounds. The present invention also provides a silylated polyurethane composition that can be obtained by means of the process according to the invention, an adhesive composition comprising said silylated polyurethane composition and a self-adhesive item obtained from the adhesive composition according to the invention.

Provided is a rubber composition that can achieve excellent breaking resistance while having high operability. A rubber composition comprises: a rubber component containing a multicomponent copolymer that contains a conjugated diene unit, a non-conjugated olefin unit, and an aromatic vinyl unit; and at least one selected from an ethylene-α olefin copolymer and an ethylene-aromatic vinyl copolymer each having a number-average molecular weight of 500 to 30,000.

Provided is a rubber composition that can achieve excellent breaking resistance while having high operability. A rubber composition comprises: a rubber component containing a multicomponent copolymer that contains a conjugated diene unit, a non-conjugated olefin unit, and an aromatic vinyl unit; and at least one selected from an ethylene-α olefin copolymer and an ethylene-aromatic vinyl copolymer each having a number-average molecular weight of 500 to 30,000.

A composition comprises: a resin component including an olefin-aromatic vinyl compound-aromatic polyene copolymer satisfying all the following conditions (1) to (4): (1) a number average molecular weight of the copolymer is 500 or more and 100000 or less; (2) the aromatic vinyl compound monomer is an aromatic vinyl compound having 8 or more and 20 or less carbon atoms, and a content of a unit of the aromatic vinyl compound monomer is 0 mass % or more and 70 mass % or less; (3) the aromatic polyene is one or more selected from polyenes having 5 or more and 20 or less carbon atoms and having a plurality of vinyl groups and/or vinylene groups in the molecule, and a content of the vinyl groups and/or the vinylene groups derived from the unit of the aromatic polyene is 1.5 pieces or more and less than 20 pieces per number average molecular weight; and (4) the olefin is one or more selected from olefins having 2 or more and 20 or less carbon atoms, and a total of units of the olefin monomer, the aromatic vinyl compound monomer, and the aromatic polyene monomer is 100 mass %; and a surface-treated silica. The volume ratio between the resin component and the silica is in the range of 98 to 15:2 to 85. A cured product of the composition has a value of the dielectric tangent obtained by resonator method at a measurement frequency of 10 GHz and/or a measurement frequency range of 25 GHz to 40 GHz of 1.2×10.sup.−3 or less and a storage elastic modulus at 250° C. in the range of 10 MPa or more and 10 GPa or less.

A laminate has an olefin-aromatic vinyl compound-aromatic polyene copolymer and a metal foil. The number average molecular copolymer weight is between 5000 and 100000; the aromatic vinyl compound monomer is aromatic vinyl compound having between 8 and 20 carbon atoms, and the aromatic vinyl compound monomer unit content is between 10 and 60 mass %; the aromatic polyene is selected having between 5 and 20 carbon atoms and vinyl and/or vinylene groups in the molecule, the content derived from the aromatic polyene unit is between 1.5 and 20 pieces per number average molecular weight; and the olefin is selected having between 2 and 20 carbon atoms, being ethylene alone, or having a mass ratio of α-olefin monomer components other than ethylene to an ethylene monomer component contained in the olefin, of 1/7 or less, and the total monomer units of the olefin, aromatic vinyl compound, and aromatic polyene is 100 mass %.

Provided is an electronic device housing including a metal member and a plastic antenna cover that are joined and integrated by insert molding. In this electronic device housing, the plastic antenna cover is a molded product of a thermoplastic resin composition containing a thermoplastic polyester resin having a melting point Tm equal to or higher than 250° C.

Provided is an electronic device housing including a metal member and a plastic antenna cover that are joined and integrated by insert molding. In this electronic device housing, the plastic antenna cover is a molded product of a thermoplastic resin composition containing a thermoplastic polyester resin having a melting point Tm equal to or higher than 250° C.

A pressure sensitive hot melt adhesive is provided including at least one olefin block copolymer, a hydrogenated hydrocarbon tackifier, and a plasticizer. The adhesive is free from any oil containing constituents and the pressure sensitive label with the adhesive exhibits desired adhesion performance in low temperature as well as in normal temperature for a host of different substrates. The adhesive also resistant to yellowing, water-whitening and is non-swelling. The adhesive and the label enables recycling in recycling streams when the face material and/or substrate being labeled is also of olefin based material.

A pressure sensitive hot melt adhesive is provided including at least one olefin block copolymer, a hydrogenated hydrocarbon tackifier, and a plasticizer. The adhesive is free from any oil containing constituents and the pressure sensitive label with the adhesive exhibits desired adhesion performance in low temperature as well as in normal temperature for a host of different substrates. The adhesive also resistant to yellowing, water-whitening and is non-swelling. The adhesive and the label enables recycling in recycling streams when the face material and/or substrate being labeled is also of olefin based material.