A copolymer of ethylene and hydrolysable silane includes from 0.1 wt % to 5.0 wt % hydrolysable silane groups and has a Mz(abs)/Mw(abs) of less than or equal to 9.5; a ratio of Mz(abs)/Mw(abs) to polydispersity of less than or equal to 1.5; a polydispersity of 6.6 or greater; a Density?Polydispersity of 6.0 or greater; or an Amorphous Content at Room Temperature?Polydispersity of 360 or greater. Methods for forming a moisture-crosslinkable polymer composition include forming a copolymer of ethylene and hydrolysable silane at a polymerization temperature of greater than or equal to 180? C. to less than or equal to 400? C. at a pressure from 5,000 psi to 50,000 psi; and adding a silanol condensation catalyst to the copolymer of ethylene and hydrolysable silane.

Disclosed are polyolefin copolymer films comprising alkoxysilane groups and a catalyst for crosslinking the alkoxysilane groups; wherein the crosslinking catalyst is a Lewis or Bronsted acid or base compound that has a relatively high melting point and therefore initiates the crosslinking essentially only at the lamination temperature, preferably at or above at least 50 C. Also disclosed are films wherein (i) the layer or layers comprising the alkoxysilane groups, including surface layer(s), comprise the crosslinking catalyst; or (ii) layer or layers comprising alkoxysilane groups do not contain crosslinking catalyst and have a facial surface in adhering contact with a layer of a thermoplastic polyolefin copolymer comprising the crosslinking catalyst; or (iii) there is a combination of layers (i) and (ii). Also disclosed are laminated glass structures and processes for their preparation that employ such films. The disclosed laminate structures include safety glass and photovoltaic modules.

Disclosed are polyolefin copolymer films comprising alkoxysilane groups and a catalyst for crosslinking the alkoxysilane groups; wherein the crosslinking catalyst is a Lewis or Bronsted acid or base compound that has a relatively high melting point and therefore initiates the crosslinking essentially only at the lamination temperature, preferably at or above at least 50 C. Also disclosed are films wherein (i) the layer or layers comprising the alkoxysilane groups, including surface layer(s), comprise the crosslinking catalyst; or (ii) layer or layers comprising alkoxysilane groups do not contain crosslinking catalyst and have a facial surface in adhering contact with a layer of a thermoplastic polyolefin copolymer comprising the crosslinking catalyst; or (iii) there is a combination of layers (i) and (ii). Also disclosed are laminated glass structures and processes for their preparation that employ such films. The disclosed laminate structures include safety glass and photovoltaic modules.

The invention relates to a backsheet element for a photovoltaic module comprising at least one layer, which comprises a crosslinked polymer composition, which comprises a polymer of ethylene, to a photovoltaic module comprising at least one photovoltaic element and the backsheet element of the invention and to the use of the crosslinked polymer composition for producing at least one layer of a backsheet element of the invention for a photovoltaic module.

Silane-crosslinkable polymeric compositions comprising a polyolefin having hydrolyzable silane groups, an acidic silanol condensation catalyst, a phenolic antioxidant, and an ester-functionalized thioether. Such crosslinkable polymeric compositions can be employed in various articles of manufacture, such as in the wire and cable industry.

To provide a resin film which comprises an ethylene/tetrafluoroethylene copolymer and which is to be used as, for example, a rubber plug lamination film to prevent breakage at the time of producing a laminated rubber plug. The resin film comprises an ethylene/tetrafluoroethylene copolymer and is characterized in that the product of the value of the endothermic peak height ?H (mW/mg) obtained by its DSC-analysis and the haze (%) measured at a thickness of 100 ?m, is from 0.1 to 0.2 (mW/mg.Math.%).

A composition for manufacturing a crosslinked ethylene tetrafluoroethylene (ETFE) copolymer with enhanced abrasion resistance and heat resistance is provided, the composition including ETFE, about 0.1-10% w/w of a metal oxide that effectively scavenges high levels of fluoride ions; and a crosslinking agent. Methods of using and making the composition are also provided.

A composition for manufacturing a crosslinked ethylene tetrafluoroethylene (ETFE) copolymer with enhanced abrasion resistance and heat resistance is provided, the composition including ETFE, about 0.1-10% w/w of a metal oxide that effectively scavenges high levels of fluoride ions; and a crosslinking agent. Methods of using and making the composition are also provided.

Provided are a thermoplastic fluororesin composition including a thermoplastic fluororesin (A) having a Shore D hardness of less than or equal to 50, the Shore D hardness being measured at 23 C. in accordance with ASTM D2240, and a cross-linked structure forming agent (B) that is selected from the group consisting of a polyfunctional unsaturated compound (b-1), a polyamine compound (b-2), and a polyhydroxy compound (b-3) and that is capable of forming a cross-linked structure through a reaction with the thermoplastic fluororesin (A), the thermoplastic fluororesin composition not substantially containing a peroxide compound when containing the (b-1), not substantially containing an acid acceptor when containing the (b-2), and not substantially containing at least one of the acid acceptor and an onium compound when containing the (b-3); and a method for producing a cross-linked body including a step of cross-linking the thermoplastic fluororesin composition by an ionizing radiation.

An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) made in a pre-reaction adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof.