The problem of the invention is to provide a hot-melt adhesive having reduced thread formation at the time of applying, excellent thermal resistance and thermal stability after bonding. The means for solving the problem is a hot-melt adhesive comprising a copolymer of ethylene and olefins having 3 to 20 carbon atoms (A), a copolymer of ethylene and carboxylate esters having ethylenically double bonds (B), a tackifying resin (C) and a wax (D), wherein the copolymer of ethylene and olefins having 3 to 20 carbon atoms (A) comprises a metallocene-type propylene/ethylene copolymer (A1).

The problem of the invention is to provide a hot-melt adhesive having reduced thread formation at the time of applying, excellent thermal resistance and thermal stability after bonding. The means for solving the problem is a hot-melt adhesive comprising a copolymer of ethylene and olefins having 3 to 20 carbon atoms (A), a copolymer of ethylene and carboxylate esters having ethylenically double bonds (B), a tackifying resin (C) and a wax (D), wherein the copolymer of ethylene and olefins having 3 to 20 carbon atoms (A) comprises a metallocene-type propylene/ethylene copolymer (A1).

Provided is a novel transparent adhesive material having low relative permittivity as well as excellent adhesive characteristics, whereby an olefinic polymer resin layer and an acrylic polymer adhesive layer can be suitably integrated. Suggested is a transparent adhesive material provided with an outermost surface layer containing an acrylic polymer (B) and a photocrosslinking initiator, and an intermediate layer containing an olefinic polymer (A), a crosslinking agent, and a photocrosslinking initiator, in which the intermediate layer contains a (meth)acrylate monomer as the crosslinking agent.

The present invention provides an adhesive composition including an ethylene/alpha-olefin copolymer; and a tackifier, wherein the ethylene/alpha-olefin copolymer has narrow molecular weight distribution together with a low density and an ultra low molecular weight, minimized number of unsaturated functional groups, and particularly a small amount of vinylidene among the unsaturated functional groups, thereby showing excellent physical properties.

Embodiments of the present disclosure are directed to coextruded multilayer films comprising a comprising a plurality of layers, wherein at least one layer comprises the thermoplastic adhesive composition, the thermoplastic adhesive composition comprising: at least one maleic anhydride-grafted ethylene-based polymer; at least one at least one ethylene/α-olefin/non-conjugated diene interpolymer having a molecular weight distribution (MWD)≥2.5, wherein MWD=Mw/Mn, wherein Mw is weight averaged molecular weight and Mn is number averaged molecular weight, which are both determined by gel permeation chromatography; and a very low density polyethylene (VLDPE) having a density in the range 0.885 to 0.915 grams/cm.sup.3.

Embodiments of the present disclosure are directed to coextruded multilayer films comprising a comprising a plurality of layers, wherein at least one layer comprises the thermoplastic adhesive composition, the thermoplastic adhesive composition comprising: at least one maleic anhydride-grafted ethylene-based polymer; at least one at least one ethylene/α-olefin/non-conjugated diene interpolymer having a molecular weight distribution (MWD)≥2.5, wherein MWD=Mw/Mn, wherein Mw is weight averaged molecular weight and Mn is number averaged molecular weight, which are both determined by gel permeation chromatography; and a very low density polyethylene (VLDPE) having a density in the range 0.885 to 0.915 grams/cm.sup.3.

A biaxially oriented multilayer film may include at least one sealing layer including at least a linear low density polyethylene (LLDPE); and at least one core layer including at least a polypropylene copolymer. A biaxially oriented polypropylene multilayer film, may include at least one sealing layer comprising at least a polyethylene blend and at least one core layer comprising at least a polypropylene copolymer, wherein the polyethylene blend comprises at least a linear low density polyethylene (LLDPE) and at least a high density polyethylene (HDPE).

A biaxially oriented multilayer film may include at least one sealing layer including at least a linear low density polyethylene (LLDPE); and at least one core layer including at least a polypropylene copolymer. A biaxially oriented polypropylene multilayer film, may include at least one sealing layer comprising at least a polyethylene blend and at least one core layer comprising at least a polypropylene copolymer, wherein the polyethylene blend comprises at least a linear low density polyethylene (LLDPE) and at least a high density polyethylene (HDPE).

Provided are adhesive articles that include a barrier layer that is substantially impermeable to oxygen gas at ambient temperature and pressure along with a heat-bondable layer, which could be a discrete layer adjacent to the barrier layer or integral with the barrier layer. The adhesive article further includes a backing extending across and coupled to the barrier layer and an adhesive layer extending across and coupled to the backing opposite the barrier layer. The barrier layer reduces or eliminates migration of plasticizers from the bonded seal into the adhesive article, limiting deterioration of tape performance over time.

The present invention provides an ethylene/alpha-olefin copolymer having narrow molecular weight distribution together with a low density and an ultra low molecular weight, having minimized number of unsaturated functional groups, and having uniform crystallinity, thereby showing excellent physical properties, and a method for preparing the same.