A well treatment additive includes a siloxane surfactant, a solvent and an aqueous phase. The solvent is preferably a terpene hydrocarbon. Also disclosed is a method for using the well treatment additive to form and enhance the properties of terpene solvent based additives useful for the treatment of oil and gas wells. Methods of using the novel well treatment additives include using the additives in a variety of well treatment processes including, but not limited to, acidizing operations, hydraulic fracturing operations, well remediation operations and water removal operations.

Disclosed is a composition and use thereof for the recovery of hydrocarbon fluids from a subterranean reservoir. More particularly, this invention concerns sulfonated epoxy resin polymers comprising an epoxide-containing compound, a primary amino sulfonate, and optionally one or more of a primary monoamine alkylene oxide oligomer, that modify the permeability of subterranean formations and increase the mobilization and/or recovery rate of hydrocarbon fluids present in the formations.

A polymer breaking solution usable in fracking and other downhole applications comprises a solution of aqueous hydrogen peroxide, an anionic surfactant, a metal chelating agent, an acidic pH buffer, a soluble zinc compound, and in some embodiments, a viscosifying agent. In other embodiments, the solution may additionally comprise a linear hydrophobic surfactant. At treatment concentrations of between 500 ppm to 1,500 ppm, the solution is non-toxic and usable at a wide range of downhole temperatures (32° C. to 82° C.).

Polymers and fracturing fluid compositions including a base fluid, an effective amount of a hydratable polymer composition including one or more gel-forming hydratable polymers, a friction reducer composition including hydrolyzed or partially hydrolyzed hydrolyzable polymers and copolymers, a cross-linking composition in an amount sufficient to crosslink the one or more gel-forming hydratable polymers to form crosslinked structures within the fracturing fluid composition with or without a proppant and methods including combining an aqueous fluid and an oleaginous fluid to prepare an invert emulsion comprising a polymerizable composition, degassing the invert emulsion under an extensional flow regime through an elongated passageway of an extender and thereby removing oxygen to produce a degassed invert emulsion and compositions and methods including a hydratable additive concentrate comprising a hydratable additive that is at least substantially hydrated and a hydrating liquid, wherein the hydratable additive concentrate is a mixture produced according to a method that includes flowing a hydrating liquid in a extensional flow regime through an elongated passageway of an extender.

Compositions and methods for use in subterranean treatment fluids involving thermoassociative polymers are provided. In some embodiments, the methods include providing a treatment fluid that includes an aqueous base fluid, one or more thermoassociative polymers that include a water soluble polymeric backbone having one or more hydrophobic moieties attached to the polymer backbone, wherein the thermoassociative polymer exhibits thermoassociation at a first temperature T.sub.assoc, and one or more tuning additives that changes the temperature at which at least one of the thermoassociative polymers exhibits thermoassociation from T.sub.assoc to a second temperature T.sub.assoc′; and introducing the treatment fluid into a portion of a subterranean formation.

In wellbore servicing fluids and methods related thereto a Pickering emulsion is produced by mixing silica, an oleaginous fluid, an aqueous base fluid and an emulsifier. The silica can comprise a silica dust and larger proppant particles that work together to form a Pickering emulsion with the proppant particles suspended therein. In some embodiments, the proppant particles are a silica sand.

An additive comprising: a polymeric weak acid, wherein the polymeric weak acid is in a free acid form or in a monovalent, divalent, or trivalent salt form of the polymeric weak acid, and wherein the additive converts an invert emulsion having an external phase comprising a hydrocarbon liquid to an emulsion having an external phase comprising water. The additive can be added to the invert emulsion in a dry form or included in a base fluid. The invert emulsion can include polyvalent cations. The base fluid can also include a second additive comprising polyvalent cations.

Provided are particulate polyvinyl alcohol-based diverting agents for use in subterranean treatments, which are prepared by compacting a specified polyvinyl alcohol copolymer optionally with certain specified additives and optionally other polyvinyl alcohols.

Methods for breaking polymer-containing treatment fluids for use in subterranean formations are provided. In one or more embodiments, the methods include providing a treatment fluid comprising a base fluid and a polymer, wherein the treatment fluid was recovered from at least a portion of a subterranean formation located at a wellsite; transporting the treatment fluid from the wellsite to an off-site location; and applying a cavitation technique to at least a portion of the treatment fluid at the off-site location.

Emulsions, treatment fluids and methods for treating subterranean formations are provided, wherein the emulsions comprise water, a water-immiscible liquid, one or more polymers, one or more ethoxylated amine compounds and optionally, one or more organic or inorganic salts. The emulsions are particularly suitable for use in harsh brine conditions.