A nanoparticle-resin coated frac sand composition is provided. The nanoparticle-resin coated frac sand composition includes a silica sand, an epoxy resin, methanol, a hardener, and nanoparticles. The nanoparticles may be silica nanoparticles, alumina nanoparticles, zinc oxide (ZnO) nanoparticles, or titanium oxide (TiO.sub.2) nanoparticles. The methanol is used as a diluent for the epoxy resin. The nanoparticle-resin coated frac sand composition may be used as a proppant in a hydraulic fracturing operation, such by injecting a hydraulic fracturing fluid having the composition into a subterranean formation. Methods of manufacturing the composition and hydraulic fracturing of a subterranean formation are also provided.

Treatment fluid compositions that include a carrier fluid, a crosslinkable polymer, one or more degradable fibers grafted with a crosslinking moiety capable of crosslinking the crosslinkable polymer, and optionally a proppant or gravel. Methods and systems for treating a subterranean wellbore or formation using the grafted degradable fiber treatment fluids are further provided. The presently disclosed treatment fluids may be suitable for use as hydraulic fracturing treatment fluids, gravel packing treatment fluids, or fluid diversion treatment fluids.

The method for well-stimulation through a wellbore in a rock formation is hydraulic fracturing under high temperature conditions. The method includes injecting a fracturing fluid system to the rock formation; fracturing the rock formation at a temperature between 150-260 degrees Celsius; and recovering fluid components of the fracturing fluid system from the wellbore and setting the proppant in the fractures. The fracturing fluid system includes proppant and a plurality of fluid components. The fluid components can include water, a gelling agent, and a stabilizer made of ascorbic acid ranging from 50-100 ppt so as to adjust pH and delay said cross linking agent.

Methods of treating a subterranean formation penetrated by a wellbore include providing environmental water, admixing a viscosifying amount of a polymer and at least one divalent cation with the environmental water to form an admixture, and pumping the admixture through the wellbore at a rate and pressure sufficient to treat the subterranean formation. The viscosity of the admixture increases after the at least one divalent cation, the viscosifying amount of polymer and the environmental water are admixed. Such viscosity increase may be at least about 5% over at least a 10 minute period after the admixture is prepared. The divalent cation(s) may be selected from the group consisting of barium, calcium, copper(II), iron(II), magnesium, manganese(II), strontium, tin(II), zinc, and mixtures thereof. Further, the divalent cation(s) may be provided in the form of a salt with one or more anions selected from acetate, bicarbonate, nitrate, chloride, bromide, iodide, sulfate ion, and mixtures thereof.

A composition and method for treating a fracturing fluid comprising produced water with high levels of dissolved solids using a polymer crosslinked with a boron compound and a high pH alkylamine buffer. The composition improves the viscosity stability of the fracturing fluid at elevated bottom-hole temperatures, particularly when the fluid has high levels of calcium and magnesium. The composition is particularly useful with polysaccharides, including galactomannan gums, such as guar gum, locust bean gum, and karaya gum, and allows for the use of the preferred boron compound crosslinkers in high total dissolved solids fracturing fluids without the pH destabilization problems encountered with the prior art.

A fracturing fluid system for increasing hydrocarbon production in a subterranean reservoir formation comprising a fluid composition and a base fluid, the fluid composition comprising a nano-crosslinker, and a base polymer; and the base fluid operable to suspend the fluid composition, the base fluid comprising water; wherein the fluid composition and the base fluid are combined to produce the fracturing fluid system, wherein the fracturing fluid system is operable to stimulate the subterranean reservoir formation. In certain embodiments, the nano-crosslinker is an amine-containing nano-crosslinker and the base polymer is an acrylamide-based polymer. In certain embodiments, the fracturing fluid systems comprise proppants for enhancing hydraulic fracturing stimulation in a subterranean hydrocarbon reservoir.

The present invention comprises a viscosifter for oil well fluids, said viscosifier comprising a cross-linked micro- or nano-fibrillated cellulose (MFC).

A dry composition of dry polyacrylamide and dry guar; or a liquid suspension made from the dry composition for treating subterranean formations and methods for enhancing proppant transport in fracturing fluids using the composition.

Various embodiments disclosed relate to compositions including acidic chelator or salt or ester thereof for treatment of subterranean formations including one or more fractures. In various embodiments, the present invention provides a method of treating a subterranean formation. The method includes placing in the subterranean formation a composition including an acidic chelator or a salt or ester thereof. The subterranean formation includes one or more fractures.

The embodiments described herein generally relate to methods and chemical compositions for coating substrates with a composition. In one embodiment, a composition is provided including a first resin, a second resin different than the first resin, and a cross-linking agent.