The present invention provides a liquid crystal composition formed by combining a polymerizable compound represented by formula I with a specific liquid crystal component, particularly a PSVA liquid crystal composition for displays or TV applications and a PSA-IPS liquid crystal composition for an IPS mode, and a liquid crystal display element or liquid crystal display comprising this liquid crystal composition; in particular, the polymerizable compound has a faster polymerization rate, and a “material system” formed from the selected polymerizable component and liquid crystal component should have the lowest rotary viscosity and the best photoelectric properties, and has a high VHR after (UV) photoradiation, this avoiding the problem of the occurrence of residual images to final displays. ##STR00001##

Disclosed is a liquid crystal composition comprising one or more compounds represented by formula I, one or more compounds represented by formula II, and one or more compounds represented by formula III: ##STR00001##
The liquid crystal composition has simultaneously a lower rotary viscosity, a better photoelectric performance, a higher clearing point, a good low temperature performance, and less display defects. Further disclosed is a liquid crystal display element or device comprising the liquid crystal composition.

The present invention relates to dibenzofuans and dibenzothiophenes thiophenes of formula I

##STR00001##

in which the occurring groups and parameters have the meanings as indicated in claim 1, to liquid-crystalline media comprising same and to high-frequency components comprising these media, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves, in particular for microwave phased-array antennas.

The present invention relates to liquid crystalline media comprising one or more naphthothiadiazol derivatives of formula I, ##STR00001##
in which R.sup.11, R.sup.12, A.sup.11, A.sup.12, A.sup.21, A.sup.22, Z.sup.11, Z.sup.12, Z.sup.21, Z.sup.22, W, X.sup.11, X.sup.12, L, r, s and t have the meanings indicated in claim 1, to the use of such liquid crystal media for optical, electro-optical and electronic purposes, in particular in devices for regulating the passage of energy from an outside space into an inside space, for example in windows.

The invention relates to compounds of the formula I

##STR00001##

in which groups and parameters that occur have the definitions given in Claim 1, to the preparation thereof, to the use thereof as components in liquid-crystalline media and to electrooptical display elements comprising the liquid-crystalline media of the invention.

A liquid-crystalline medium which comprises at least one compound selected from the group of compounds of the formulae IA to IH, ##STR00001##
in which Z.sup.1 denotes a single bond, —CH.sub.2CH.sub.2—, —CH═CH—, —CH.sub.2O—, —OCH.sub.2—, —CF.sub.2O—, —OCF.sub.2—, —COO—, —OCO—, —C.sub.2F.sub.4—, —(CH.sub.2).sub.4—, —CHFCHF—, —CF.sub.2CH.sub.2—, —CH.sub.2CF.sub.2—, —C≡C—, —CF═CF—, —CH═CHCHO— or —CH.sub.2CF.sub.2O—,
and the use thereof for an active-matrix display, in particular based on the VA, PSA, PS-VA, PALC, FFS, PS-FFS, SA-VA, PS-IPS or IPS effect.

Provide are a liquid crystal compound represented by formula I, and a liquid crystal mixture comprising the compound ##STR00001## A lateral trifluoromethyl-containing liquid crystal compound having the structural characteristics of Formula I not only has a negative dielectric anisotropy (Δε), an appropriate optical anisotropy (Δn), a higher clearing point (CP), a prominent low-temperature miscibility with other liquid crystals, and a low rotary viscosity (γ1), but also has a good stability to UV and high temperatures, particularly, a negative dielectric anisotropy. Same can be applied to the formulation of liquid crystal compositions of positive and negative types, and it is particularly prominent that same has the advantages of a good solubility at low temperatures and a high transmittance.

The spontaneous orientation aid for a liquid crystal composition provides storage stability and allows liquid crystal molecules to be vertically aligned without a PI layer when added to a liquid crystal composition. When used in a liquid crystal composition, the spontaneous orientation aid can adsorb to substrates sandwiching a liquid crystal composition (liquid crystal layer) and keep the liquid crystal molecules aligned in a vertical direction. The spontaneous orientation aid makes it possible to align liquid crystal molecules without a PI layer (to induce vertical alignment of liquid crystal molecules under no applied voltage and to achieve horizontal alignment of the liquid crystal molecules under an applied voltage).

Compounds of the formula I, and liquid-crystalline media, preferably having a nematic phase and negative dielectric anisotropy, comprising a) one or more compounds of the formula I ##STR00001## and one or more compounds selected from b) one or more compounds of formula II ##STR00002## and/or c) one or more compounds selected from compounds of formulae III-1 to III-4 and formula B ##STR00003## Methods for making and using these liquid-crystalline media in electro-optical displays, particularly in active-matrix displays based on the VA, ECB, PALC, FFS or IPS effect and the displays which contain these media. Methods for stabilizing liquid-crystalline media with compounds of formula I, where the liquid-crystalline media comprise one or more compounds of the formula II and one or more compounds selected from compounds of the formulae III-1 to III-4 and formula B.

Compounds of formula I, and liquid-crystalline media, preferably having a nematic phase and negative dielectric anisotropy, comprising: a) one or more compounds of formula I ##STR00001## and one or more other compounds selected from: b) one or more compounds of formula II ##STR00002## and/or c) one or more compounds selected from compounds of formulae III-1 to III-4 and B ##STR00003## Use thereof in electro-optical displays, particularly in active-matrix displays based on the VA, ECB, PALC, FFS or IPS effect and use of compounds of formula I for stabilisation of liquid-crystalline media which comprise one or more compounds of formula II and/or one or more compounds selected from compounds of formulae III-1 to III-4 and B.