Provided is a laminate, which has a polarizer and an optically anisotropic layer and is excellent in thermal durability, and an organic electroluminescent device and a liquid crystal display device, which include the laminate. The laminate has two substrates and a polarizing plate disposed between the two substrates, in which the polarizing plate has a polarizer and an optically anisotropic layer, the polarizer contains a polyvinyl alcohol-based resin, the optically anisotropic layer is formed of a composition containing a polymerizable liquid crystal compound represented by General Formula (I): L.sub.1-G.sub.1-D.sub.1-Ar-D.sub.2-G.sub.2-L.sub.2, a moisture permeability of the substrate is 10.sup.3 g/m.sup.2.Math.day or less, and a water content of the polarizing plate is 3.0 g/m.sup.2 or less.

Disclosed is a polymerizable liquid crystal material wherein an amount of a salt represented by the following formula (I) is less than 0.01 parts by mass per 100 parts by mass of a polymerizable liquid crystal compound, and an amount of a nitrogen-containing compound represented by the following formula (II) is 0.01 parts by mass or less per 100 parts by mass of the polymerizable liquid crystal compound. 10 to R.sup.5 each independently represent a hydrogen atom or a C1-C7 alkyl group, R.sup.6 and R.sup.7 represents a hydrogen atom, and X represents F.sup., Br.sup., Cl.sup., I.sup., HSO.sub.4.sup., 1/2(HPO.sub.4.sup.2), H.sub.2PO.sub.4.sup., RC(O)O.sup., 1/2(.sup.O(CO)R(CO)O.sup.) or RSO.sub.3.sup., where R represents a hydrogen atom or a monovalent hydrocarbon group, and R represents a single bond or a divalent hydrocarbon group.

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A polymerizable liquid crystal composition having excellent solubility, used for formation of an optically anisotropic film having excellent durability. The polymerizable liquid crystal composition contains a polymerizable liquid crystal compound P1 represented by Formula (1): A-Ar-A , a polymerizable liquid crystal compound P2 represented by Formula (2): A-Ar-B , and a polymerizable liquid crystal compound P3 represented by Formula (3): BAr-B .

In Formulae (1) and (2), A's represent predetermined side chains, all of which exhibit the same C log P value, and in Formulae (2) and (3), B's represent predetermined side chains, all of which exhibit the same C log P value. It should be noted that A and B represent side chains having C log P values different from each other, in which the C log P value of A is larger than the C log P value of B and the C log P value of at least one of A or B is 3.3 or more.

A laminate is provided having excellent adhesiveness between a light absorption anisotropic film and a barrier layer, a manufacturing method of the laminate, and an image display device using the laminate. A laminate having: a barrier layer A; and a light absorption anisotropic film B, in which the barrier layer A is adjacently provided on the light absorption anisotropic film B, a relationship between a highest content of a compound A1 contained in the barrier layer A and a highest content of a compound B1 contained in the light absorption anisotropic film B satisfies a relationship in which a value of distance calculated from Hansen solubility parameters and represented by Formula (I) is within a range of 0.0 to 5.0, and the light absorption anisotropic film B contains a component same as the compound A1.

distance={4(.sub.D(B1).sub.D(A1)).sup.2+(.sub.P(B1).sub.P(A1)).sup.2+(.sub.H(B1).sub.H(A1)).sup.2}.sup.0.5(I)

A polymerizable liquid crystal composition used for formation of an optically anisotropic film retaining good reciprocal wavelength dispersibility and having an excellent surface condition, an optically anisotropic film, an optical film, a polarizing plate, and an image display device. The polymerizable liquid crystal composition contains a polymerizable liquid crystal compound represented by Formula (I): L.sup.1-SP.sup.1-A.sup.1-D.sup.3-G.sup.1-D.sup.1-Ar-D.sup.2-G.sup.2-D.sup.4-A.sup.2-SP.sup.2-L.sup.2 and a polymerizable compound represented by Formula (II): L.sup.5-SP.sup.5-D.sup.9-C(O)-Cy.sup.1-Cy.sup.2-C(O)-D.sup.7-A.sup.5-D.sup.8-(A.sup.6-D.sup.10).sub.n-SP.sup.6-L.sup.6 and not corresponding to Formula (I).

A laminate film comprising a retardation layer exhibiting blocking characteristics against specific ultraviolet rays even in a state where the retardation layer does not include any ultraviolet absorber or light stabilizer. The laminate film which can be used alone or in combination with an appropriate sunscreen or a light stabilizer as needed to selectively block ultraviolet rays in a region requiring blocking, without affecting display performance, such as color senses and image quality, of a display device. The laminate film can also be formed with a lower thickness without requiring a separate ultraviolet blocking layer, and also has excellent durability, because the laminate film exhibits a certain ultraviolet blocking property even in the absence of an ultraviolet absorber or light stabilizer.

Described herein are liquid crystal compositions containing a five-membered heterocyclic ring that can allow for the adjustment of their refractive indices under the application of an electric field. In addition, selectively dimmable reverse-mode polymer dispersed liquid crystal (PDLC) elements and devices using the aforementioned compositions are also described, which are transparent when no voltage is applied and opaque when a voltage is applied.

A side chain type polymer liquid crystalline compound with which a light absorption anisotropic film having a high alignment degree can be formed, which includes a liquid crystalline composition, a light absorption anisotropic film which is formed of the liquid crystalline composition, a laminate, and an image display device. A liquid crystalline composition contains a side chain type polymer liquid crystalline compound and a dichroic substance, the side chain type polymer liquid crystalline compound is a copolymer having repeating units 1 and 2, the repeating unit 1 has a mesogenic group and an electron-withdrawing group having a Hammett's substituent constant p of greater than 0 at a terminal of the mesogenic group, and the repeating unit 2 has a mesogenic group and a group having a Hammett's substituent constant p of 0 or less at a terminal of the mesogenic group.

An object of the present invention is to provide a method for manufacturing an optical laminate in which an alignment defect is less likely to occur in a light-absorbing anisotropic layer even in a case where a surface of a photo-alignment layer is rubbed; an optical laminate; and an image display device. The method for manufacturing an optical laminate according to an embodiment of the present invention is a method for manufacturing an optical laminate in which an optical laminate including a photo-alignment layer and a light-absorbing anisotropic layer and having a front transmittance of 60% or less is produced and which includes a photo-alignment layer formation step of forming a photo-alignment layer on a polymer film, and a light-absorbing anisotropic layer formation step of applying a liquid crystal composition containing a dichroic substance and a high-molecular liquid crystalline compound onto the photo-alignment layer to form a light-absorbing anisotropic layer.

The present invention is to provide an optical film having optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. An optical film of the present invention is an optical film having at least an optically anisotropic layer, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a predetermined liquid crystal compound and a polymerization initiator, and an extrapolated glass transition starting temperature of the optically anisotropic layer is 70 C. or higher.