Patent classifications
C09K19/3497
Polymerizable liquid crystal composition, method for producing polymerizable liquid crystal composition, optically anisotropic film, optical film, polarizing plate, and image display device
A polymerizable liquid crystal composition having excellent solubility, used for formation of an optically anisotropic film having excellent durability. The polymerizable liquid crystal composition contains a polymerizable liquid crystal compound P1 represented by Formula (1): A-Ar-A, a polymerizable liquid crystal compound P2 represented by Formula (2): A-Ar-B, and a polymerizable liquid crystal compound P3 represented by Formula (3): B-Ar-B. In Formulae (1) and (2), A's represent predetermined side chains, all of which exhibit the same C log P value, and in Formulae (2) and (3), B's represent predetermined side chains, all of which exhibit the same C log P value. It should be noted that A and B represent side chains having C log P values different from each other, in which the C log P value of A is larger than the C log P value of B and the C log P value of at least one of A or B is 3.3 or more.
Compound, composition, cured object, optically anisotropic body, and reflective film
The present invention provides a compound, a composition, a cured object, an optically anisotropic body, and a reflective film which have high refractive index anisotropy Δn and excellent light resistance, and which exhibit liquid crystallinity. The compound of the present invention is a compound represented by General Formula (1). ##STR00001##
LIQUID CRYSTAL COMPOSITION, LIQUID CRYSTAL CURED LAYER, OPTICAL FILM, POLARIZING PLATE, AND IMAGE DISPLAY DEVICE
Provided are a liquid crystal composition, a liquid crystal cured layer, an optical film, a polarizing plate, and an image display device, each of which suppresses streak defects and has excellent temporal stability. The liquid crystal composition includes a liquid crystal compound and a basic compound, in which a pKa of a conjugate acid of the basic compound is 4 to 10.
OPTICAL ELEMENT, LIGHT GUIDE ELEMENT, AND LIQUID CRYSTAL COMPOSITION
An optical element includes an optically-anisotropic layer that is formed of a liquid crystal composition including a liquid crystal compound having a polymerizable group, in which a ratio of a bend elastic constant K33 to a splay elastic constant K11 in the liquid crystal composition satisfies 0.8≤K33/K11≤1.2 at any temperature of a nematic temperature range, and the optically-anisotropic layer has a liquid crystal alignment pattern in which a direction of an optical axis derived from the liquid crystal compound changes while continuously rotating in at least one in-plane direction.
COMPOSITION, POLARIZER LAYER, LAMINATE, AND IMAGE DISPLAYING DEVICE
Provided is a composition that is capable of forming a polarizer layer having an excellent degree of alignment and excellent adhesiveness to another layer in a case of being applied to a laminate, a polarizer layer, a laminate, and an image display device. The composition of the present invention is a composition including at least a polymer liquid crystal compound, a dichroic material, and a low-molecular-weight liquid crystal compound, in which the polymer liquid crystal compound is a copolymer having a repeating unit (1) represented by Formula (1), the low-molecular-weight liquid crystal compound is a compound represented by Formula (LC), and relationships represented by Expressions |log P(SP1)−log P(SPL1)|≤2.0 (11), |log P(MG1)−log P(SP1)|≥4.5 (12), and |log P(ML)−log P(SPL1)|≥4.0 (13) are satisfied.
##STR00001##
FLUORINE-CONTAINING POLYMER, COMPOSITION, OPTICAL FILM, LIQUID CRYSTAL FILM, HARDCOAT FILM, AND POLARIZING PLATE
A fluorine-containing polymer includes a repeating unit represented by General Formula (I). In General Formula (I), L.sub.1 represents a single bond or a divalent linking group, R.sub.1 represents a hydrogen atom, a fluorine atom, a chlorine atom, or an alkyl group having 1 to 20 carbon atoms, and R.sub.2 represents a group including a fluorine atom
##STR00001##
POLYMERIZABLE LIQUID CRYSTAL COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, RETARDATION FILM, METHOD FOR PRODUCING RETARDATION FILM, TRANSFER LAMINATE, OPTICAL MEMBER, METHOD FOR PRODUCING OPTICAL MEMBER, AND DISPLAY DEVICE
A polymerizable liquid crystal compound represented by the following general formula (1):
##STR00001##
(the symbols in the general formula (1) are as described in the DESCRIPTION.)
POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC OBJECT
The present invention aims to provide a polymerizable compound that has high storage stability without causing crystal precipitation when added to a polymerizable composition and to provide a polymerizable composition containing the polymerizable compound. A polymer film produced by polymerization of the polymerizable composition has a low haze, high thickness uniformity, low occurrence of nonuniform orientation, high surface hardness, high adhesiveness, and good appearances and fewer orientation defects even after ultraviolet irradiation. The present invention also aims to provide a polymer produced by polymerization of the polymerizable composition and an optically anisotropic body produced from the polymer.
POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY
A problem of the present invention is to provide a polymerizable compound and a polymerizable composition which cause little decrease in retardation and discoloration when a film-shaped polymer produced by polymerization is irradiated with ultraviolet/visible light for a long time at high temperature. A further problem is to provide a polymer produced by polymerizing the polymerizable composition and an optically anisotropic body using the polymer. As a result, a compound useful as a component of a polymerizable composition was obtained. An optically anisotropic body using a polymerizable liquid crystal composition containing the compound of the present invention is useful for application to an optical film and the like.
POLYMERIZABLE COMPOSITION, FILM, AND HALF MIRROR FOR DISPLAYING PROJECTION IMAGE
The present invention provides a polymerizable composition containing a polymerizable liquid crystal compound represented by Formula (I) and an oxime compound,
##STR00001## in the formula, A.sup.1 and A.sup.2 each represent a phenylene group or a trans-1,4-cyclohexylene group, L.sup.1 and L.sup.2 each represent single bond, —C(═O)O—, or —OC(═O)—, Q.sup.1 and Q.sup.2 each represent a polymerizable group or the like, m and n represent an integer of 0 to 2, X may represent —X.sup.3-Sp.sup.3-Q.sup.3 or two X's may be bonded to each other to form a fused ring, X.sup.3 represents —C(═O)O—, Sp.sup.1, Sp.sup.2, and Sp.sup.3 each represent single bond, an alkylene group, or the like, Q.sup.3 represents hydrogen atom, a cycloalkyl group, a polymerizable group, or the like, and l represents an integer of 0 to 4. The polymerizable composition hardly causes yellowing after curing and is useful for manufacturing a film and a half mirror for displaying a projection image.