A dual host system for OLEDs that contains hole-transporting indolocarbazole and electron-transporting indolocarbazole exhibiting superior performance in the OLEDs is disclosed.

This invention relates to compounds containing heterocycles or azaheterocycles and phenylene or azaphenylene wherein at least one ring is a five-membered ring. These novel compounds are useful as host materials for phosphorescent electroluminescent devices.

A phosphorescent emitter or delayed fluorescent and phosphorescent emitters represented by Formula I or Formula II, where M is platinum or palladium.

##STR00001##

Compounds comprising phosphorescent metal complexes comprising cyclometallated ligands having a structure of ##STR00001##
In the vgs3, each of the E.sup.1 atoms is selected from C and N, except that E.sup.1g is selected from C, N, and S. The E.sup.1 atoms collectively comprise an 18 pi-electron system, provided that E.sup.1a and E.sup.1p are different. The R.sup.1 substituents are each, independently, H, hydrocarbyl, heteroatom substituted hydrocarbyl, cyano, fluoro, OR.sup.2a, SR.sup.2a, NR.sup.2aR.sup.2b, BR.sup.2aR.sup.2b, or SiR.sup.2aR.sup.2bR.sup.2c, where the R.sup.2 substituents are each, independently, hydrocarbyl or heteroatom substituted hydrocarbyl. Any of the R.sup.1 or R.sup.2 substituents can be linked to form a saturated or unsaturated, aromatic or non-aromatic ring, provided that the R.sup.1 substituents are not present when the corresponding one of E atoms is N or S. Organic light emitting diode devices comprising these compounds are also described.

The invention relates to an organic molecule for optoelectronic devices. According to the invention, the organic molecule has a structure of Formula I:

##STR00001## wherein X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, X.sup.9, X.sup.10, X.sup.11, X.sup.12, X.sup.13, and X.sup.14 is independently selected from the group consisting of N and CR.sup.a; and Z is at each occurrence independently selected from the group consisting of a direct bond, CR.sup.3R.sup.4, CCR.sup.3R.sup.4, CO, CNR.sup.3, NR.sup.3, O, SiR.sup.3R.sup.4, S, S(O), and S(O).sub.2.

A phosphorescent emitter or delayed fluorescent and phosphorescent emitters represented by Formula I or Formula II, where M is platinum or palladium. ##STR00001##

An object of the present invention is to provide a resin composition which can be detected both by X-ray radiation and by fluorescence or phosphorescence, and a molded article obtained from the resin composition. The present invention provides a resin composition containing a light-emitting substance and a radiopaque substance; in which the light-emitting substance is a near-infrared fluorescent material or a phosphorescent material. a radiopaque substance of the resin composition is any one of barium sulfate, bismuth oxide, bismuth subcarbonate, calcium carbonate, aluminum hydroxide, tungsten, zinc oxide, zirconium oxide, zirconium, titanium, platinum, bismuth subnitrate, and bismuth. A molded article can be obtained by processing any one of the resin compositions described above.

The present invention relates to mechanically linked emitter-emitter, host-host, and emitter-host materials. These materials may be useful in organic electroluminescence devices.

Compounds comprising phosphorescent metal complexes comprising cyclometallated ligands having a structure of

##STR00001##

In the vgs3, each of the E.sup.1 atoms is selected from C and N, except that E.sup.1g is selected from C, N, and S. The E.sup.1 atoms collectively comprise an 18 pi-electron system, provided that E.sup.1a and E.sup.1p are different. The R.sup.1 substituents are each, independently, H, hydrocarbyl, heteroatom substituted hydrocarbyl, cyano, fluoro, OR.sup.2a, SR.sup.2a, NR.sup.2aR.sup.2b, BR.sup.2aR.sup.2b, or SiR.sup.2aR.sup.2bR.sup.2c, where the R.sup.2 substituents are each, independently, hydrocarbyl or heteroatom substituted hydrocarbyl. Any of the R.sup.1 or R.sup.2 substituents can be linked to form a saturated or unsaturated, aromatic or non-aromatic ring, provided that the R.sup.1 substituents are not present when the corresponding one of E atoms is N or S. Organic light emitting diode devices comprising these compounds are also described.

Compounds comprising phosphorescent metal complexes comprising cyclometallated imidazo[1,2-f]phenanthridine and diimidazo[1,2-a:1,2-c]quinazoline ligands, or isoelectronic or benzannulated analogs thereof, are described. Organic light emitting diode devices comprising these compounds are also described.