A fuel additive concentrate for gasoline, a gasoline fuel containing an additive mixture, a method for reducing wear in an engine and in a fuel delivery system of a gasoline engine, and a method for improving injector performance. The additive concentrate includes an aromatic solvent and a mixture that contains (i) N,N-bis(2-hydroxyethyl)alkylamide, (ii) 2-((2-(bis(2-hydroxyethyl)amino)ethyl)amino)ethyl alkanoate and N-(2-(bis(2-hydroxyethyl)amino)ethyl)-N-(2-hydroxyethyl)alkylamide, and (iii) fatty acid ester(s) and amide(s) derived from a self-condensation product of diethanolamine (DEA) containing at least 3 amino groups. A weight ratio of (i) to (ii) to (iii) in the concentrate ranges from about 8:2:0 to about 2:5:3. The fuel additive mixture is substantially devoid of glycerin and remains fluid at a temperature down to about 20 C.

The invention provides fuel mixtures containing biodiesel oil, glycerol, glycerol soluble compounds, surfactants and additives. The fuel mixtures are uniform, remain suspended in solution, and are resistant to phase separation. Upon combustion, the mixtures generate reduced CO, CO.sub.2, SOx, NOx and particulate matter emissions compared to petroleum fuels and offer improved engine performance over petroleum and water mixtures.

Disclosed herein is a method comprising the steps of (a) providing a fuel additive concentrate comprising (i) from about 5 to about 50 wt. %, based on the total weight of the fuel additive concentrate, of one or more fatty acid sorbitan esters, and (ii) about 10 to about 95 wt. %, based on the total weight of the fuel additive concentrate, of a fuel carrier fluid, and (b) storing the fuel additive concentrate at a low temperature environment. Also disclosed is a method operating an internal combustion engine with a fuel composition comprising (a) a major amount of a fuel, and (b) a minor amount of one or more fatty acid sorbitan esters in a low temperature environment.

Disclosed herein is a fuel additive comprising a mixture of (a) one or more fatty acid sorbitan esters and (b) one or more fatty acid monoesters of a polyol, wherein the one or more fatty acid sorbitan esters are present in an amount of about 0.05 wt. % to about 50 wt. %, based on the weight of the fuel additive, and the one or more fatty acid monoesters of a polyol are present in an amount of about 99.95 wt. % to about 50 wt. %, based on the weight of the fuel additive. Also disclosed is a fuel composition comprising a major amount of a fuel and minor amount of the fuel additive.

The present invention relates to the use of a diesel fuel additive for removing deposits in a diesel engine.

This invention relates to the use of an oil-soluble mono-, di-, or tri-glyceride of at least one hydroxy polycarboxylic acid, or a derivative thereof, as an anti-camshaft-wear additive in a non-aqueous lubricant composition and/or in a fuel composition.

A corrosion-inhibiting composition includes a diluent and a mixture of organic salts of half ester-half acids of a dioic acid with of a glyceride group with a fatty acyl residue. Included are organic salts of glyceride-cyclic carboxylic acid anhydride adducts.

Problem

A detergent friction modifying agent having both a detergent performance that ameliorates and prevents degradation over time that is caused by deposits in the engine, and a friction reducing effect that lowers frictional resistance in the engine; a fuel additive that improves drivability with a good balance over the entire range of engine speeds, and provides engine characteristics such that, over the entire range of driving speeds, the engine-braking characteristics are such that the feeling of free running will be strongly produced, such that a fuel consumption improvement effect is produced in actual vehicles that is greater than the values produced on the test bench, and which also has storage stability; and a fuel composition containing the same.

Solution

The present invention is characterized by containing a polyetheramine carboxylic acid salt; the fuel additive of the present invention is added to fuel at 0.5 wt % or less.

The disclosure generally provides branched diester compounds having exceptional low-temperature and flow properties. The disclosure also provides uses of the branched diester compounds in lubricant compositions, for example, as a base oil, and in other applications where their low-temperature and flow properties can be employed beneficially. The disclosure also provides efficient and green methods for making the branched diester compounds.

In certain embodiments, a vegetable oil-based diester (1,6-hexyldioleate) was branched with propanoic acid (C3) using a green synthetic approach involving solvent-free and catalyst-free epoxide ring opening followed by in situ normal esterification. A total of three branched ester derivatives possessing varied numbers of internal protruding branched ester groups and hydroxyl groups were obtained. All of the pure branched derivatives were comprised of mixtures of positional isomers and/or stereoisomers. Differential scanning calorimetry (DSC) showed that regardless of the composition inhomogeneity of each branched derivative, crystallization was suppressed completely in all of the branched compounds, and they all demonstrated glass transitions below 65 C.

Without being bound by any theory, it is believed that this unique thermal behavior is attributed to the internal protruding branched moieties and hydroxyl groups, which dramatically slowed down mass transfer starting with the least branched compound (2-branched derivative). The viscosity of the branched compounds was one order of magnitude larger than that of the starting di ester due to the increased branching and increased resistance to flow associated with hydrogen bonding introduced by the OH groups. Overall, these branched diesters demonstrated superior low temperature and flow properties comparable to existing non-sustainable commercial lubricants and analogous biobased materials which makes them suitable alternatives for use in lubricant formulations particularly in high performance industrial gear and bearing lubricants.

This present disclosure relates to biodiesel compositions comprising polymeric pour point depressants, and crystallization modifiers, to improve cold flow properties for biodiesel fuels.