Patent classifications
C10L1/223
Catalysis of the reaction between hydrogen sulfide scavengers and hydrogen sulfide using tertiary amines
While some triazines have low reactivity, a method and composition is described for improving their reactivity. The H.sub.2S scavenging composition and method utilizes a tertiary amine to catalyze the scavengers with slower kinetics to achieve improved results over traditional systems with the scavenger alone. A hydrogen sulfide scavenging composition comprises: a tertiary amine as a catalyst in at least one of (i) a triazine scavenger selected from the group consisting of: methyl amine, C2-C5 alkyl amine, dimethylaminopropylamine, isopropanolamine, aniline, cyclohexylamine, isobutanolamine and methoxypropylamine triazines/bisoxazolidines; or (ii) an aldehyde-based scavenger such as glyoxal.
Aviation gasoline compositions
The present disclosure provides base aviation gasoline formulations. In addition, the present disclosure provides formulations in which one or more additives can optionally be added to the base aviation gasoline formulation to produce a finished aviation gasoline formulation.
Aviation gasoline compositions
The present disclosure provides base aviation gasoline formulations. In addition, the present disclosure provides formulations in which one or more additives can optionally be added to the base aviation gasoline formulation to produce a finished aviation gasoline formulation.
Method for producing N-methyl-p-toluidine for use as an additive for aviation gasoline
The invention relates to novel methods for preparing N-methyl-p-toluidine for the use thereof as additive for aviation fuel, and to specific catalysts for these methods.
OXYGENATED AROMATIC AMINES AND USE AS ANTIOXIDANTS
Described are compounds, compositions, and methods that include oxygenated aromatic amines, such as an aminophenol-, phenyl-p-phenylenediamine-, and diaminobenzene-based compound useful as antioxidants. The oxygenated aromatic amine includes a secondary and/or tertiary amine group having a nitrogen that is attached to one or two carbon-containing group(s), the carbon-containing group(s) having a hydroxyl and/or ether group separated from the nitrogen by one or more carbon atoms.
Fuel compositions
Gasoline fuel composition suitable for use in an internal combustion engine comprising: (a) Fischer-Tropsch derived naphtha at a level from 2 to 20% v/v; (b) at least one aromatic octane booster present at a level of 0.75 to 8% v/v or less; and (c) a gasoline base fuel; wherein the gasoline fuel composition comprises 40% v/v or less of aromatics. In a preferred embodiment, the Research Octane Number (RON) of the gasoline fuel composition is increased while maintaining the aromatic content of the gasoline fuel composition at a level of 40% v/v or less, based on the gasoline fuel composition.
Fuel compositions
Gasoline fuel composition suitable for use in an internal combustion engine comprising: (a) Fischer-Tropsch derived naphtha at a level from 2 to 20% v/v; (b) at least one aromatic octane booster present at a level of 0.75 to 8% v/v or less; and (c) a gasoline base fuel; wherein the gasoline fuel composition comprises 40% v/v or less of aromatics. In a preferred embodiment, the Research Octane Number (RON) of the gasoline fuel composition is increased while maintaining the aromatic content of the gasoline fuel composition at a level of 40% v/v or less, based on the gasoline fuel composition.
METHOD FOR PRODUCING N-METHYL-P-TOLUIDINE FOR USE AS AN ADDITIVE FOR AVIATION GASOLINE
The invention relates to novel methods for preparing N-methyl-p-toluidine for the use thereof as additive for aviation fuel, and to specific catalysts for these methods.
HIGH OCTANE UNLEADED AVIATION GASOLINE
Concentrate for the manufacture of unleaded aviation gasoline. High quality aviation alkylate, or similar base fuel is blended with selected aromatic solvents, including alkyl benzenes effective to improve the functional engine performance to avoid harmful detonation in aircraft piston engines. Monoalkylated benzenes such as toluene and ethylbenzene are utilized in combination with dialkylated benzenes, such as xylenes. Aromatic amines, for example p-toluidine and m-toluidine, may be added to increase MON. Alcohols such as ethanol and/or methanol may be added in effective amounts to produce unleaded AVGAS which meets a required freeze point. Amounts of toluene to p-toluidine, and/or of the amount of p-toluidine to m-toluidine may be in a controlled ratio in amounts effective to produce unleaded AVGAS which meets a required freeze point. Isopentane and/or butane may be included to provide a required vapor pressure profile.
HIGH OCTANE UNLEADED AVIATION GASOLINE
Concentrate for the manufacture of unleaded aviation gasoline. High quality aviation alkylate, or similar base fuel is blended with selected aromatic solvents, including alkyl benzenes effective to improve the functional engine performance to avoid harmful detonation in aircraft piston engines. Monoalkylated benzenes such as toluene and ethylbenzene are utilized in combination with dialkylated benzenes, such as xylenes. Aromatic amines, for example p-toluidine and m-toluidine, may be added to increase MON. Alcohols such as ethanol and/or methanol may be added in effective amounts to produce unleaded AVGAS which meets a required freeze point. Amounts of toluene to p-toluidine, and/or of the amount of p-toluidine to m-toluidine may be in a controlled ratio in amounts effective to produce unleaded AVGAS which meets a required freeze point. Isopentane and/or butane may be included to provide a required vapor pressure profile.