Fuel and lubricant compositions are provided that contain a primary low-speed pre-ignition (LSPI)-reducing additive comprising (i) an amino additive, (ii) an amine additive, (iii) a triazole additive, (iv) a benzamidinium additive, (v) a benzoxazole additive, or (vi) a NCX motif additive. Methods for preventing or reducing low speed pre-ignition events in spark-ignited engines using these compositions are also provided.

The use of tetrahydrobenzoxazines I ##STR00001##
where R.sup.1 is a hydrocarbyl radical and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R.sup.2 to R.sup.5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

An additive composition improves the stability and the engine performances of gas oils, including gas oils of the non-road type in compliance with the decree of 10 Dec. 2010. The additive composition includes: at least one metal deactivator or chelating agent, at least one antioxidant of the hindered phenol type (alkylphenol), at least one dispersant and/or detergent, and at least one metal passivator, wherein the composition includes improved properties, in particular relative to the oxidation resistance, storage stability, thermal stability, reduction in fouling of the injectors, reduction in loss of power, reduction in the tendency of filters to clog.

An additive composition improves the stability and the engine performances of gas oils, including gas oils of the non-road type in compliance with the decree of 10 Dec. 2010. The additive composition includes: at least one metal deactivator or chelating agent, at least one antioxidant of the hindered phenol type (alkylphenol), at least one dispersant and/or detergent, and at least one metal passivator, wherein the composition includes improved properties, in particular relative to the oxidation resistance, storage stability, thermal stability, reduction in fouling of the injectors, reduction in loss of power, reduction in the tendency of filters to clog.

The use of tetrahydrobenzoxazines I

##STR00001##

where R.sup.1 is a hydrocarbyl radical and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R.sup.2 to R.sup.5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

This disclosure relates to a composition for use as an additive for fuels and lubricants including a reductive amination product of a vinyl terminated macromonomer (VTM) based aldehyde. Optionally aldehyde is reacted with the amino compound under condensation conditions sufficient to give an imine intermediate, and the imine intermediate is reacted under hydrogenation conditions sufficient to give the composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde. A reductive amination method for making a composition for use as an additive for fuels and lubricants. The method includes reacting a VTM based aldehyde with an amino compound containing at least one NH group under condensation conditions sufficient to give an imine intermediate, and reacting the imine intermediate under hydrogenation conditions sufficient to give said composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde.

The use of tetrahydrobenzoxazines I ##STR00001##
where R.sup.1 is a hydrocarbyl radical and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R.sup.2 to R.sup.5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

The present disclosure provides methods for identifying a hydrocarbon fuel, such as the presence and/or amounts of marker compounds having a fluorescence intensity and, through correlation, the presence and/or amounts of additive package(s) within the hydrocarbon fuel. The methods include obtaining a sample of a hydrocarbon fuel including a marker compound having fluorescence, combining the hydrocarbon fuel with water, and subjecting a water phase thereof to light for observing fluorescence.

A synergistic mixture comprising from 1 to 99.9% by weight of compounds having structural elements (I) ##STR00001##
in which the free valencies on the oxygen atom and on the nitrogen atom may be combined to form a five-, six- or seven-membered ring and the benzene ring may also bear substituents at one or more of the free positions, and from 0.1 to 99% by weight of sulfur-containing organic compounds with antioxidant action. This synergistic mixture is suitable as a stabilizer for stabilizing inanimate organic material, especially mineral oil products and fuels, against the action of light, oxygen and heat.

A synergistic mixture comprising from 1 to 99.9% by weight of compounds having structural elements (I) ##STR00001##
in which the free valencies on the oxygen atom and on the nitrogen atom may be combined to form a five-, six- or seven-membered ring and the benzene ring may also bear substituents at one or more of the free positions, and from 0.1 to 99% by weight of sulfur-containing organic compounds with antioxidant action. This synergistic mixture is suitable as a stabilizer for stabilizing inanimate organic material, especially mineral oil products and fuels, against the action of light, oxygen and heat.