The invention relates to a copolymer comprising: at least one motif of the following formula (I), and motifs of the following formula (II), between 5 and 95 mol % of the groups R of the motifs of formula (II) comprising at least one quaternary amino group. The invention also relates to the production of such a copolymer, and to the use thereof as a detergent additive and/or demulsifying additive in a liquid fuel for an internal combustion engine.

##STR00001##

The invention relates to a composition of additives for fuel, comprising: (a) one or more copolymer(s) comprising the following units of formulae (I) and units of formula (IIa): R representing a hydrocarbon-based chain substituted with at least one amino group comprising at least one quaternary ammonium or iminium function, and (b) one or more copolymer(s) comprising units of formulae (I) and units of formula (IIb): R representing a hydrocarbon-based chain substituted with at least one amino group comprising at least one primary, secondary or tertiary amine function or imine function. The invention also relates to the use of such a composition as a detergent additive and/or demulsifying additive in a liquid fuel for an internal combustion engine.

##STR00001##

The invention relates to a composition of additives for fuel, comprising: (a) one or more copolymer(s) comprising the following units of formulae (I) and units of formula (IIa): R representing a hydrocarbon-based chain substituted with at least one amino group comprising at least one quaternary ammonium or iminium function, and (b) one or more copolymer(s) comprising units of formulae (I) and units of formula (IIb): R representing a hydrocarbon-based chain substituted with at least one amino group comprising at least one primary, secondary or tertiary amine function or imine function. The invention also relates to the use of such a composition as a detergent additive and/or demulsifying additive in a liquid fuel for an internal combustion engine.

##STR00001##

The present invention relates to a copolymer obtainable by copolymerization of

(A) at least one unsaturated dicarboxylic acid or derivatives thereof,
(B) at least one -olefin having from at least 6 up to and including 20 carbon atoms,
(C) optionally at least one C.sub.3- to C.sub.20-alkyl ester of acrylic acid or methacrylic acid or a mixture of such alkyl esters and
(D) optionally one or more further copolymerizable monomers other than monomers (A), (B) and (C),
with a molar incorporation ratio of (A):(B):(C):(D) of 1:0.5 to 2.0:0 to less than 0.5:0 to 0.1
followed by the reaction with at least one dialkylamine (E), where the two alkyl radicals in the at least one dialkylamine (E) are independently alkyl radicals having at least 17 up to 30 carbon atoms.

The present invention relates to a copolymer obtainable by copolymerization of

(A) at least one unsaturated dicarboxylic acid or derivatives thereof,
(B) at least one -olefin having from at least 6 up to and including 20 carbon atoms,
(C) optionally at least one C.sub.3- to C.sub.20-alkyl ester of acrylic acid or methacrylic acid or a mixture of such alkyl esters and
(D) optionally one or more further copolymerizable monomers other than monomers (A), (B) and (C),
with a molar incorporation ratio of (A):(B):(C):(D) of 1:0.5 to 2.0:0 to less than 0.5:0 to 0.1
followed by the reaction with at least one dialkylamine (E), where the two alkyl radicals in the at least one dialkylamine (E) are independently alkyl radicals having at least 17 up to 30 carbon atoms.

A copolymer obtained by copolymerization of at least: an apolar monomer (m.sub.a) with the following formula (I), where u=0 or I, w=0 or I, E=-0- or NH(Z), or OCO, or NHCO or CONH, wherein Z is H or an alkyl group, and G is a group selected among an alkyl, an aromatic ring and an arylalkyl; and a polar monomer (m.sub.b) selected among those of the following formula (II), wherein t=0 or I, Q is selected among the oxygen atom and the NR group, wherein R is selected among a hydrogen atom and hydrocarbon chains, and R is a hydrocarbon chain substituted by at least one quaternary ammonium group and optionally one or more hydroxyl groups. The invention also relates to the use of such a copolymer as a detergent additive in a liquid fuel of an internal combustion engine.

A copolymer obtained by copolymerization of at least: an apolar monomer (m.sub.a) with the following formula (I), where u=0 or I, w=0 or I, E=-0- or NH(Z), or OCO, or NHCO or CONH, wherein Z is H or an alkyl group, and G is a group selected among an alkyl, an aromatic ring and an arylalkyl; and a polar monomer (m.sub.b) selected among those of the following formula (II), wherein t=0 or I, Q is selected among the oxygen atom and the NR group, wherein R is selected among a hydrogen atom and hydrocarbon chains, and R is a hydrocarbon chain substituted by at least one quaternary ammonium group and optionally one or more hydroxyl groups. The invention also relates to the use of such a copolymer as a detergent additive in a liquid fuel of an internal combustion engine.

A block copolymer including: at least one block A of following formula (I): ##STR00001##
in which p is an integer ranging from 2 to 100, R1 is selected from hydrogen and the methyl group, R2 is chosen from C1 to C34 hydrocarbon-based chains, at least one block B of following formula (II): ##STR00002##
in which n is an integer ranging from 2 to 40, R1 is chosen from hydrogen and the methyl group, Z is chosen from the oxygen atom and the group NR with R being chosen from a hydrogen atom and C1 to C12 hydrocarbon-based chains, G is a C1 to C34 hydrocarbon-based chain substituted by at least one quaternary ammonium group and optionally one or more hydroxyl groups. Also, the use of such a block copolymer as detergent additive in an internal combustion engine liquid fuel.

A block copolymer including: at least one block A of following formula (I): ##STR00001##
in which p is an integer ranging from 2 to 100, R1 is selected from hydrogen and the methyl group, R2 is chosen from C1 to C34 hydrocarbon-based chains, at least one block B of following formula (II): ##STR00002##
in which n is an integer ranging from 2 to 40, R1 is chosen from hydrogen and the methyl group, Z is chosen from the oxygen atom and the group NR with R being chosen from a hydrogen atom and C1 to C12 hydrocarbon-based chains, G is a C1 to C34 hydrocarbon-based chain substituted by at least one quaternary ammonium group and optionally one or more hydroxyl groups. Also, the use of such a block copolymer as detergent additive in an internal combustion engine liquid fuel.

Disclosed are paraffin inhibitors, paraffin suppressant compositions, and methods of making and using them. The paraffin inhibitors comprise polymers of a maleic moiety polymerized with at least two olefins having hydrocarbon chains of a different length from each other. When added to hydrocarbon media such as crude oils to form crude oil compositions, the paraffin inhibitors inhibit the precipitation of paraffin waxes in the crude oil compositions and exhibit reduced precipitation, gelling, and/or crystallization from the hydrocarbon media when the media are subjected to sustained low temperatures.