Patent classifications
C10L3/104
Method of preparing natural gas at a gas pressure reduction stations to produce liquid natural gas (LNG)
A method to pre-treat an inlet natural gas stream at gas pressure reduction stations to produce LNG removes water and carbon dioxide from a natural gas stream. The energy required for the process is provided by recovering pressure energy in the inlet gas stream. The process eliminates the conventional gas pre-heating process at pressure reductions stations employing gas combustion heaters. The process provides a method to produce LNG at natural gas pressure reduction that meets product specifications.
Installation and method for the treatment by membrane permeation of a gas stream with the methane concentration adjusted
Installation for membrane permeation treatment of feed gas flow containing at least methane and carbon dioxide including first, second, and third membrane separation units and at least one compressor B for aspirating the second permeate, a permeate from the first membrane separation unit being fed to the third membrane separation unit, a retentate from the first membrane separation unit being fed to the second membrane separation. After measuring the aspiration pressure and methane concentration of the second permeate before it is recycled to the feed, the pressure of the second permeate is adjusted according to the measured aspiration pressure and methane concentration.
System and process for recovering methane and carbon dioxide from biogas and reducing greenhouse gas emissions
Various illustrative embodiments of a system and process for recovering high-quality biomethane and carbon dioxide product streams from biogas sources and utilizing or sequestering the product streams are provided. The system and process synergistically yield a biomethane product which meets gas pipeline quality specifications and a carbon dioxide product of a quality and form that allows for its transport and sequestration or utilization and reduction in greenhouse gas emissions. The system and process result in improved access to gas pipelines for products, an improvement in the carbon intensity rating of the methane fuel, and improvements in generation of credits related to reductions in emissions of greenhouse gases.
Energy efficient process for separating hydrogen sulfide from gaseous mixtures using a hybrid solvent mixture
Disclosed is a process for regenerating a hybrid solvent used to remove contaminants from a fluid stream and to provide an improved yield of purified fluid. Said process comprises a purification unit (12) and at least one regeneration unit (40) wherein make-up water (72) is added to the regenerated lean hybrid solvent (55) prior to reuse in the first purification unit and no water is recycled into the regeneration unit.
Process and system for producing low carbon intensity renewable hydrogen
A process and/or system for producing fuel that includes providing biogas, removing carbon dioxide from the biogas, transporting the upgraded biogas to a hydrogen plant; providing the transported upgraded biogas and fossil-based natural gas as feedstock for hydrogen production. The carbon intensity of the fuel is less than 11 gCO.sub.2-eq/MJ, at least in part because carbon dioxide removed from the biogas and carbon dioxide from hydrogen production is captured and stored.
Power generation system
A power generation system comprises a fuel gas supply device 13 for controlling methane concentration or carbon dioxide concentration in a mixed gas MG containing methane and carbon dioxide within a setting range for the concentration in the fuel gas of a gas engine 11, and for supplying the mixed gas MG to the gas engine 11 as the fuel gas, and a gas concentration sensor 14 for measuring the carbon dioxide concentration or the methane concentration of the mixed gas MG. The fuel gas supply device 13 comprises a carbon dioxide removal device 16 for removing carbon dioxide in the mixed gas MG, and an operating condition control device 17 for controlling an operating condition that affects an increase or decrease of a carbon dioxide removal rate of the carbon dioxide removal device 16, and the operating condition control device 17 controls the operating condition of the carbon dioxide removal device 16 based on the measurement result of the gas concentration sensor 14, thereby controlling the concentration of methane and carbon dioxide in the mixed gas.
A DEVICE AND A PROCESS FOR SEPARATING METHANE FROM A GAS MIXTURE CONTAINING METHANE, CARBON DIOXIDE AND HYDROGEN SULFIDE
In a device for separating methane from a gas mixture containing methane, carbon dioxide and hydrogen sulfide, comprising a gas compressor, two or three membrane separation stages downstream of the compressor and a hydrogen sulfide adsorber, comprising a bed of activated carbon having catalytic activity for oxidizing hydrogen sulfide with oxygen, arranged upstream of the membrane separation stages, oxygen content and relative humidity can be adjusted for optimum adsorption capacity of the hydrogen sulfide adsorber by recycling permeate from the second membrane separation stage, which receives the retentate of the first membrane separation stage, to a point upstream of the hydrogen sulfide adsorber.
SYSTEM FOR PROCESSING OF BIOGAS TO PRODUCE ELECTRICITY IN FUEL CELLS
A system including biogas purification and provides biogas as feedstock to a solid oxide fuel cell. The biogas purification treatment process provides a polished biogas that is substantially free of carbonyl sulfides and hydrogen sulfide. The system uses a biogas treatment apparatus, that includes apparatus such as a packed columns, comprising copper oxide or potassium permanganate packing material, and an activated carbon component configured to treat the biogas by polishing it to remove carbonyl sulfides and deleterious trace residues, such as hydrogen sulfide, that were not removed by any prior bulk H2S removal steps. In addition, an oil removal device is used to remove any entrained fine oil droplets in the biogas. A polished biogas having in the range of 60% methane is charged to the fuel cell. Electricity generated may be fed into a grid or used directly as energy to charge electrical-powered vehicles, for example. Energy credits are tracked in real time and are appropriately assigned.
High selectivity polyimide/PES blend hollow fiber membrane for gas separations
A low cost, high selectivity asymmetric polyimide/polyethersulfone (PES) blend hollow fiber membrane, a method of making the membrane and its use for a variety of liquid, gas, and vapor separations such as deep desulfurization of gasoline and diesel fuels, ethanol/water separations, pervaporation dehydration of aqueous/organic mixtures, CO.sub.2/CH.sub.4, CO.sub.2/N.sub.2, H.sub.2/CH.sub.4, He/CH.sub.4, O.sub.2/N.sub.2, H.sub.2S/CH.sub.4, olefin/paraffin, iso/normal paraffins separations, and other light gas mixture separations. The polyimide/PES blend hollow fiber membrane is fabricated from a blend of a polyimide polymer and PES and showed surprisingly unique gas separation property with higher selectivities than either the polyimide hollow fiber membrane without PES polymer or the PES hollow fiber membrane without PES polymer for gas separations such as for H.sub.2/CH.sub.4, He/CH.sub.4, H.sub.2S/CH.sub.4, CO.sub.2/CH.sub.4 separations.
Process and plant for removing thiols from synthesis gas
The invention relates to a process and a plant for removing thiols from synthesis gas. Thiols and optionally thiophene and carbon disulfide are absorbed in a dedicated absorption stage with methanol as physical absorption medium. Methanol laden with at least thiols is freed of thiols in a stripping stage with methanol vapours as stripping gas and the methanol vapours-containing thiols are freed of methanol in a scrubbing stage. The process according to the invention minimizes methanol losses and the amounts of coolant required for the process.