The invention relates to a method for removing absorbable gases from pressurized industrial gases contaminated with absorbable gases, without supplying cooling energy. The method includes an industrial gas that is to be purified is purified by an absorbent solvent, the absorbable gases situated therein being removed by the solvent, and the loaded solvent is passed to a stripping stage in which the absorbed gas is desorbed again, and the desorbed gas is compressed, in such a manner that it is heated by the compression, whereupon it is cooled to standard temperature by means of cooling water or cooling air, then expanded, in such a manner that it cools and this cooled desorption gas is again returned to the industrial gas, in such a manner that said industrial gas is also cooled by the admixture.

Perforated graphene sheets can be used in forming separation membranes. Separation membranes of the present disclosure, which can be used in gas separation processes in some embodiments, can include one or more polymer layers and one or more layers of perforated graphene. Methods for separating a gas mixture can include contacting a gas mixture with the separation membranes, and transiting one or more of the gases through the perforated graphene so as to affect separation.

A methane (CH.sub.4) gas is synthesized from carbon dioxide (CO.sub.2) and hydrogen (H.sub.2) using catalyst-dielectric barrier discharge (DBD) plasma at room temperature and atmospheric pressure. In the method and apparatus for synthesizing methane gas of the invention, methane (CH.sub.4) gas, which is synthetic natural gas, can be effectively synthesized only from carbon dioxide (CO.sub.2) and hydrogen (H.sub.2) using DBD plasma at room temperature and atmospheric pressure, and also, additional heating and pressurization devices are not used during the methane gas synthesis process, thus reducing production costs and realizing high-value-added processing due to the absence of risks during the processing.

This disclosure relates to the adsorption and separation of nitrogen in a feed stream (e.g., natural gas) using zeolite ITQ-55 as the adsorbent. A process is disclosed for removing impurities such as nitrogen while producing a high pressure hydrocarbon product. The process involves passing the feed stream through a bed of an adsorbent comprising zeolite ITQ-55 to adsorb nitrogen from the feed stream, thereby producing a product stream depleted in nitrogen at pressure as feed condition without need of recompression. The zeolite ITQ-55 has a mean crystal particle size within the range of from about 0.01 microns to about 40 microns. The feed stream is exposed to the zeolite ITQ-55 at effective conditions for performing a kinetic separation, in which the kinetic separation exhibits greater kinetic selectivity for nitrogen than for methane. The system and method of this disclosure are particularly suitable for use with feed streams utilizing rapid cycle PSA operations.

A process and/or system for producing fuel that includes providing biogas, removing carbon dioxide from the biogas, transporting the upgraded biogas to a hydrogen plant; providing the transported upgraded biogas and fossil-based natural gas as feedstock for hydrogen production. The carbon intensity of the fuel is less than 11 gCO.sub.2-eq/MJ, at least in part because carbon dioxide removed from the biogas and carbon dioxide from hydrogen production is captured and stored.

A system and method for treating natural gas, including producing natural gas from a subterranean formation via a wellhead system to a nonthermal plasma (NTP) catalytic unit, converting by the NTP unit carbon dioxide (CO.sub.2) and hydrogen sulfide (H.sub.2S) in the natural gas into carbon monoxide (CO), elemental sulfur (S), and hydrogen (H.sub.2), and removing the elemental sulfur as liquid elemental sulfur to give treated natural gas. The NTP unit may convert methane (CH.sub.4) in the natural gas to heavier hydrocarbons.

A membrane system includes a first membrane and a second membrane. At a given temperature and pressure: the first membrane has a permeation rate for a first gas and a selectivity for a gas mixture comprising the first gas a second gas different from the first gas; the second membrane has a permeation rate for the first gas and a selectivity for the gas mixture; the permeation rate of the first membrane is greater than the permeation rate of the second membrane; and the selectivity of the second membrane is greater than the selectivity of the first membrane.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve performing a startup mode process prior to beginning a normal operation mode process to remove contaminants from a gaseous feed stream. The startup mode process may be utilized for swing adsorption processes, such as TSA and/or PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

A system including biogas purification and provides biogas as feedstock to a solid oxide fuel cell. The biogas purification treatment process provides a polished biogas that is substantially free of carbonyl sulfides and hydrogen sulfide. The system uses a biogas treatment apparatus, that includes apparatus such as a packed columns, comprising copper oxide or potassium permanganate packing material, and an activated carbon component configured to treat the biogas by polishing it to remove carbonyl sulfides and deleterious trace residues, such as hydrogen sulfide, that were not removed by any prior bulk H2S removal steps. In addition, an oil removal device is used to remove any entrained fine oil droplets in the biogas. A polished biogas having in the range of 60% methane is charged to the fuel cell. Electricity generated may be fed into a grid or used directly as energy to charge electrical-powered vehicles, for example. Energy credits are tracked in real time and are appropriately assigned.

An adsorption material is disclosed that comprises a metal-organic framework and a plurality of ligands. The metal-organic framework comprising a plurality of metal ions. Each respective ligand in the plurality of ligands is amine appended to a respective metal ion in the plurality of metal ions of the metal-organic framework. Each respective ligand in the plurality of ligands comprises a substituted 1,3-propanediamine. The adsorbent has a CO.sub.2 adsorption capacity of greater than 2.50 mmol/g at 150 mbar CO.sub.2 at 40° C. Moreover, the adsorbent is configured to regenerate at less than 120° C. An example ligand is diamine 2,2-dimethyl-1,3-propanediamine. An example of the metal-organic framework is Mg.sub.2(dobpdc), where dobpdc.sup.4− is 4,4′-dioxidobiphenyl-3,3′-dicarboxylate. Example applications for the adsorption material are removal of carbon dioxide from flue gas and biogasses.