The disclosure is to provide a method for producing a core-shell catalyst that is able to increase the power generation performance of a membrane electrode assembly. A dispersion is prepared, in which a palladium-containing particle support, in which palladium-containing particles are supported on an electroconductive support, is dispersed in water; hydrogen gas is bubbled into the dispersion; the palladium-containing particles are acid treated after the bubbling; copper is deposited on the surface of the palladium-containing particles by applying a potential that is nobler than the oxidation reduction potential of copper to the palladium-containing particles in a copper ion-containing electrolyte after the acid treatment; and then a shell is formed by substituting the copper deposited on the surface of the palladium-containing particles with platinum by bringing the copper deposited on the surface of the palladium-containing particles into contact with a platinum ion-containing solution.

A method for manufacturing a semiconductor device includes: forming a first major electrode on a first major surface of a semiconductor substrate; forming a second major electrode on a second major surface of the semiconductor substrate opposite to the first major surface; carrying out a surface activating treatment to activate surfaces of the first and second major electrodes; carrying out a surface cleaning treatment to clean up the surfaces of the first and second major electrodes; and after the surface activating treatment and the surface cleaning treatment, simultaneously forming first and second Ni films on the first and second major electrodes respectively by a wet film forming method, wherein a ratio of crystalline Ni contained in the first and second Ni films is 2% or more.

The present invention is directed to a composition for depositing a palladium coating on an activated copper-coated substrate, the composition comprising: (i) palladium ions, (ii) chloride ions, (iii) ethylenediamine (EDA), (iv) ethylenediamine disuccinate (EDDS), and (v) at least one reducing agent,
wherein the composition has a pH in a range from 7.5 to 9.5, preferably from 7.6 to 9.1, more preferably from 7.7 to 8.7, and most preferably from 7.8 to 8.5.