A method for preparing a COF-protected electrode and an electrode are provided. The method includes mixing an organic framework, a small molecular organic acid and a solvent, adding a polar aqueous solution containing a substrate thereto, mixing the above uniformly and heating the system at a low temperature under an inert atmosphere, filtering the solution to obtain precipitates, washing and drying the precipitates to obtain a COF film grown on a surface of the substrate; coating a protective layer on the COF film to obtain a substrate/COF/protective layer film; etching off the substrate to obtain a COF/protective layer film; and transferring the COF/protective layer film to a surface of the electrode, and removing the protective layer.

To provide an oxygen and hydrogen production technology that is novel, convenient, and environmentally suitable, and decomposes water at a high rate. Based on the finding that an aromatic amine polymer acts as an oxidation catalyst that generates oxygen from water and a polyarylenevinylene acts as a reduction catalyst that generates hydrogen from water, oxygen and hydrogen are generated at a high rate by applying a slight overpotential relative to an equilibrium potential because these catalysts operate at a very low overpotential. Further, irradiation of the water-oxidation?oxygen-generation catalyst with light including solar light increases a production rate of oxygen and hydrogen. The aromatic amine polymer and the polyarylenevinylene are both aromatic polymers, are low cost, and have considerably high durability in water over a wide pH range and in addition, they may have hydrophilicity or hydrophobicity, interface area, and shape suited for electrode catalysts.

To provide an oxygen and hydrogen production technology that is novel, convenient, and environmentally suitable, and decomposes water at a high rate. Based on the finding that an aromatic amine polymer acts as an oxidation catalyst that generates oxygen from water and a polyarylenevinylene acts as a reduction catalyst that generates hydrogen from water, oxygen and hydrogen are generated at a high rate by applying a slight overpotential relative to an equilibrium potential because these catalysts operate at a very low overpotential. Further, irradiation of the water-oxidation?oxygen-generation catalyst with light including solar light increases a production rate of oxygen and hydrogen. The aromatic amine polymer and the polyarylenevinylene are both aromatic polymers, are low cost, and have considerably high durability in water over a wide pH range and in addition, they may have hydrophilicity or hydrophobicity, interface area, and shape suited for electrode catalysts.

The present disclosure generally relates to the field of chemical sciences and negative emission technology. The disclosure further relates to a process for converting carbon dioxide into methanol by employing quantum imprinted nanomaterials (containing nanozymes) via electrochemical reduction. The disclosure furthermore relates to an electrochemical cell which has the capability of converting carbon dioxide to methanol, wherein the electrochemical cell comprises an anode comprising Zn quantum material and a cathode comprising nano quartz coated with nanozyme(s) incorporated printed polymer with selective 3D imprinted memory for carbon dioxide electrochemical reduction.

The present disclosure generally relates to the field of chemical sciences and negative emission technology. The disclosure further relates to a process for converting carbon dioxide into methanol by employing quantum imprinted nanomaterials (containing nanozymes) via electrochemical reduction. The disclosure furthermore relates to an electrochemical cell which has the capability of converting carbon dioxide to methanol, wherein the electrochemical cell comprises an anode comprising Zn quantum material and a cathode comprising nano quartz coated with nanozyme(s) incorporated printed polymer with selective 3D imprinted memory for carbon dioxide electrochemical reduction.

A method for preparing a COF-protected electrode and an electrode are provided. The method includes mixing an organic framework, a small molecular organic acid and a solvent, adding a polar aqueous solution containing a substrate thereto, mixing the above uniformly and heating the system at a low temperature under an inert atmosphere, filtering the solution to obtain precipitates, washing and drying the precipitates to obtain a COF film grown on a surface of the substrate; coating a protective layer on the COF film to obtain a substrate/COF/protective layer film; etching off the substrate to obtain a COF/protective layer film; and transferring the COF/protective layer film to a surface of the electrode, and removing the protective layer.

A method for preparing a COF-protected electrode and an electrode are provided. The method includes mixing an organic framework, a small molecular organic acid and a solvent, adding a polar aqueous solution containing a substrate thereto, mixing the above uniformly and heating the system at a low temperature under an inert atmosphere, filtering the solution to obtain precipitates, washing and drying the precipitates to obtain a COF film grown on a surface of the substrate; coating a protective layer on the COF film to obtain a substrate/COF/protective layer film; etching off the substrate to obtain a COF/protective layer film; and transferring the COF/protective layer film to a surface of the electrode, and removing the protective layer.

An electrolytic device includes: an electrolysis cell including: an anode; a cathode; a first flow path plate facing on the anode, the first flow path plate having a first recess defining an anode flow path through which a first liquid flows; a second flow path plate facing on the cathode, the second flow path plate having a second recess defining a cathode flow path through which a first gas flows; and a separator provided between the anode and the cathode. The second flow path plate has an uneven surface on an inner surface of the second recess. An arithmetic mean roughness of the uneven surface is 0.03 ?m or more and 50 ?m or less.

The present disclosure generally relates to apparatuses, systems, and methods for separating a target species (e.g., CO.sub.2) from a gas mixture (e.g., gas stream) via an electrochemical process.

An electrochemical cell comprises an anode, an anode electrolyte solution in contact with the anode, wherein the anode electrolyte solution has a first pH, a cathode comprising an ionomer, a cathode electrolyte solution in contact with the cathode wherein the cathode electrolyte solution has a second pH, and a separator positioned between the anode and the cathode, wherein the electrochemical cell is configured to maintain a pH differential between the first pH and the second pH.