A platform technology that uses a novel membrane electrode assembly, including a cathode layer, an anode layer, a membrane layer arranged between the cathode layer and the anode layer, the membrane conductively connecting the cathode layer and the anode layer, in a CO.sub.x reduction reactor has been developed. The reactor can be used to synthesize a broad range of carbon-based compounds from carbon dioxide and other gases containing carbon.

Methods, apparatuses, and systems related to the electrochemical separation of target gases from gas mixtures are provided. In some cases, a target gas such as carbon dioxide is captured and optionally released using an electrochemical cell (e.g., by bonding to an electroactive species in a reduced state). Some embodiments are particularly useful for selectively capturing the target gas while reacting with little to no oxygen gas that may be present in the gas mixture. Some such embodiments may be useful in applications involving separations from gas mixtures having relatively low concentrations of the target gas, such as direct air capture and ventilated air treatment.

Methods, apparatuses, and systems related to the electrochemical separation of target gases from gas mixtures are provided. In some cases, a target gas such as carbon dioxide is captured and optionally released using an electrochemical cell (e.g., by bonding to an electroactive species in a reduced state). Some embodiments are particularly useful for selectively capturing the target gas while reacting with little to no oxygen gas that may be present in the gas mixture. Some such embodiments may be useful in applications involving separations from gas mixtures having relatively low concentrations of the target gas, such as direct air capture and ventilated air treatment.

Nation-modified electrodes for the CO.sub.2 reduction reaction (CO.sub.2RR) to hydrocarbon products. Depending on the thickness of the Nation membrane and its admixture with other polymers, CO.sub.2 reduction occurs principally at the electrode-polymer interface. A Nation overlayer of 15 μm on a Cu electrode enables an extraordinarily high yield of CH.sub.4 production (88% Faradaic efficiency) at a low overpotential (540 mV). Other embodiments directed to admixtures of Nation and other polymers and/or cocatalysts, various metal substrates and electrolyte solutions which comprise an aprotic solvent in addition to a bicarbonate solution show impact on the Faradaic efficiency, yield and carbon-based products produced by the present invention.

A composite material made of an amorphous (bi)metal sulfide nanoparticles directly linked, through coordinate covalent bonds, to a sulfur-containing polymer and a method of preparation of the composite material. The composite material can also be used as a catalyst for hydrogen production. Finally, a proton-exchange membrane (PEM) electrolyser and a photoelectrochemical cell, can both including the composite material.

This disclosure relates to graphene derivatives, as well as related devices including graphene derivatives and methods of using graphene derivatives.

Solution-phase (e.g., homogeneous) or surface-immobilized (e.g., heterogeneous) electrode-driven oxidation catalysts based on iridium coordination compounds which self-assemble upon chemical or electrochemical oxidation of suitable precursors and methods of making and using thereof are. Iridium species such as {[Ir(LX).sub.x(H.sub.2O).sub.y(μ-O)].sub.z.sup.m+}.sub.n wherein x, y, m are integers from 0-4, z and n from 1-4 and LX is an oxidation-resistant chelate ligand or ligands, such as such as 2(2-pyridyl)-2-propanolate, form upon oxidation of various molecular iridium complexes, for instance [Cp*Ir(LX)OH] or [(cod)Ir(LX)] (Cp*=pentamethylcyclopentadienyl, cod=cis-cis,1,5-cyclooctadiene) when exposed to oxidative conditions, such as sodium periodate (NaIO.sub.4) in aqueous solution at ambient conditions.

The present invention is directed to an anode including bacteria, a polymer, and a conductive material, wherein the bacteria, the polymer and the conductive material are deposited on at least one surface of the anode. Further provided is a microbial electrochemical system comprising the herein disclosed anode, and methods of using the same, such as for treating wastewater, hydrogen production, or generating electricity.

An organic carbonate synthesis catalyst for electrochemically synthesizing an organic carbonate from carbon monoxide, comprises: an active particle containing a metal element; and a porous carbon supporting the active particle.

Photoelectrochemical cells including a cathode including alpha-hematite and a metal dichalcogenide, an anode including a conducting polymer, and an electrolyte.