An electrochemical cell including a first chamber having an anode, a second chamber having a cathode, at least one ionic connection between the first chamber and the second chamber, such that liquid electrolyte from the first chamber is prevented from mixing with liquid electrolyte in the second chamber is provided. The first chamber and the second chamber can be arranged in parallel and positioned remotely from each other. An electrochemical system including the electrochemical cell, and first and second sources of saline aqueous solutions is also provided. Water treatment systems are also provided. A method of operating an electrochemical cell including introducing first and second saline aqueous solutions into first and second chambers of the electrochemical cell, and applying a current across the anode and the cathode to generate first and second products, respectively is also provided. A method of facilitating operation of an electrochemical cell is also provided.

A method of operating an electrochemical cell including introducing an aqueous solution into the electrochemical cell, applying a current across an anode and a cathode to produce a product, monitoring the voltage, dissolved hydrogen, or a condition of the aqueous solution, and applying the current in a pulsed waveform responsive to one of the measured parameters is disclosed. An electrochemical system including an electrochemical cell including an anode and a cathode, a source of an aqueous solution having an outlet fluidly connectable to the electrochemical cell, a sensor for measuring a parameter, and a controller configured to cause the anode and the cathode to apply the current in a pulsed waveform responsive to the parameter measurement is disclosed. Methods of suppressing accumulation of hydrogen gas within the electrochemical cell are also disclosed. Methods of facilitating operation of an electrochemical cell are also disclosed.

A method, a system, and an apparatus of certain embodiments are provided to recover water and carbon dioxide from combustion emissions. The recovery includes, among other things, electrolysis and carbon dioxide capture in a suitable solvent. The recovered water and carbon dioxide are subject to reaction, such as a catalytic methanation reaction, to generate at least methane.

Disclosed herein are methods and systems that relate to electrochemically producing hydrogen gas by maintaining a steady-state pH differential of greater than 1 between an anode electrolyte and a cathode electrolyte in a hydrogen-gas generating electrochemical cell.

A method for electrolysis, wherein an anolyte is brought into contact with an anode, and a catholyte is brought into contact with a cathode, wherein the anolyte contains hydroxide ions and the catholyte contains an auxiliary, wherein an electrical voltage is applied between the anode and the cathode such that the hydroxide ions in the anolyte are oxidized at the anode and the auxiliary in the catholyte is reduced at the cathode, and wherein H2O and the reduced auxiliary are brought into contact with a catalyst such that the reduced auxiliary is oxidized and hydrogen is formed from the H2O. By means of the auxiliary, the electrolysis can be carried out under low pressure, and hydrogen can still be obtained at high pressure. This facilitates the construction of the electrolytic cell and prevents an efficiency-reducing gas cross-permeation.

A method for electrolysis, wherein an anolyte is brought into contact with an anode, and a catholyte is brought into contact with a cathode, wherein the anolyte contains hydroxide ions and the catholyte contains an auxiliary, wherein an electrical voltage is applied between the anode and the cathode such that the hydroxide ions in the anolyte are oxidized at the anode and the auxiliary in the catholyte is reduced at the cathode, and wherein H2O and the reduced auxiliary are brought into contact with a catalyst such that the reduced auxiliary is oxidized and hydrogen is formed from the H2O. By means of the auxiliary, the electrolysis can be carried out under low pressure, and hydrogen can still be obtained at high pressure. This facilitates the construction of the electrolytic cell and prevents an efficiency-reducing gas cross-permeation.

A method of operating an electrochemical cell including introducing an aqueous solution into the electrochemical cell, applying a current across an anode and a cathode to produce a product, monitoring the voltage, dissolved hydrogen, or a condition of the aqueous solution, and reversing polarity of the anode and the cathode responsive to one of the measured parameters is disclosed. An electrochemical system including an electrochemical cell including an anode and a cathode, a source of an aqueous solution having an outlet fluidly connectable to the electrochemical cell, a sensor for measuring a parameter, and a controller configured to cause the anode and the cathode to reverse polarity responsive to the parameter measurement is disclosed. Methods of suppressing accumulation of hydrogen gas within the electrochemical cell are also disclosed. Methods of facilitating operation of an electrochemical cell are also disclosed.

The embodiments provide an eco-friendly carbon dioxide fixation method and a system for carrying out the method. The carbon dioxide fixation method according to the embodiment includes: immersing a magnesium alloy in an aqueous solvent; blowing carbon dioxide-containing gas into the aqueous solvent; and electrically energizing and thereby subjecting the aqueous solvent to electrolysis treatment so as to produce precipitates containing magnesium carbonate. This method can be carried out in a system having: a treating bath for storing a magnesium alloy and an aqueous solvent to treat a magnesium alloy in which said magnesium alloy is treated, a gas-introducing unit for blowing carbon dioxide-containing gas into the aqueous solvent, a pair of electrodes for applying voltage to the aqueous solvent so as to conduct electrolysis treatment, and a power control unit connected to the electrodes.

Provided is an operation assistance apparatus including: a production amount acquisition unit which acquires a target production amount of a product produced in a predetermined period by one electrolyzer or a plurality of electrolyzers; a production amount calculation unit which calculates a maximum production amount of the product when an ion exchange membrane included in the one electrolyzer or the plurality of electrolyzers is updated, the maximum production amount being a maximum production amount of the product produced in the period by the one electrolyzer or the plurality of electrolyzers; and a period specification unit which specifies the period during which the maximum production amount becomes equal to or more than the target production amount.

Provided is an operation assistance apparatus including: a production amount acquisition unit which acquires a target production amount of a product produced in a predetermined period by one electrolyzer or a plurality of electrolyzers; a production amount calculation unit which calculates a maximum production amount of the product when an ion exchange membrane included in the one electrolyzer or the plurality of electrolyzers is updated, the maximum production amount being a maximum production amount of the product produced in the period by the one electrolyzer or the plurality of electrolyzers; and a period specification unit which specifies the period during which the maximum production amount becomes equal to or more than the target production amount.