A flow-through electrochemical reactor includes a housing having a solution flow-path. A flow-through or solid first electrode is disposed within the solution flow path. A second electrode is spaced apart from the flow-through or solid first electrode, thereby creating an electroactive gap between the flow-through or solid first electrode and the second electrode. The electroactive gap is less than 5 mm and greater than 2 mm.

Various embodiments relate to an electrochemical cell for removal of materials from water and methods of using the same. A method of removing phosphorus from water includes immersing an electrochemical cell in water including phosphorus to form treated water including a salt that includes the phosphorus. The electrochemical cell includes an anode including Mg, Al, Fe, Zn, or a combination thereof, a cathode including Cu, Ni, Fe, or a combination thereof. The method includes separating the salt including the phosphorus from the treated water, to form separated water having a lower phosphorus concentration than the water including phosphorus.

An electrode apparatus for removing contaminants from a fluid is provided. In another aspect, an electrochemical destruction apparatus for wastewater effluent using Boron-doped diamond electrodes is employed. A further aspect of the present apparatus includes a fluid-carrying conduit, electrodes located within the conduit, an electrical controller connected to the electrodes, a sensor connected to the controller being adapted to sense a chemical characteristic associated with contaminants in the fluid, and the controller automatically varying an electrical characteristic associated with at least one of the electrodes based, at least in part, on an input from the sensor. Yet another aspect includes a programmable controller and software which automatically employ a feedback control loop to increase or decrease electrical current density to contaminant-removing electrodes.

A microbial electrochemical cell is described herein. The cell includes an anode electrode disposed in an anoxic environment below a water surface. The anode receives electrons from anaerobic decomposition of organic matter or other reduced compounds by microbes in sediment below the water surface. The cell also includes a cathode electrode disposed in an environment at a higher electrochemical potential than the anoxic environment. The cathode is electrically connected to the anode to receive the electrons from the anode. A reference electrode is disposed in the environment at the higher electrochemical potential than the anoxic environment. A potentiostat is electrically connected to each of the anode, the cathode and the reference electrode and is configured to receive electrons from the anode and control distribution of the electrons to the cathode based on a potential difference between the anode and the reference electrode. Methods of remediating aquaculture sediment are also described.

Disclosed is a treatment reactor for treating a continuously flowing liquid, comprising: an inlet for receiving liquid to be treated; and an outlet for outputting the treated liquid, whereby the liquid flows from the inlet to the outlet, wherein the reactor comprises an electrolysis unit arranged to subject the flowing liquid to electrolysis, and a microwave unit arranged to subject the flowing liquid to a microwave field.

A denitrification system for removing nitrates in a water body by electrocatalytic hydrogen evolution and catalytic hydrogenation is disclosed. The denitrification system includes an electrolytic cell and a three-electrode system inserted into the electrolytic cell. The electrolytic cell contains electrolyte solution, and the denitrification catalyst is dispersed and suspended in the electrolyte solution. The three-electrode system includes a working electrode, a counter electrode and a reference electrode. The counter electrode adopts Pt sheet, the working electrode adopts the catalyst Ni.sub.3S.sub.2—NF, and the preparation steps of the catalyst Ni.sub.3S.sub.2—NF are as follows: (i) cutting a certain size nickel mesh and cleaning it; (ii) adding the cleaned nickel mesh into thiourea solution; (iii) reacting under hydrothermal conditions, and washing and drying to obtain the catalyst Ni.sub.3S.sub.2—NF. The invention avoids the hazards of storing and transporting hydrogen storage and realizes the efficient removal of nitrate in water by electrocatalytic hydrogen evolution and catalytic hydrogenation.

Disclosed are a deionization electrode having ion adsorption layers and ion selective membranes formed at opposite ends thereof, an electrode module configured such that deionization electrodes are stacked, and a deionization unit having electrode modules received therein to separate ions from water. The deionization electrode includes a current collector configured to have a circular flat structure, the current collector having a first hole formed therein, a first porous adsorption layer located on one surface of the current collector, the first adsorption layer being configured to have a flat structure, a second porous adsorption layer located on the other surface of the current collector, the second adsorption layer being configured to have a flat structure, a first ion selective membrane located on the surface of the first adsorption layer, and a second ion selective membrane located on the surface of the second adsorption layer.

A novel cell for generating ozonated water, the cell comprises a nafion membrane separating a diamond coated anode, and a gold surfaced cathode enclosed within a cell housing with the catalyst side of the nafion membrane facing the cathode. The cell housing has a cathode housing portion and an anode housing portion separated by the membrane, each housing portion having ridges to enhance substantially even flow of fluid over the cathode and anode. The housing portions contain O-rings in grooves to prevent leaks, and alignment features to keep the electrodes aligned. The cathode and anode have an array of holes allowing fluid to penetrate to the surface of the niobium membrane. Input ports allow fluid to flow into the housing and over the anode and cathode and then out of the housing through outlet ports. The housing may also incorporate an integrated spectral photometer including a bubble trap.

A hydrogen peroxide water manufacturing device includes an ejector unit including an introduction-side diameter-increasing portion to which water to be treated is introduced, a nozzle portion connected to the introduction-side diameter-increasing portion and having an introduction opening to which a source gas containing oxygen gas is introduced from outside, on a side wall, and a discharge-side diameter-increasing portion that is connected to the nozzle portion and from which the water to be treated mixed with the source gas is discharged, and an electrolysis unit disposed downstream of the ejector unit and including electrolytic electrodes to electrolyze the discharged water to be treated mixed with the source gas and generate hydrogen peroxide by using the source gas as a source.

Various embodiments relate to methods and systems for removing phosphorus and/or nitrogen from water. A method of removing phosphorus and nitrogen from water includes passing starting material water including nitrogen and phosphorus through an elevated pH phosphorus removal stage. The method includes passing the water through an electrolytic nitrogen removal stage. The method includes passing the water through a galvanic phosphorus removal stage. The water produced by the method has a lower phosphorus concentration and a lower nitrogen concentration than the starting material water.