Provided is a material set for forming a three-dimensional object, the material set including: a first liquid material for forming a three-dimensional object; and a second liquid material for forming a three-dimensional object, wherein the first liquid material contains a solvent, an organic compound A, and inorganic particles, and wherein the second liquid material contains an organic compound B having reactivity with the organic compound A.

A moldable green-body composite includes milling silicon nitride powder with a solvent and adding a surface modifier to the milled slurry to modify a surface of the silicon nitride particles. A polysiloxane in a solvent and a binder are also added to create a green body slurry. The solvents may be polar or non-polar solvents. A sintering aid, such as yttria-alumina, may be added to the slurry as well. A reduced density silicon nitride ceramic is made from the moldable green-body composite by molding the moldable green-body composite in a mold and curing at a curing temperature to convert the moldable green-body composite to a converted composite. The converted composite can then be sintered to form a reduced density silicon nitride ceramic that has a smooth surface finish and requires no post machining or polishing. The reduced density silicon nitride ceramic may also have very good dielectric properties.

Methods of making ceramic matrix prepregs are described. The methods include exposing a coated tow of ceramic fibers to a ceramic matrix slurry comprising a solvent and ceramic precursor. The coating is at least partially removed and the slurry infuses into the ceramic fibers to form prepreg. Steps to form ceramic matrix composites are also described, including forming the prepreg into a green body, and sintering the ceramic precursor.

Composites with high thermal conductivities and high loadings of hexagonal boron nitride particles in an organic polymer matrix are provided. Also provided are thermally conductive, electrically insulating coatings for magnet wires made from the composites and thermally conductive, electrically insulating infills for windings made from the composites.

An ink, and products formed from the ink, formulated at least in part from ceramic particles. The ink is formulated so that it can be used in additive manufacturing processes to form three-dimensional printed bodies. The three-dimensional printed bodies can have graded density and can be infiltrated by an infiltration material.

Green ceramic batch mixtures include at least one inorganic batch component, at least one organic binder, and a water-in-oil emulsion including at least one lubricant, at least one aqueous solvent, and at least one emulsifier. Methods for forming ceramic bodies include forming a green ceramic batch mixture including a water-in-oil emulsion and extruding the green ceramic batch mixture. The methods and batch mixtures can be used to produce green and fired ceramic bodies.

The present application discloses and claims a method to make a flexible ceramic fibers (Flexiramics) and polymer composites. The resulting composite has an improved mechanical strength (tensile) when compared with the Flexiramics respective the nanofibers alone. Additionally a composite has better properties than the polymer alone such as lower fire retardancy, higher thermal conductivity and lower thermal expansion. Several different polymers can be used, both thermosets and thermoplastics. Flexiramics has unique physical characteristic and the composite materials can be used for numerous industrial and laboratory applications.

Pre-ceramic particle solutions can prepared by a Coordinated-PDC process, a Direct-PDC process or a Coordinated-Direct-PDC process. The pre-ceramic particle solution includes a polymer selected from the group consisting of (i) an organic polymer including a metal or metalloid cation, (ii) a first organometallic polymer and (iii) a second organometallic polymer including a metal or metalloid cation different from a metal in the second organometallic polymer, a plurality of particles selected from the group consisting of (a) a ceramic fuel particle and (b) a moderator particle, a dispersant, and a polymerization initiator. The pre-ceramic particle solution can be supplied to an additive manufacturing process, such as digital light projection, and made into a structure (which is pre-ceramic particle green body) that can then be debinded to form a polymer-derived ceramic sintered body. In some embodiments, the polymer-derived ceramic sintered body is a component or structure for fission reactors.

A composition including a binder and a variable thermal conductivity material satisfying a conditional expression 1, wherein a content of the variable thermal conductivity material is from 300 parts by weight to 10,000 parts by weight with respect to a content of 100 parts by weight of the binder:

.sub.max/.sub.251.2[conditional expression 1] (wherein, .sub.25 represents a thermal conductivity at 25 C., and .sub.max represents the maximum value of a thermal conductivity at 200 C. or 500 C.)

This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.