Provided is a piezoelectric material that is free of lead and potassium, has satisfactory insulation property and piezoelectricity, and has a high Curie temperature. The piezoelectric material includes a perovskite-type metal oxide represented by the following general formula (1): General formula (1) (Na.sub.xM.sub.1-y)(Zr.sub.z(Nb.sub.1-wTa.sub.w).sub.y(Ti.sub.1-vSn.sub.v).sub.(1-y-z))O.sub.3 where M represents at least any one of Ba, Sr, and Ca, and relationships of 0.80≦x≦0.95, 0.85≦y≦0.95, 0<z≦0.03, 0≦v<0.2, 0≦w<0.2, and 0.05≦1−y−z≦0.15 are satisfied.

A bismuth and magnesium co-doped lithium niobate crystal includes Li.sub.2CO.sub.3, Nb.sub.2O.sub.5, Bi.sub.2O.sub.3 and MgO, wherein the molar ratio of [Li] and [Nb] is 0.90-1.00, the molar percentage of Bi.sub.2O.sub.3 in the mixture is 0.25-0.80%, and the molar percentage of MgO in the mixture is 3.0-7.0%. The bismuth and magnesium co-doped lithium niobate crystal has enhanced photorefraction, improved photorefractive sensitivity, shortened holographic grating saturation writing time, and the photorefractive diffraction efficiency can reach up to 17%. The response time is only 170 ms, when the holographic storage experiment is carried out using 488 nm continuous laser. Therefore, this crystal can be used in the field of holographic imaging.

The present invention discloses a dielectric ceramic formula enabling one to obtain a multilayer ceramic capacitor by alternatively stacking the ceramic dielectric layers and base metal internal electrodes. The dielectric ceramic composition comprises a primary ingredient:

[(Na.sub.1-xK.sub.x).sub.sA.sub.1-s].sub.m[(Nb.sub.1-yTa.sub.y).sub.uB1.sub.vB2.sub.w)]O.sub.3

wherein:
A is at least one selected from the alkaline-earth element group of Mg, Ca, Sr, and Ba;
B1 is at least one selected from the group of Ti, Zr, Hf and Sn;
B2 is at least one selected from transition metal elements;
and wherein:
x, y, s, u, v, and w are molar fractions of respective elements, and m is the molar ratio of [(Na.sub.1-xK.sub.x).sub.sA.sub.1-s] and [(Nb.sub.1-yTa.sub.y).sub.uB1.sub.vB2.sub.w)]. They are in the following respective range:
0.93≤m≤1.07;
0.7≤s≤1.0;
0.00≤x≤0.05; 0.00≤y≤0.65;
0.7≤u≤1.0; 0.0≤v≤0.3; 0.001≤w≤0.100;
a first sub-component composes of at least one selected from the rare-earth compound,
wherein the rare-earth element is no more than 10 mol % parts with respect to the main component; and
a second sub-component composes a compound with low melting temperature to assist the ceramic sintering process, said frit, which is Li free and could be at least one selected from fluorides, silicates, borides, and oxides. The content of frit is within the range of 0.01 mol % to 15.00 mol % parts with respect to the main component.

This invention relates to a multilayer ceramic capacitor produced by alternatively stacking the ceramic dielectric layers and internal electrodes mainly comprise base metals. The present dielectric ceramic composition having a main component with a perovskite structure ABO.sub.3 formula of:

(K.sub.xNa.sub.yLi.sub.zA.sub.1-x-y-z).sub.m(Nb.sub.uTa.sub.vB.sub.w)O.sub.3

wherein:
A is at least one selected from the alkaline earth element group of Ca, Sr, and Ba;
B is at least one selected from the group of Ti, Zr, Hf and Sn;
and wherein:
x, y, z, u, v, and w are molar fractions of respective elements, and m is the molar ratio of A-site and B-site elements. They are in the following respective range:
0.95≤m≤1.05;
0.05≤x≤0.90; 0.05≤y≤0.90; 0.00≤z≤0.12
0<u<1; 0.0≤w≤0.3; u+v+w=1
The dielectric ceramic composition further contains:
a first accessory ingredient composes at least one selected from the rare-earth compounds, wherein the rare-earth element is no more than 10 mole parts with respect to 100 mole parts of the main component; a second accessory ingredient composes at least one selected from transition metal compounds, wherein the transition metal element is in the range of 0.05 mole to 10.00 mole parts with respect to 100 mole parts of the main component; and a third accessory ingredient composes a compound with low melting temperature to assist the ceramic sintering process, which is within the range of 0.01 mole to 15 mole parts with respect to 100 mole parts of the main component.

A piezoelectric composition having a complex oxide including potassium and niobium, in which the complex oxide has a first phase represented by a compositional formula KNbO.sub.3, and one or two phases selected from a second phase represented by a compositional formula K.sub.4Nb.sub.6O.sub.17 and a third phase represented by a compositional formula KNb.sub.3O.sub.8.

Disclosed herein are embodiments of materials having high thermal conductivity along with a high dielectric constants. In some embodiments, a two phase composite ceramic material can be formed having a contiguous aluminum oxide phase with a secondary phase embedded within the continuous phase. Example secondary phases include calcium titanate, strontium titanate, or titanium dioxide.

Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

A method that incorporates teachings of the subject disclosure may comprise, for example, selecting a barium-strontium-titanate (BST) material, wherein the BST material has a perovskite lattice structure with at least a first lattice constant and a second lattice constant; selecting a strontium-barium-niobate (SBN) material, wherein the SBN material has a lattice structure with at least a third lattice constant and a fourth lattice constant, wherein the third lattice constant is substantially equal to the first lattice constant, and wherein the fourth lattice constant is substantially equal to the second lattice constant; and growing, on a grain boundary region of the BST material, the SBN material, wherein the growing is via self-assembly, and wherein the growing is facilitated by the third lattice constant of the SBN material being substantially equal to the first lattice constant and the fourth lattice constant of the SBN material being substantially equal to the second lattice constant. Other embodiments are disclosed.

Disclosed are embodiments of high Q modified materials. In some embodiments, complex tungsten oxides and/or hexagonal perovskite crystal structures can be added to provide for advantageous properties. In some embodiments, no tin is used in the formation of the material.

The present disclosure belongs to the field of preparation technology and provides an ultralimit alloy and a preparation method therefor. The ultralimit alloy comprises an alloy matrix. A bonding layer and a ceramic layer are successively deposited on a surface of the alloy matrix. The alloy matrix includes one of a magnesium alloy matrix, an aluminium alloy matrix, a titanium alloy matrix, an iron alloy matrix, a nickel alloy matrix, a copper alloy matrix, a zirconium alloy, and a tin alloy. For an ultralimit magnesium alloy, an ultralimit aluminium alloy, an ultralimit nickel alloy, an ultralimit titanium alloy, an ultralimit iron alloy and an ultralimit copper alloy, the bonding layer is a composite bonding layer, the ceramic layer is a composite ceramic layer, and the outside of the composite ceramic layer is further successively deposited with a reflecting layer, a catadioptric layer, an insulating layer and a carbon foam layer.