A mix for the manufacture of ceramic articles comprising at least two of the following components a frit comprising silicon dioxide present in a concentration by weight, evaluated with respect to the total weight of the frit, comprised between 30% and 75%; calcium oxide or magnesium oxide present in a concentration by weight, evaluated with respect to the total weight of the frit, comprised between 0.01% and 50%; aluminum oxide, present in a concentration by weight, evaluated with respect to the total weight of the frit, comprised between 0.01% and 30%; one or more flux materials comprising tectosilicates; one or more binding materials comprising phyllosilicates.

A particulate mixture, suitable for use in ceramic article production, wherein the mixture includes from 30 wt % to 80 wt % recycled aluminium silicate material. The particulate mixture has a particle size distribution such that: (i) the d.sub.50 particle size is from 10 μm to 30 μm; (ii) the d.sub.70 particle size is less than 40 μm; and (iii) the d.sub.98 particle size is less than 60 μm.

A process for the production of a ceramic article includes the steps of: (a) preparing a particulate mixture; (b) contacting the particulate mixture to water to form a humidified mixture; (c) pressing the humidified mixture to form a green article; (d) optionally, subjecting the green article to an initial drying step; (e) optionally, glazing the green article to form a glazed green article; (f) subjecting the green article to a heat treatment step to form a hot fused article; and (g) cooling the hot fused article to form a glazed ceramic article. The particulate mixture includes from 30 wt % to 80 wt % recycled aluminium silicate material. The particulate mixture has: (i) a d.sub.50 particle size from 10 μm to 30 μm; (ii) a d.sub.70 particle size of less than 40 μm; and (iii) a d.sub.98 particle size of less than 60 μm. Steps (c) and (f), and optionally steps (d) and (e) are continuous process steps.

A blank material for a ceramic tile consists of the following components in percentage by weight: nepheline powder: 10%-15%; clay with a carbon content of ≥3.0 wt %: 10%-15%; clay with a carbon content of ≤0.5 wt %: 15%-22%; clay with a carbon content between 0.5 wt % and 3.0 wt %: 10%-15%; recycled waste blank: 5%-10%; sodium potassium powder: 5%-10%; sodium feldspar powder: 12%-20%; desulfurization residue: 0%-7%; waste from edging and polishing: 15%-26%; waste porcelain powder: 5%-10%; liquid gel remover: 0.3%-1.0%; liquid reinforcing agent: 0.2%-0.8%. Its preparation method comprises the following steps: preparing raw materials for a blank body and ball milling, powder spray granulation, aging, pressing and molding of the blank body, drying, polishing the blank body, spraying water, glazing, applying a decorative pattern, firing.

A porous ceramic honeycomb body (10) including intersecting walls that form channels (22) extending axially from a first end face to a second end face and layered plugs (62) comprised of a first layer (64) disposed on channel walls and a second layer (66) disposed inward toward an axial center of each respective channel on the first layer. The plugs seal at least one of a first portion of the channels at the first end face and a second portion of channels at the second end face of the porous ceramic honeycomb body.

A process for preparing a granular ceramic mixture includes the steps of: (a) contacting fluid bed combustion fly ash with an acidic aqueous solution to obtain acidic fluid bed combustion fly ash slurry; (b) removing excess acid from the slurry obtained in step (a) to obtain solid acid treated fluid bed combustion fly ash; and (c) contacting together: (i) the solid acid treated fluid bed combustion fly ash obtained in step (b); (ii) clay; (iii) optionally, feldspar; and (iv) optionally, other ingredients.

A mixture for coating a metal substrate to prevent or limit scale formation. The mixture comprises 20 to 90% by weight of at least one of: an oxide ceramic material, an aluminosilicate mineral or glass frit. The mixture further comprises 1 to 20% by weight of clay and 3 to 70% by weight of an alkali metal silicate.

A modification layer on a surface of a ceramic substrate, includes, in parts by mass: 56 to 67.5 parts of silicon dioxide; 12 to 18 parts of aluminum oxide; and 2.8 to 5.5 parts of lithium oxide. In an embodiment, the modification layer further includes, in parts by mass: at least one of 1.8 to 2.8 parts of phosphorus pentoxide; 0.5 to 2.0 parts of calcium oxide; 0.15 to 1.5 parts of magnesium oxide; and 2.5 to 5.25 parts of barium oxide.

A recycled aluminium silicate material, suitable for use in ceramic article production, wherein the recycled aluminium silicate material has a particle size distribution such that: (i) the d.sub.50 particle size is from 10 μm to 30 μm; (ii) the d.sub.70 particle size is less than 40 μm; and (iii) the d.sub.98 particle size is less than 60 μm. A particulate mixture, suitable for use in ceramic article production, includes the above defined recycled aluminium silicate material.

A crucible having a heat treated body. The heat treated body comprises a composition including an oxide material, from 5 wt % to 50 wt % a nitride material, and optionally a sintering aid. A weight ratio of the nitride material to the oxide material ranges from 0.02:1 to 2.0:1. The heat treated body has an oxide material lattice structure with nitride material at least partially encapsulated therein.