Multi-reactor systems with aromatization reactor vessels containing a catalyst with low surface area and pore volume, followed in series by aromatization reactor vessels containing a catalyst with high surface area and pore volume, are disclosed. Related reforming methods using the different aromatization catalysts also are described.

The present invention relates to a process for producing benzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide a benzene-rich aromatic stream and recovering the benzene from the benzene-rich aromatic stream.

The present invention relates to a process for producing benzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide a benzene-rich aromatic stream and recovering the benzene from the benzene-rich aromatic stream.

Multi-reactor systems with aromatization reactor vessels containing a catalyst with low surface area and pore volume, followed in series by aromatization reactor vessels containing a catalyst with high surface area and pore volume, are disclosed. Related reforming methods using the different aromatization catalysts also are described.

The present invention relates to a process for producing alkylated aromatic hydrocarbons such as ethyl benzene or cumene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to hydrocracking to provide benzene and subjecting said benzene to alkylation.

The present invention relates to a process for producing alkylated aromatic hydrocarbons such as ethyl benzene or cumene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to hydrocracking to provide benzene and subjecting said benzene to alkylation.

Spent aromatization catalysts containing a transition metal and a catalyst support are selectively poisoned in the disclosed reforming methods, resulting in improvements in overall aromatics yield and selectivity.

A process for producing cumene and/or ethylbenzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide an aromatization product stream and subjecting the thus obtained aromatization product stream to alkylation to produce an alkylated aromatic stream.

A process for producing cumene and/or ethylbenzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide an aromatization product stream and subjecting the thus obtained aromatization product stream to alkylation to produce an alkylated aromatic stream.

Catalysts and method of preparing the catalysts are disclosed. One of the catalysts includes a zeolite support, a Group VIII metal on the zeolite support, and at least two halides bound to the zeolite support, to the Group VIII metal, or to both, and can have an average crush strength greater than 11.25 lb based on at least two samples of pellets of the catalyst measured in accordance with ASTM D4179.