Provided herein are inter alia novel compositions and methods having application in the field of enhanced oil recovery. In particular, the large hydrophobe compounds and mixtures thereof presented herein can be used, inter alia, for the recovery of a large range of crude oil compositions from challenging reservoirs.

Provided herein are inter alia novel compositions and methods having application in the field of enhanced oil recovery. In particular, the large hydrophobe compounds and mixtures thereof presented herein can be used, inter alia, for the recovery of a large range of crude oil compositions from challenging reservoirs.

This invention relates to an anionic-cationic-nonionic surfactant as substantially represented by the formula (I), production and use thereof in tertiary oil recovery. The anionic-cationic-nonionic surfactant of this invention exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present anionic-cationic-nonionic surfactant, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.

##STR00001##

In the formula (I), each group is as defined in the specification.

This invention relates to an anionic-cationic-nonionic surfactant as substantially represented by the formula (I), production and use thereof in tertiary oil recovery. The anionic-cationic-nonionic surfactant of this invention exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present anionic-cationic-nonionic surfactant, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.

##STR00001##

In the formula (I), each group is as defined in the specification.

The present specification relates to a sulfonate-based compound and a polymer electrolyte membrane using the same, a membrane electrode assembly including the same, and a fuel cell including the same.

The present specification relates to a sulfonate-based compound and a polymer electrolyte membrane using the same, a membrane electrode assembly including the same, and a fuel cell including the same.

Methods of enhanced oil recovery are disclosed that use compositions including an alkyl polyether anionic surfactant having the general structure R.sup.1JA, wherein R.sup.1 is a C.sub.8-C.sub.18 primary or secondary radical group, J is a random, block, alternating, or alternating block polyether segment having the structure [(PO).sub.x(EO).sub.y(BO).sub.z], wherein x is 4 to 18, y is 0 to 20, and z is 0 to 5, and A is an anionic group; a co-surfactant having the general structure (R.sup.2).sub.q(B)Ph-L-Ph(D)(R.sup.3).sub.r, wherein R.sup.2 and R.sup.3 are each, independently in each instance, a C.sub.8-C.sub.24 linear or branched, primary or secondary alkyl group, B and D are anionic groups, q is 1 to 3, r is 1 to 3, and L is O or CH.sub.2; and an alkoxy alcohol.

Methods of enhanced oil recovery are disclosed that use compositions including an alkyl polyether anionic surfactant having the general structure R.sup.1JA, wherein R.sup.1 is a C.sub.8-C.sub.18 primary or secondary radical group, J is a random, block, alternating, or alternating block polyether segment having the structure [(PO).sub.x(EO).sub.y(BO).sub.z], wherein x is 4 to 18, y is 0 to 20, and z is 0 to 5, and A is an anionic group; a co-surfactant having the general structure (R.sup.2).sub.q(B)Ph-L-Ph(D)(R.sup.3).sub.r, wherein R.sup.2 and R.sup.3 are each, independently in each instance, a C.sub.8-C.sub.24 linear or branched, primary or secondary alkyl group, B and D are anionic groups, q is 1 to 3, r is 1 to 3, and L is O or CH.sub.2; and an alkoxy alcohol.

An anionic-cationic-nonionic surfactant as substantially represented by the formula (I) exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present anionic-cationic-nonionic surfactant, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.

##STR00001##

In the formula (I), each group is as defined in the specification.

An anionic-cationic-nonionic surfactant as substantially represented by the formula (I) exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present anionic-cationic-nonionic surfactant, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.

##STR00001##

In the formula (I), each group is as defined in the specification.