Patent classifications
C07F7/188
PREPARATION OF MULTIFUNCTIONAL ORGANOSILICON COMPOUNDS
A method of preparing a multifunctional organosilicon compound is provided. The method comprises reacting (A) an organosilanol compound comprising a functional moiety selected from alkoxysilyl moieties and acryloxy moieties and (B) a hydridosilane compound having at least two hydrolysable groups in the presence of (C) an acetate salt. A multifunctional organosilicon compound prepared according to the method is also provided.
METHOD OF MANUFACTURING ALKOXYSILANE COMPOUND
Provided is a method of manufacturing an alkoxysilane compound that is capable of more effectively removing ammonia generated as a by-product when the alkoxysilane compound is manufactured using a silazane-based compound, the method including adding an alcohol to a silazane-based compound of Formula 1:
##STR00001##
and allowing the alcohol to react with the silazane-based compound to prepare a first mixture comprising an alkoxysilane compound and ammonia; adding an alcohol and a compound of Formula 2:
(R.sub.1).sub.n(R.sub.2).sub.3-nSi—X
to the first mixture and allowing the alcohol and the compound of Formula 2 to react with the first mixture to prepare a second mixture in which an additional alkoxysilane compound and an ammonium salt are generated; adding an aqueous solvent to the second mixture to dissolve the ammonium salt; and separating and removing the ammonium salt.
COMPOSITIONS ND METHODS USING SAME FOR GERMANIUM SEED LAYER
Precursors and methods for (a) forming silicon-containing films and (b) functionalizing substrate surfaces in order to generate a germanium seed layer suitable for deposition of Ge films. In one aspect, there is provided a precursor of Formula I and/or a precursor of Formula II:
##STR00001##
##STR00002##
as described herein.
Functionalized Mesoporous Silica via an Aminosilane Surfactant Ion Exchange Reaction: Controlled Scaffold Design and Nitric Oxide Release
Nitric oxide-releasing mesoporous silica nanoparticles (MSNs) were prepared using an aminosilane-template surfactant ion exchange reaction. Initially, bare silica particles were synthesized under basic conditions in the presence of cetyltrimethylammonium bromide (CTAB). These particles were functionalized with nitric oxide (NO) donor precursors via the addition of aminosilane directly to the particle sol, and a commensurate ion exchange reaction between the cationic aminosilanes and CTAB. N-diazeniumdiolate NO donors were formed at the secondary amines to yield NO-releasing silica MSNs. Tuning of the ion exchange-based MSN modification approach allowed for the preparation of monodisperse particles ranging from 30 to 1100 nm. Regardless of size, the MSNs stored appreciable levels of NO (0.4-1.5 μmol/mg) with tunable NO-release durations (1-33 h) dependent on the aminosilane modification. The range of MSN sizes and NO release demonstrate the versatility of this strategy.
Bevel portion treatment agent composition and method of manufacturing wafer
A bevel portion treatment agent composition of the present invention is a bevel portion treatment agent composition containing a silylating agent, which is used for treating a bevel portion of a wafer, in which a surface modification index Y and a surface modification index Z measured by a predetermined procedure have a characteristic of satisfying 0.5≤Y/Z≤1.0.
MONOMER FOR POLYMER GEL, POLYMER GEL AND PREPARATION THEREFOR
Please replace the following substitute abstract for the abstract currently on file: Disclosed are a monomer for a polymer gel, a polymer gel and a preparation method therefor. The preparation method includes: reacting 4,4′,4″-trihydroxytriphenylmethane with tert-butyldimethylchlorosilane to obtain TPC-OTBS; reacting 4,4′,4″-trihydroxy triphenylmethane with sulfuryl fluoride in the presence of triethylamine to prepare TPC-OSO.sub.2F; and dissolving the TPC-OTBS and TPC-OSO.sub.2F in DMF, then adding DBU and ultrasonically dispersing same until uniform, and letting same stand to obtain a polymer gel. The gel obtained by the present invention can selectively adsorb an organic solvent by means of electrostatic interaction and Van der Waals force. The surface and internal morphologies of a solid material are characterized by SEM and TEM, in which the porous morphology of the solid material is found, and most of the pores are macropores.
PROCESSES AND INTERMEDIATES FOR THE PREPARATION OF CARBAPROSTACYCLIN ANALOGUES
The invention relates to processes for preparing carbaprostacyclin analogues and intermediates prepared from the processes. The invention also relates to cyclopentenone intermediates in racemic or optically active form.
PROCESSES AND INTERMEDIATES FOR THE PREPARATION OF CARBAPROSTACYCLIN ANALOGUES
The invention relates to processes for preparing carbaprostacyclin analogues and intermediates prepared from the processes. The invention also relates to cyclopentenone intermediates in racemic or optically active form.
Method for preparing aminopropylsilanes
Aminopropylalkoxysilanes of the formula
H.sub.2N—CR.sup.2R.sup.3—CHR.sup.1—CH.sub.2—SiR.sup.4R.sup.5(OR.sup.6) I,
are synthesized by hydrosilylating silazanes of the formulae ##STR00001##
and mixtures thereof, in the presence of a catalyst containing rhodium and/or iridium compounds, and then reacted with alcohol to form an aminopropylalkoxysilane.
Functionalized mesoporous silica via an aminosilane surfactant ion exchange reaction: controlled scaffold design and nitric oxide release
Nitric oxide-releasing mesoporous silica nanoparticles (MSNs) were prepared using an aminosilane-template surfactant ion exchange reaction. Initially, bare silica particles were synthesized under basic conditions in the presence of cetyltrimethylammonium bromide (CTAB). These particles were functionalized with nitric oxide (NO) donor precursors via the addition of aminosilane directly to the particle sol, and a commensurate ion exchange reaction between the cationic aminosilanes and CTAB. N-diazeniumdiolate NO donors were formed at the secondary amines to yield NO-releasing silica MSNs. Tuning of the ion exchange-based MSN modification approach allowed for the preparation of monodisperse particles ranging from 30 to 1100 nm. Regardless of size, the MSNs stored appreciable levels of NO (0.4-1.5 μmol/mg) with tunable NO-release durations (1-33 h) dependent on the aminosilane modification. The range of MSN sizes and NO release demonstrate the versatility of this strategy.