A film: (a) 50 to 85 wt % polymer comprising: (i) 30 to 70 wt % hard polymer with T.sub.g from 40 to 70° C. and 40 to 80 wt % (C.sub.1-C.sub.10)alkyl (meth)acrylate; 10 to 40 wt % C.sub.3-C.sub.8 carboxylic acid; and 0 to 25 wt % hydroxyalkyl (meth)acrylate; and (ii) 30 to 70 wt % soft polymer with T.sub.g from −20 to 20 ° C. and 50 to 90 wt % (C.sub.1-C.sub.10)alkyl (meth)acrylate; 5 to 30 wt % C.sub.3-C.sub.8 carboxylic acid; and 0 to 25 wt % hydroxyalkyl (meth)acrylate;
hard T.sub.g minus soft T.sub.g is at least 30° C.; (iii) 0 to 10 wt %, of (C.sub.12-C.sub.24)alkyl (meth)acrylate polymer containing crystallizable portion with T.sub.m from 0° C. to 37° C.; (b) 10 to 40 wt % of polyethylene oxide having M.sub.w from 250,000 to 4,000,000; and (c) 0 to 10 wt % of poly(vinylpyrrolidone) having M.sub.w from 25,000 to 2,000,000.

Curable adhesive compositions are provided that can be cured using ultraviolet or visible light radiation. These curable adhesive compositions, which contain a curable (meth)acrylate copolymer, have a creep compliance that is less than 5(10.sup.−4) inverse Pascals at 25° C., a creep compliance that is greater than 1(10.sup.−3) inverse Pascals at 70° C., and a shear storage modulus greater than 40 kiloPascals when measured at 25° C. at a frequency of 1 radian/second.

A toner comprising a toner particle comprising a binder resin, wherein the binder resin comprises a resin A and a resin B, in a differential scanning calorimetric measurement, a peak top temperature of the largest endothermic peak is present within a specific temperature range and an endothermic amount of an endothermic peak derived from the resin A is 30 to 70 J/g per 1 g of the toner, a ratio of content of the resin A in the toner particle is 60.0 to 90.0 mass %, the resin A comprises 40.0 to 70.0 mass % of a monomer unit (a) represented by formula (1) below, and the resin B comprises 5.0 to 30.0 mass % of a monomer unit (b) represented by formula (2) below:

##STR00001## in formulae (1) and (2), R.sup.1 and R.sup.2 denote a hydrogen atom or a methyl group, n and m denote a specific integer.

A toner comprising a toner particle comprising a binder resin, wherein the binder resin comprises a resin A and a resin B, in a differential scanning calorimetric measurement, a peak top temperature of the largest endothermic peak is present within a specific temperature range and an endothermic amount of an endothermic peak derived from the resin A is 30 to 70 J/g per 1 g of the toner, a ratio of content of the resin A in the toner particle is 60.0 to 90.0 mass %, the resin A comprises 40.0 to 70.0 mass % of a monomer unit (a) represented by formula (1) below, and the resin B comprises 5.0 to 30.0 mass % of a monomer unit (b) represented by formula (2) below:

##STR00001## in formulae (1) and (2), R.sup.1 and R.sup.2 denote a hydrogen atom or a methyl group, n and m denote a specific integer.

The present invention is an assembly layer for a flexible device. The assembly layer is derived from precursors that include about 0 to about 50 wt % C.sub.1-C.sub.9 alkyl(meth)acrylate, about 40 to about 99 wt % C.sub.10-C.sub.24 (meth)acrylate, about 0 to about 30 wt % hydroxyl (meth)acrylate, about 0 to about 10 wt % of a non-hydroxy functional polar monomer, and about 0 to about 5 wt % crosslinker.

The present invention is an assembly layer for a flexible device. The assembly layer is derived from precursors that include about 0 to about 50 wt % C.sub.1-C.sub.9 alkyl(meth)acrylate, about 40 to about 99 wt % C.sub.10-C.sub.24 (meth)acrylate, about 0 to about 30 wt % hydroxyl (meth)acrylate, about 0 to about 10 wt % of a non-hydroxy functional polar monomer, and about 0 to about 5 wt % crosslinker.

A photoinitiated polymerizable composition for 3D printing, the polymerizable composition comprising a nanogel component that comprises nanogel particles, wherein the nanogel particles comprise a copolymer with polymerizable reactive groups suitable for reacting with each other or a reactive diluent monomer, a reactive oligomer, a resin, or a combination thereof that is present in the polymerizable composition upon photoinitiation, wherein the nanogel component has a glass transition temperature that is in a range of about −50 C and about 20 C and an average molecular weight that is in a range of about 10 kg/mol and about 100 kg/mol, and wherein the nanoparticles have an average hydrodynamic radius that is in a range of 1 nm to about 5 nm.

In an active energy ray-curable polyurethane resin including a reaction product of a resin material containing an isocyanate group-terminated prepolymer and a hydroxy group-containing unsaturated compound, the isocyanate group-terminated prepolymer includes a reaction product of a prepolymer material containing a polyisocyanate component containing a xylylene diisocyanate and/or a hydrogenated xylylene diisocyanate, and a polyol component containing a polyoxyalkylene polyol having a number average molecular weight of 6000 or more and 12000 or less, and the viscosity at 25° C. of the active energy ray-curable polyurethane resin is 20000 mPa.Math.s or more and 40000 mPa.Math.s or less.

In an active energy ray-curable polyurethane resin including a reaction product of a resin material containing an isocyanate group-terminated prepolymer and a hydroxy group-containing unsaturated compound, the isocyanate group-terminated prepolymer includes a reaction product of a prepolymer material containing a polyisocyanate component containing a xylylene diisocyanate and/or a hydrogenated xylylene diisocyanate, and a polyol component containing a polyoxyalkylene polyol having a number average molecular weight of 6000 or more and 12000 or less, and the viscosity at 25° C. of the active energy ray-curable polyurethane resin is 20000 mPa.Math.s or more and 40000 mPa.Math.s or less.

The present invention provides an actinic ray-sensitive or radiation-sensitive resin composition containing (A) a resin having a polarity that increases by an action of an acid, and (B) a compound that generates an acid upon irradiation with actinic rays or radiation, represented by a specific general formula, is which the resin (A) includes a repeating unit represented by a specific general formula; and an actinic ray-sensitive or radiation-sensitive film formed of the actinic ray-sensitive or radiation-sensitive resin composition, a pattern forming method, and a method for manufacturing an electronic device.