The present invention provides dialkyl phosphorus-containing compounds, namely reactive mono-hydroxyl-functional dialkyl phosphinates, serving as highly efficient reactive flame retardants in flexible polyurethane foams. The invention further provides fire-retarded polyurethane compositions comprising said the reaction product of the mono-hydroxyl-functional dialkyl phosphinates with polyol and isocyanate foam forming components.

Shaped PU foam articles, preferably mattresses and/or cushions, wherein the polyurethane foam has been obtained by reaction of at least one polyol component and at least one isocyanate component in the presence of at least one compound of formula (1a) and at least one compound of formula (1b) and at least one blowing agent, are described.

Recovery times and/or airflow of flexible polyurethane foam is increased by including certain tackifiers in the foam formulation. The tackifiers are formed into an emulsion that includes a polyether containing oxyethylene groups, a nonionic surfactant and certain fumed silica, carbon black or talc particles.

Recovery time and/or airflow of flexible polyurethane foam is increased by including certain tackifiers in the foam formulation. The tackifiers are characterized in being incompatible with polyol or polyol mixture used to make the foam, having a viscosity of at least 10,000 centipoise at 25 C., having a glass transition temperature of at most 15 C. and being inert to other components of the foam formulation.

The present invention relates to a reaction mixture including one or more polyfunctional isocyanates such that the average isocyanate functionality of the mixture is greater than 2.1, and a catalyst composition including at least one trimerization catalyst and at least one epoxide group; and curing the reaction mixture to give a cured polymer composition made up of the reaction product of isocyanates with themselves.

A method for producing a polyurethane foam includes mixing and reacting a polyurethane foam raw material containing a polyol, an isocyanate, a foaming agent, and a catalyst, wherein the polyurethane foam raw material contains sodium bicarbonate and an organic solid acid such as citric acid or malic acid.

The invention relates to a method for producing polyurethane foams by reacting the following components A a polyol component, containing A1 40 to 100 parts by weight of polyether carbonate polyol with a hydroxyl number according to DIN 53240-1 June 2013 of 20 mg KOH/g to 120 mg KOH/g, A2 0 to 60 parts by weight of polyether polyol with a hydroxyl number according to DIN 53240-1 June 2013 of 20 mg KOH/g to 250 mg KOH/g and an ethylene oxide content of 0 to 60 wt. %, wherein the polyether polyol A2 is free from carbonate units, B B1 a catalyst and B2 optionally auxiliary and additional materials, C water and/or physical blowing agents with D di- and/or polyisocyanates, wherein the production occurs at a characteristic value of 90 to 120 and in the presence of a component K, characterised in that the component K is selected from at least one compound of the following formulas (R.sub.1)(R.sub.2)XC(O)(Y).sub.mZ (1) [(R.sub.1)(R.sub.2)XC(O)N(H)N(H)C(O)R.sub.3].sub.2 (2) [(R.sub.1)(R.sub.2)XR.sub.3C(O)N(H)].sub.2 (3), wherein m represents 0 or 1, X represents a hydroxyphenyl group, Y represents N(H), O, OR.sub.4 or C.sub.1- to C.sub.6-alkyls, Z represents H, a substituted or unsubstituted aryl group or a substituted or unsubstituted heteroaryl group, wherein Z does not represent H when Y represents O, R.sub.1, R.sub.2 respectively represent H, hydroxyl, a substituted or unsubstituted C.sub.1- to C.sub.6-alkyl group or OR.sub.5, R.sub.3 represents a substituted or unsubstituted to C.sub.12-alkylene group, a substituted or unsubstituted C.sub.1- to C.sub.12-alkenylene group, R.sub.4 represents a substituted or unsubstituted C.sub.1- to C.sub.6-alkylene group, R.sub.5 represents a substituted or unsubstituted C.sub.1- to C.sub.12-alkylene group, and the component K is used in a quantity of 0.05 to 10.00 parts by weight, in relation to the sum of the parts by weight of the components A1+A2=100 parts by weight.

Compositions suitable for production of polyurethane foams, comprising at least one OH-functional compound (OHC) obtainable by the partial or complete hydrogenation of ketone-aldehyde resins, wherein the OH-functional compound contains at least one structural element of the formula (1a) and optionally of the formulae (1b) and/or (1c), ##STR00001##
with R=aromatic with 6-14 carbon atoms, (cyclo)aliphatic with 1-12 carbon atoms, R.sup.1=H, CH.sub.2OH, R.sup.2=H, or a radical of the formula (CH.sub.2CH(R)O).sub.yH where R is hydrogen, methyl, ethyl or phenyl and y=1 to 50, k=2 to 15, preferably 3 to 12, more preferably 4 to 11, m=0 to 13, preferably 0 to 9, l=0 to 2,
where the sum of k+l+m is from 5 to 15, preferably from 5 to 12, and k>m, are described.

The method of the polyurethane polyol comprises (1) dissolving 2,3-epoxybutane and an acid catalyst in an inert solvent to obtain a solution A; dissolving triethylene glycol in an inert solvent to obtain a solution B; and dissolving epoxy vegetable oil in an inert solvent to obtain a solution C; (2) respectively and simultaneously pumping the solutions A and B into a first micromixer for mixing; (3) pumping the solution C and an effluent of the first microreactor into a second micromixer for mixing while carrying out step (2); and (4) dissolving the vegetable oil polyol in an inert solvent to obtain a solution D; dissolving epoxypropane and an alkaline catalyst in an inert solvent to obtain a solution E; and pumping the solution D and the solution E into a tank reactor for reaction, thereby obtaining the polyurethane polyol.

Fossil-fuel and rubber-derived waste stream conversion to composite lumber substitutes or barrier members; the composites having material properties and uses of greater value than the solid waste stream components separately or together. Preferred combinations including waste materials derived from waste carpet, waste tires, and waste bituminous roofing shingles, all enormous problems for landfill disposal. In a range of formulation ratios, when combined with a binder, new and marketable products are made from solid waste. Improved resistance to rot, to water, and to weathering is exhibited in synergy with improved compressive and flexural strength, enabling production of a wide variety of useful and environmentally-friendly structural products, for example. Product weight and strength can be engineered to suit and may be structural members for architectural, engineering or agricultural use. Advantageously, the new products themselves can be re-usedby an end-of-life process for making more new products, achieving the capacity to make and remake multigenerational products from solid wastes and to reduce loading of landfills.