Two-component solventless polyurethane adhesive compositions comprising an isocyanate component and an isocyanate-reactive are disclosed, the compositions comprising an isocyanate component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and, optionally, a bio-based polyol. Methods for forming laminate structures are also disclosed, the methods comprising forming an adhesive composition by mixing an isocyanate adhesive component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive adhesive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and optionally, a bio-based polyol, applying the adhesive composition to a surface of a first substrate, and bringing a surface of a second substrate into contact with the adhesive composition on the surface of the first substrate, thereby forming the laminate structure. Laminate structures are also disclosed.

The dental restorative material of the present invention is a dental restorative material that contains a resin matrix and an inorganic filler in an amount of 25 to 1,000 parts by mass per 100 parts by mass of the resin matrix, and in the dental restorative material, the resin matrix contains a polyurethane resin, and the inorganic filler has an average particle diameter of 0.001 to 100 μm. According to the present invention, a dental restorative material that has a high bending strength and a high surface hardness, and is excellent in transparency and cutting workability, and a resin material for dental cutting work containing the same can be provided.

The invention relates to a thermoplastic moulding composition comprising A) at least one thermoplastic polyurethane polymer obtainable by reacting at least the following constituent components: I) one or more aliphatic diisocyanates having a molecular weight of between 140 g/mol to 170 g/mol and II) one or more aliphatic diols having a molecular weight of between 62 g/mol to 120 g/mol, the constituent components used to produce the thermoplastic polyurethane polymer consisting of at least 95% by weight of one or more aliphatic diisocyanates I) and one or more aliphatic diols II), based on the total mass of the constituent components used, wherein the one or more aliphatic diisocyanates I) and the one or more aliphatic diols II) are present in a molar ratio in the range from 1:0:0.95 to 0.95:1.0, characterized in that the ratio (I) of the thermoplastic polyurethane polymer is in a range from 2.3 to 6, wherein (II) is the molar mass centrifugal agent and (III) is the molar mass average, in each case determined by gel permeation chromatography in hexafluoroisopropanol against polymethyl methacrylate as standard, also comprising B) at least one mould release agent. The invention also relates to the use of the moulding composition for producing mouldings and to the mouldings thereof.

Disclosed is a polyurethane-modified epoxy resin composition capable of satisfying both high toughness and high elasticity. This epoxy resin composition is an epoxy resin composition, in which (A) a polyurethane-modified epoxy resin having a polycarbonate structure in the molecule and having a urethane modification rate of 20 to 60% by weight, (B) a non-polyurethane-modified epoxy resin that is liquid at 30° C., (C) a solid epoxy resin having a glass transition temperature or melting point of 50° C. or higher and (D) an amine-based curing agent that is dicyandiamide or a derivative thereof are as essential components, and 20.0 to 50.0% by weight of (A), 0.1 to 50.0% by weight of (B) and 0.1 to 50.0% by weight of (C) are contained relative to the total of (A) to (D).

Disclosed is a polyurethane-modified epoxy resin composition capable of satisfying both high toughness and high elasticity. This epoxy resin composition is an epoxy resin composition, in which (A) a polyurethane-modified epoxy resin having a polycarbonate structure in the molecule and having a urethane modification rate of 20 to 60% by weight, (B) a non-polyurethane-modified epoxy resin that is liquid at 30° C., (C) a solid epoxy resin having a glass transition temperature or melting point of 50° C. or higher and (D) an amine-based curing agent that is dicyandiamide or a derivative thereof are as essential components, and 20.0 to 50.0% by weight of (A), 0.1 to 50.0% by weight of (B) and 0.1 to 50.0% by weight of (C) are contained relative to the total of (A) to (D).

Provided is a decorative film having excellent weather resistance, scratch resistance, and elongation properties, and a decorative article using the same, and a surface protective composition that can exhibit such properties. A decorative film according to one embodiment of the present disclosure includes a surface protective layer. The surface protective layer contains a polyurethane resin obtained by reacting a composition containing a polycarbonate diol, and a trimer or higher multimer of a diisocyanate including a cyclohexane structure, a diisocyanate including a cyclohexane structure or a prepolymer thereof, or a mixture thereof, and the decorative film satisfies Formulas 1 to 3 below: 0≤X.sup.1≤2.00 . . . Formula 1 X.sup.1≤−0.7×X.sup.2+4.67 . . . Formula 2 X.sup.1≥−0.7×X.sup.2+2.14 . . . Formula 3 where X.sup.1 is a numerical value obtained by multiplying the number of branches from a branch point relative to a converted molecular weight of the polyurethane resin by 1000, and X.sup.2 is a numerical value obtained by multiplying the number of cyclohexane structure portions included in the polyurethane resin relative to the converted molecular weight of the polyurethane resin by 1000.

A biomedical device is disclosed which is a polymerization product of a mixture comprising (a) one or more difunctional isocyanates; (b) one or more polyalcohols; (c) one or more hydroxy-terminated polysiloxane prepolymers; and (d) one or more polyoxazoline polyols having a weight average molecular weight of equal to or greater than about 1000 Daltons.

An aqueous polyurethane resin dispersion, the polyurethane resin is obtainable by reacting an allophanate based isocyanate according to general formula I or II, optionally a polyether diol, a polyol containing a quaternary N-atom or tertiary amino group and a polyol selected from the group consisting of polyester polyol, polyether polyol, polycarbonate polyol, a polyacrylate polyol, a polyolefin and a polyamide polyol. The polyurethane resin is suitable as a resin in treatment liquids of substrates and images made by inkjet printing.

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An aqueous polyurethane resin dispersion, the polyurethane resin is obtainable by reacting an allophanate based isocyanate according to general formula I or II, optionally a polyether diol, a polyol containing a quaternary N-atom or tertiary amino group and a polyol selected from the group consisting of polyester polyol, polyether polyol, polycarbonate polyol, a polyacrylate polyol, a polyolefin and a polyamide polyol. The polyurethane resin is suitable as a resin in treatment liquids of substrates and images made by inkjet printing.

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A present invention related to a method for manufacturing a dot bonding shoe insole using an adhesive resin containing hydrophobic nano-silica, including: melting adhesive resin made of any one selected from thermoplastic polyurethane (TPU) or ethylene vinyl acetate (EVA) containing hydrophobic nano-silica in the range of 0.2 to 5 phr and applying to the surface of the transfer roller in which the intaglio dot pattern is formed in a mesh shape in the shape of the shoe insole;

removing the adhesive resin applied other area than the intaglio dot pattern of the surface of the transfer roller;
transferring the adhesive resin applied to the intaglio dot pattern of the surface of the transfer roller to either one of the foam or the fabric;
bonding the foam and the fabric by compressing; and
cutting a shoe insole shape in a package in which the foam and the fabric are bonded.