Rotational cast polyurethane composition prepared from a prepolymer composition comprising: a) an isocyanate-terminated polyurethane prepolymer; and b) a curative agent comprising i) a polyol; ii) an aromatic diamine; iii) a thixotropic aliphatic amine; and iv) a thixotropic colloidal additive, wherein the prepolymer comprises a product produce by the reaction of a polyol with an organic diisocyanate monomer comprising 4,4-diisocyanato diphenylmethane (MDI), and which prepolymer comprises less than 1.0% by weight of free MDI monomer, based on the toal weight of the prepolymer, exhibits a range of enhanced physical properties compared to those obtained from prepolymers comprising a higher level of free MDI monomer.

Polyureas made from amino-functional alkoxysilanes, polyisocyanates, and polyfunctional amino- and/or hydroxyl compounds. The polyureas may be moisture-cured in a 1K system or be included in a 2K system with amino and epoxy or acrylate compounds.

The present invention relates to a process for producing flame-retardant porous materials comprising the following steps: (a) reacting at least one polyfunctional isocyanate (a1) and at least one polyfunctional aromatic amine (a2) in an organic solvent optionally in the presence of water as component (a3) and optionally in the presence of at least one catalyst (a5); and then (b) removing the organic solvent to obtain the organic porous material,
where step (a) is carried out in the presence of at least one organic flame retardant as component (a4), where this flame retardant is soluble in the solvent. The invention further relates to the porous materials thus obtainable, and also to the use of the porous materials for thermal insulation.

The present invention relates to a polymer structure, comprising a base member, a polymer mediator formed by molecular layer deposition (MLD) on the base member, a linker formed on the mediator, and a transmitter bonded with the linker, wherein a bond between the linker and the transmitter is cleavable by an external stimulus.

One variation of a method for directly casting a thin layer onto a substrate includes: combining a prepolymer, a solvent, and a curing agent to define a viscous material; advancing a substrate from a roll across a surface continuously at a first speed; depositing the viscous material at a viscosity through a deposition head onto the substrate, the viscous material flowing laterally across the substrate to form a thin layer of substantially uniform thickness over the substrate over a period of time while the substrate advances along the surface; and, at a distance from the deposition head depositing the viscous material onto the substrate corresponding to a duration of time for the viscous material to flow laterally across the substrate, heating the viscous material to evaporate solvent and to induce reaction between the curing agent and the prepolymer to cure the viscous material to form a layer.

One variation of a method for directly casting a thin layer onto a substrate includes: combining a prepolymer, a solvent, and a curing agent to define a viscous material; advancing a substrate from a roll across a surface continuously at a first speed; depositing the viscous material at a viscosity through a deposition head onto the substrate, the viscous material flowing laterally across the substrate to form a thin layer of substantially uniform thickness over the substrate over a period of time while the substrate advances along the surface; and, at a distance from the deposition head depositing the viscous material onto the substrate corresponding to a duration of time for the viscous material to flow laterally across the substrate, heating the viscous material to evaporate solvent and to induce reaction between the curing agent and the prepolymer to cure the viscous material to form a layer.

The invention relates to peelable and chemically resistant coatings for metal and plastic substrates, and to the coating agent compositions required to produce same. The invention also relates to a process for producing such coatings and to the use of the coating agent compositions to protectively coat metal and plastic substrates in the field of aircraft construction.

Urethane-urea-acrylic cast sheet materials are made from a reaction product of components including polyisocyanate compound having at least two isocyanate functional groups and optional polyol (or pre-reacted urethane prepolymer having at least two isocyanate functional groups), curative having at least two amine functional groups, acrylic monomer, and optional multifunctional monomer having a first functional group having an active hydrogen and a second functional group having at least one double bond. The urethane-urea-acrylic cast sheet materials exhibit excellent impact properties and desirable hardness while also maintaining optical properties such as low haze that can be comparable to that of conventional cast acrylic sheet.

A polyurea or polyurea-urethane elastomer comprises a soft polymer segment and a hard polymer segment, wherein the hard polymer segment includes polyurea groups in combination with H-bond accepting chain extenders (HACEs) to reduce the flow temperature (T.sub.flow) while maintaining the excellent mechanical properties such that the resulting polyurea elatomer is rendered melt-processable.

The present invention is a polishing pad formed by foamed polyurethane, with a content of S phase in the foamed polyurethane, as determined by pulsed NMR measurement at 25 C., exceeding 70%.