Patent classifications
C08G18/3296
Quick-drying solvent-free sag-resistant polyurethane waterproof coating and preparation method therefor
A quick-drying solvent-free sag-resistant polyurethane waterproof coating and preparation method therefor, raw materials therefor comprising a polyurethane prepolymer, a plasticizer, a dispersant, a filler, a dehydrant, a catalyst, a defoamant, and an oxazolidine reactive diluent. The catalyst is composed of pentamethyl dipropylene triamine, tetramethylethylenediamine, and 1,8-diazabicyclo[5.4.0]undecene. Raw materials of the polyurethane prepolymer comprise a polyether diol, a polyether triol, an isocyanate, and a chain extender. The prepolymer is prepared by means of the following method: 1) measuring out the raw materials for the polyurethane prepolymer, and reacting the polyether diol with the isocyanate until reaction is complete; 2) then adding the polyether triol for reaction until reaction is complete; 3) then adding the chain extender for reaction, completing preparation. The waterproof coating preparation method is: i) preparing the polyurethane prepolymer; ii) mixing the prepared polyurethane prepolymer with the rest of the raw materials for the waterproof coating to obtain the final product. The present waterproof coating features such advantages as exceptional film-forming speed and sag resistance, and low viscosity.
LOW VOC, HIGH SOLID DECK MEMBRANES
A basecoat coating composition includes an aromatic polyurethane pre-polymer having isocyanate terminal end groups, a first solvent and optionally a second VOC-exempt solvent, in which the total composition formulation has a VOC content of less than 97 g/L. A topcoat coating composition includes an aliphatic polyurethane pre-polymer having isocyanate terminal end groups, a first solvent and optionally a second VOC-exempt solvent, in which the total composition formulation has a VOC content of less than or equal to 95 g/L. The total composition formulations of the basecoat and/or topcoat may have a VOC content of less than 50 g/L. A membrane system may include an optional primer coating, and the above described basecoat and topcoat coating compositions.
LOW VOC, HIGH SOLID DECK MEMBRANES
A basecoat coating composition includes an aromatic polyurethane pre-polymer having isocyanate terminal end groups, a first solvent and optionally a second VOC-exempt solvent, in which the total composition formulation has a VOC content of less than 97 g/L. A topcoat coating composition includes an aliphatic polyurethane pre-polymer having isocyanate terminal end groups, a first solvent and optionally a second VOC-exempt solvent, in which the total composition formulation has a VOC content of less than or equal to 95 g/L. The total composition formulations of the basecoat and/or topcoat may have a VOC content of less than 50 g/L. A membrane system may include an optional primer coating, and the above described basecoat and topcoat coating compositions.
TWO-COMPONENT POLYURETHANE ADHESIVE HAVING SUBSTANTIALLY TEMPERATURE-INDEPENDENT MECHANICAL PROPERTIES AND HIGH STRENGTH
A two-component polyurethane composition containing at least 55% by weight of polybutadiene polyols based on the total amount of all polyols having an average molecular weight of at least 500 g/mol, and at least one latent hardener, where the ratio of the number of reactive groups in the latent hardener to the number of OH groups present is in the range from 0.02 to 0.4. The composition has a long open time, blister-free curing, a very low glass transition temperature, high elasticity and surprisingly high strength which is very constant over a wide temperature range. Furthermore, it has very good adhesion to metallic and nonmetallic substrates, causing barely any stress cracks on glassy thermoplastics.
POLYURETHANE COMPOSITION WITH LOW PLASTICISER MIGRATION
A composition having at least one polyisocyanate and/or at least one isocyanate-group-containing polyurethane polymer and at least one latent hardener having aldimino group(s) of formula (I)as an elastic adhesive, sealant or coating, which is applied on at least one plasticiser migration sensitive substrate and/or is provided with at least one covering layer and a composite obtained therefrom. The method is characterized in that porous material or stress-crackforming plastics can be used without restriction as substrates and very different materials can be used without restriction as covering layers, without the occurrence of damage associated with plasticiser migration from the composition, such as bleeding, discoloring, spotting, softening, swelling or detachment.
POLYURETHANE COMPOSITION WITH LOW PLASTICISER MIGRATION
A composition having at least one polyisocyanate and/or at least one isocyanate-group-containing polyurethane polymer and at least one latent hardener having aldimino group(s) of formula (I)as an elastic adhesive, sealant or coating, which is applied on at least one plasticiser migration sensitive substrate and/or is provided with at least one covering layer and a composite obtained therefrom. The method is characterized in that porous material or stress-crackforming plastics can be used without restriction as substrates and very different materials can be used without restriction as covering layers, without the occurrence of damage associated with plasticiser migration from the composition, such as bleeding, discoloring, spotting, softening, swelling or detachment.
HYDROXYALDIMINE AND CURABLE POLYURETHANE COMPOSITION WITH A LOW MONOMERIC ISOCYANATE CONTENT
Hydroxyaldimines of formula (I), their reaction products, in particular products of their reaction with polyisocyanates, and compositions including isocyanate groups and containing such reaction products. The hydroxyaldimine permits compositions which have good storage stability, a long open time, low odour, rapid, bubble-free curing and good mechanical properties, and which are not susceptible to plasticizer migration and have a particularly low content of monomeric diisocyanates. In particular, it permits reactive hot-melt adhesives with a particularly good workability.
HYDROXYALDIMINE AND CURABLE POLYURETHANE COMPOSITION WITH A LOW MONOMERIC ISOCYANATE CONTENT
Hydroxyaldimines of formula (I), their reaction products, in particular products of their reaction with polyisocyanates, and compositions including isocyanate groups and containing such reaction products. The hydroxyaldimine permits compositions which have good storage stability, a long open time, low odour, rapid, bubble-free curing and good mechanical properties, and which are not susceptible to plasticizer migration and have a particularly low content of monomeric diisocyanates. In particular, it permits reactive hot-melt adhesives with a particularly good workability.
One-component type curable composition and one-component type waterproofing material
A one-component type curable composition includes: an isocyanate group-containing urethane prepolymer (A) obtained by allowing a polyoxyalkylene-based polyol (a-1) having a number average molecular weight of 1,000 or more and less than 3,000, a polyol (a-2) having a number average molecular weight of less than 1,000, an epoxy (meth)acrylate (a-3) containing two or more hydroxyl groups in one molecule, and isophorone diisocyanate (a-4) to react with each other; a compound (B) having an oxazolidine ring; a first curing accelerator (C) configured to accelerate a reaction between at least one of a secondary amino group or a hydroxyl group generated by hydrolysis of the (B) and an isocyanate group of the (A); and a second curing accelerator (D) configured to accelerate the hydrolysis of the (B).
One-component type curable composition and one-component type waterproofing material
A one-component type curable composition includes: an isocyanate group-containing urethane prepolymer (A) obtained by allowing a polyoxyalkylene-based polyol (a-1) having a number average molecular weight of 1,000 or more and less than 3,000, a polyol (a-2) having a number average molecular weight of less than 1,000, an epoxy (meth)acrylate (a-3) containing two or more hydroxyl groups in one molecule, and isophorone diisocyanate (a-4) to react with each other; a compound (B) having an oxazolidine ring; a first curing accelerator (C) configured to accelerate a reaction between at least one of a secondary amino group or a hydroxyl group generated by hydrolysis of the (B) and an isocyanate group of the (A); and a second curing accelerator (D) configured to accelerate the hydrolysis of the (B).